• 한국환경과학회지
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• 제13권7호
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• pp.627-635
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• 2004

Evaluated were household THMs exposure associated with the use of municipal tap water treated with chlorine and with ozone-chlorine. The current study measured the THMs concentrations in the tap water and indoor and outdoor air in the two types of household, along with an estimation of THMs exposure from water ingestion, showering, and the inhalation of indoor air. Chloroform was the most abundant THMs in all three media, yet no bromoform was detected in any sample. Contrary to previous findings, the fall water THMs concentrations exhibited no significant difference between the chlorine and ozone-chlorine treated water. However, the spring median chloroform concentration in the tap water treated with chlorine (17.6 ppb) was 1.3 times higher than that in the tap water treated with ozone-chlorine (13.4 ppb). It is suggested that the effects of the water parameters should be considered when evaluating the advantage of ozone-chlorine disinfection for THMs formation over chlorine disinfection. The indoor air THMs concentration trend was also consistent with the water concentration trend, yet the outdoor air THMs concentrations did not differ significantly between the two types of household. The indoor to outdoor air concentration ratios were comparable with previous studies. The THMs exposure estimates from water ingestion, showering, and the inhalation of indoor air suggested that, for the residents living in the surveyed households, their exposure to THMs in the home was mostly associated with their household water use, rather than the indoor air. The THMs exposure estimates from tap water ingestion were similar to those from showering.

• 환경위생공학
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• 제21권1호
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• pp.58-65
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• 2006

This study is measured in at ozone concentrated places in school and outside of school where places that use copy machine and the others do not use one. Library copy room, Search room, Y-Copy, J-copy, R-shop are the places using copy machines and Search room, K-apt, J-billiard hall are the opposite. The measurement was held three times a day-the morning, the afternoon and the evening-once for each at indoor and outdoor. 8 places were lower than domestic ozone concentration standard(0.06ppm). The indoor ozone concentration average was the highest in Search room of school and was the lowest in Library restroom. The outdoor ozone concentration average was the highest in J-billiard hall.

• 한국산업보건학회지
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• 제26권2호
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• pp.188-197
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• 2016

Objectives: The purpose of this study was to evaluate the ozone exposure levels and the variations in ozone concentration in a semiconductor fabrication facility and office in relation to the ozone concentration in the outdoor air. Methods: This study was performed in an office, semiconductor fabrication facility(such as etching, diffusion, diffusion plenum), and outdoors from June to August, 2015. Measurements were taken six times at the same places using an active sampler(pumped) and real-time equipment. Ozone monitoring by the active sampler method and analysis were carried out by OSHA Method ID-214. Real-time measurement was carried out by ozone measuring equipment using a non-dispersive ultraviolet absorption method. Results: Ozone concentrations in the semiconductor fabrication facility and office were 0.7~7.1 ppb in area samples and 0.72~4.07 ppb in real-time measurement, which were 0.88~8.88% of the occupational exposure limit. The concentration of ozone generated by a laser printer in the office was less than 2 ppb. There was not a significant difference between ozone concentrations before and after using the laser printer. The indoor/outdoor concentration ratio(I/O ratio) in the semiconductor fabrication facility and office was 0.05 and 0.06, respectively. Conclusions: All the samples contained ozone levels lower than the occupational exposure limit and it was confirmed that the concentration of outdoor ozone had no significant effect on indoor ozone concentration.

• 한국조경학회지
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• 제28권5호
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• pp.87-92
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• 2000

The purpose of this study is to investigate Ozone which we have to contact in our daily lives. Recently Ozone becomes a serious pollutant in the inside and outside. To select th indicator plants or the purifier plants for air pollution caused by ozone, this stud has been conducted with interior landscape plant of 10 species. The results are as follows; 1) The visible demage by Ozone was firstly observed on Viburnum awabuki among 10 species, and it occurred after the lapse of 10, 8 and 4 hours on 0.5, 1.0 and 2.0 ppm ozone treatment, respectively. The first symptom of visible demage appeared on chlorosis or blotting of leaves, then progressed on necrosis of leaves. 2) On the other hand, Litsea japonica and Ardisia japonica were so resistant against Ozone fumigation that they were not demage independently of Ozone concentration till the lapse of 60 hours. 3) Chlorophyll contents were decreased by the increased Ozone concentration. At this time, grana destruction was observed. The most sensitive plant to ozone was Viburnum awabuki, and we suggest that Viburnum awabuki would be possible one to use for the indicator plant. The most resistance plant to Ozone was Litsea japonic and Ardisia japonica, we suggest that Litsea japonica and Ardisia japonica would be possible to use for the purifier plant for Ozone pollution.

