• 한국수소및신에너지학회논문집
• /
• 제32권6호
• /
• pp.524-533
• /
• 2021

In this study, a series of anion conductive organic/inorganic composite membranes with excellent ionic conductivity and chemical stability were prepared by introducing graphene oxide (GO) inorganic nanofiller into the quaternized poly(phenylen oxide (Q-PPO) polymer matrix. The fabricated organic/inorganic composite membranes showed higher ionic conductivity than the pristine membrane. In particular, Q-PPO/GO 0.7 showed the highest ionic conductivity value of 143.2 mS/cm at 90℃, which was 1.56 times higher than the pristine membrane Q-PPO (91.5 mS/cm). In addition, the organic/inorganic composite membrane showed superior dimensional stability and alkaline stability compared to the pristine membrane, and the physicochemical stability was improved as the content of inorganic fillers increased. Therefore, we suggest that the as-prepared organic/inorganic composite membranes are very promising materials for anion exchange membrane applications with high conductivity and alkaline stability.

• Bulletin of the Korean Chemical Society
• /
• 제21권6호
• /
• pp.604-610
• /
• 2000

Drying-step in sol-gel processing was bypassed by exchanging alcoholic solvent in forsterite alcogel directly with MMA. By in-situ polymerization of the MMA, organic-inorganic nano-composite of PMMA-forsterite was prepared. As porous nature of inorganic networks in the gel was preserved and fixated in the composite, spherical morphology of PMMA was resulted. The PMMA-forsterite composite was optically transparent, machinable,mechanically sustainable, and thermally more stable than pristine PMMA. When doped with $Eu^{+3}$, inorganic moiety in the composite provided site environment that is very different from that in pristine PMMA. Prominent $^{5}D_0$ → $^{7}F_0$ transition at 578 nm, broken degeneracy in $^{5}D_0$ → $^{7}F_1$ and $^{5}D_0$ →$^{7}F_2$ transitions suggested that $Eu^{+3}$ was exclusively doped in the inorganic moiety of the composite, which had lower symmetry than the organic counterpart.

• Bulletin of the Korean Chemical Society
• /
• 제28권6호
• /
• pp.1015-1020
• /
• 2007

A simple approach to prepare arrays of Au/TiO2 composite nanoparticles by using Au-loaded block copolymers as templates combined with a sol-gel process is described. The organic-inorganic hybrid films with closely packed inorganic nanodomains in organic matrix are produced by spin coating the mixtures of polystyrene-block-poly(ethylene oxide) (PS-b-PEO)/HAuCl4 solution and sol-gel precursor solution. After removal of the organic matrix with deep UV irradiation, arrays of Au/TiO2 composite nanoparticles with different compositions or particle sizes can be easily produced. Different photoluminescence (PL) emission spectra from an organic-inorganic hybrid film and arrays of Au/TiO2 composite nanoparticles indicate that TiO2 and Au components exist as separate state in the initial hybrid film and form composite nanoparticles after the removal of the block copolymer matrix.

• 한국세라믹학회지
• /
• 제50권6호
• /
• pp.460-465
• /
• 2013

Plate-shaped inorganic particles are coated onto a stainless steel substrate by the electrophoretic deposition of a precursor slurry which includes the inorganic particles of $Al_2O_3$ and polymer resin in mixed solvents to mimic the abalone shell structure, which is a composite of plate-shaped inorganic particles and organic interlayer binding materials with a layered orientation. The process parameters of the electrophoretic deposition include the voltage, coating time, and conductivity of the substrate. In addition, the suspension parameters are the particle size, concentration, viscosity, conductivity, and stability. We prepared an organic-inorganic composite coating with a high inorganic solid content by arraying the plate-shaped $Al_2O_3$ particles and electrophoretic resin via an electrophoretic deposition method. We analyzed the effect of the slurry composition and the electrophoretic deposition process parameters on the physical, mechanical and thermal properties of the coating layer, i.e., the thickness, density, particle orientation, Young's modulus and thermogravimetric analysis results.

• 한국분말재료학회지
• /
• 제31권2호
• /
• pp.126-131
• /
• 2024

The aim of this study was to improve the chemical stability of cycloserine containing organic and inorganic compounds. Composite particles were manufactured with a 1:1 weight ratio of organic/inorganic compounds and cycloserine. The influence of organic/inorganic compounds on the stability of cycloserine was investigated under accelerated stress conditions at 60℃/75% RH for 24 hours. In addition, the properties of the composite particles were evaluated using differential scanning calorimetry (DSC), scanning electron microscopy (SEM), and the dissolution of the drug was assessed by preparing it as a hard capsule. Among the organic and inorganic compounds investigated, calcium hydroxide most improved the stability of cycloserine under accelerated stress conditions (53.3 ± 2.2% vs 1.7 ± 0.2%). DSC results confirmed the compatibility between calcium hydroxide and the cycloserine, and SEM results confirmed that it was evenly distributed around the cycloserine. Calcium hydroxide also showed more than 90% cycloserine dissolution within 15 minutes. Therefore, the calcium hydroxide and cycloserine composite particles may be candidates for cycloserine oral pharmaceuticals with enhanced drug stability.

• 분석과학
• /
• 제5권3호
• /
• pp.309-317
• /
• 1992

졸-겔법에 의해 무기-유기 복합체를 합성하였으며, 복합체의 결합특성을 알아보기 위하여 DMTA(Dynamic Mechanical Thermal Analyzer)를 이용하여 유리전이 온돈(Tg)를 측정하였다. HCl 과 물의 양이 증가될수록 Tg는 고운으로 진행됨으로부터 복합화가 더 잘 일어남을 알 수 있었다. 그러나 반응시간에 따른 Tg의 변화는 관찰되지 않았다.

• 한국수소및신에너지학회논문집
• /
• 제33권1호
• /
• pp.28-37
• /
• 2022

In this study, we synthesized a poly(pheneylene oxide) (PPO)-based organic/inorganic composite membrane having silicotungstic acid (STA) for the development of an anion exchange membrane with excellent ionic conductivity and physicochemical stability. The organic/inorganic composite membranes were prepared by introducing different STA contents (0 wt%, 10 wt%, 30 wt%, and 50 wt%) into the quaternizaed(Q)-PPO matrix. The prepared anion exchange membranes were subjected to structural analysis by proton neclear magnetic resonance and Fourier transform infrared, and thermal behavior of membranes was confirmed by thermogravimetric analysis. Among the prepared composite membranes, the ion conductivity of Q-PPO/STA-50 (40.5 mS cm^-1) showed 1.46 times compared to that of the pristine membrane (27.6 mS cm^-1). Therefore, these results demonstrated that organic/inorganic composite membranes are promising candidates for application of anion exchange membranes.

• 한국안전학회지
• /
• 제19권1호
• /
• pp.81-87
• /
• 2004

Composite particles using inorganic and organic chemicals were synthesized and the results of those reaction were compared to variation of temperature and agitation speed in presence of $CaCO_3$ which was adsorbed SDBS. Also the synthesises were optimized according to conversion rate of composite particles. In inorganic/organic core-shell composite particle polymerization, $CaCO_3$ adsorbed by 0.5wt% surfactant SDBS was prepared initially and then core $CaCO_3$ was encapsulated by sequential emulsion polymerization using MMA at the addition of APS 3.16${\times}$$10^{-3}$mol/L to minimize the coagulated PMMA particle itself during MMA shell polymerization. Encapsulated PMMA on $CaCO_3$ as inorganic/organic core-shell particles was verified by FT-IR and DSC analysis. It was found that the $CaCO_3$ was very well encapsulated by PMMA as shell. The surfaces were distinctly found as spindle shape and broad particle distribution after capsulation.

• 한국구조물진단유지관리공학회 논문집
• /
• 제24권6호
• /
• pp.50-58
• /
• 2020

발수제를 콘크리트 표면에 함침시키는 방법은 콘크리트의 균열이 발생할 경우, 기대하는 내구성을 확보할 수가 없다. 최근, 다양한 방수 및 발수 재료들을 콘크리트나 모르타르 내부에 혼입하여 균열 내부에서도 발수성을 확보하였으나 압축강도가 크게 저하되었다. 압축강도 저하를 극복하기 위해 아직까지 유기물과 무기물의 장점들을 동시에 이용한 연구가 없기 때문에, 본 연구에서는 유기물과 무기물을 적절히 혼합한 유무기 복합 발수제를 모르타르에 혼입하여 물리적 특성 및 발수성능을 평가하였다. 유무기 복합 발수제 혼입 시 Liquid 시험체에 비해 플로우 약 10%, 공기량이 약 50% 감소하였으며, P6L1 시험체의 경우, 기존 발수제인 Powder와 같은 39.5MPa로 무혼입 모르타르 대비 약 3.5%의 압축강도 저하를 확인하였다. 발수성능도 유무기 복합 발수제 혼입 시험체가 기존의 발수제 혼입 시험체인 Powder보다 높은 발수성을 확인하였으며, 염화물 침투 저항성 평가결과, 유무기 복합 발수제 혼입 시험체가 무혼입 모르타르 대비 약 45% 통과 전하량이 감소되는 것을 확인하였다. 이상의 실험을 종합하면, Powder 발수제와 Liquid 발수제를 5:1의 비율로 혼입한 P5L1 유무기 복합 발수제가 압축강도 저하 방지 및 발수성능 확보를 위하여 가장 합리적이라고 판단된다.

• 멤브레인
• /
• 제18권4호
• /
• pp.345-353
• /
• 2008

염료감응형 태양전지에 사용되기 위한 유기/무기 복합소재를 합성하였다. 다양한 분자량(400, 600, 1,500, 3,400)의 polyethylene glycol의 양 끝단을 ethoxysilane기로 치환하여 전구체를 제조하였으며, 전구체의 졸-겔 반응을 통하여 복합소재를 합성하였다. 전해질막은 유기/무기 복합소재를 NaI 및 $I_2$로 도핑하여 제조하였으며, 제조한 전해질막의 이온전도 특성을 측정하였다. 전해질막의 이온전도도는 원료로 사용한 PEG에 크게 영향을 받았으며 가장 높은 이온전도도는 분자량 1,500의 PEG를 원료로 사용한 전해질 막에서 볼 수 있었다. 복합전해질막은 전도도에 있어서 큰 향상을 보였다. PEO 전해질막에 비하여 분자량 1,500의 PEC로 제조한 복합전해질막은 월등하게 높은 이온전도도를 보였다.