• 한국방사선학회논문지
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• 제10권3호
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• pp.171-180
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• 2016

본 연구는 고 에너지 방사선 조사에 기인된 방사선치료실 내 오존 농도의 변화를 비교 분석하고자 하였다. 이를 위하여 치료실 주변 대기 중 오존 농도와 치료실 내 배경 오존 농도를 분석하여 고 에너지 방사선 조사에 기인된 치료실 내 평균 오존 농도를 비교하였다. 치료실 내 배경 오존 농도는 평균 $17.4{\pm}7.9ppb$로 방사선치료실 주변의 대기 중 오존 농도(평균 $36.8{\pm}22.3ppb$)보다 약 50% 정도 통계적으로 유의하게 낮게 나타났다(p<0.05). 고 에너지 방사선 조사에 기인된 치료실 내 오존 농도는 방사선이 조사됨과 동시에 배경 오존 농도의 약 2배 수준으로 급격하게 증가되었으며 조사시간이 증가함에 따라 기울기가 일정한 증가 추이를 보이다가 약 130초에서 180초 부근에서 최대 오존 농도를 이루고 점차 포화되는 경향을 보였으며 배경 오존 농도로 감소하는데 소요되는 시간은 약 10분 이상이었다. 본 연구 결과를 토대로 고 에너지 방사선 조사에 기인된 방사선치료실 내 오존 농도는 후각을 자극하는 오존의 특이한 냄새를 맡거나 순간적인 호흡 곤란과 마른기침으로 가슴 통증 등의 신체적 증상이 나타날 수 있는 수준으로 밀폐된 방사선치료실에서 고농도 오존에 장시간 노출될 경우 폐 질환을 악화시킬 수 있기 때문에 각별한 주의가 요구된다.

• 한국입자에어로졸학회지
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• 제7권1호
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• pp.1-8
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• 2011

In this study, the formation of nanoparticles by a reaction of ozone with the volatile organic compounds(VOCs) emitted from a commercial home cleaner liquid was investigated using a $1-m^3$ reaction chamber($1{\times}1{\times}1m$). The home cleaner liquid was found to contain many VOCs, particularly terpenes. Some of these VOCs are known to readily react with ozone, forming indoor secondary pollutants. The correlation of particle concentration and reacted ozone concentration was examined with injections of three different ozone concentrations; 50, 100 and 200 ppb. The secondary nanoparticles were formed faster, with their numbers and mass concentrations becoming higher on increasing the concentration of ozone injected.

• 한국산림과학회지
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• 제102권4호
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• pp.601-607
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• 2013

오존에 따른 피해 현상을 관찰해 보고 식물 수종에 따라 어떤 차이가 있는지 알아보기 위해서 소나무(Pinus densiflora)와 실내식물 가운데 많이 활용되는 스파티필름(Spathiphyllum patinii), 스킨답서스(Epipremnum aureum)의 항산화 효소인 GR(Glutathione Reductase), APX(Ascorbate peroxidase)의 활성, 광합성속도와 잎의 해부학적 피해 현상을 관찰하였다. 오존농도는 30 ppb로 유지했고, 50일 동안 하루 8시간(09:00~17:00) 오존을 처리한 후 다음과 같은 결과를 얻었다. 오존 농도가 30 ppb정도의 낮은 농도에서 소나무는 광합성속도, 수분이용효율, 항산화 효소의 활성, 잎의 해부학적인 특성에서 대조구와 크게 다르지 않은 것을 알 수 있었다. 반면에 실내식물인 스파티필름과 스킨답서스의 광합성속도, 항산화 효소의 활성(특히, GR의 활성), 잎의 해부학적 특성이 대조구와 오존 처리구간의 상당한 차이를 보여, 오존에 대한 민감성이 소나무에 비해 큰 것으로 나타났다.

• 한국환경과학회지
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• 제16권8호
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• pp.1001-1009
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• 2007

Passive sampler is a simple and cost-effective measuring equipment for ambient and indoor air pollution. We studied the performance of a short term (1 hour mean concentration) ozone passive sampler which was coated with a colorant (indigo carmine) to a filter substrate. Acetone and sulfamic acid added ozone passive sampler was investigated to measure short term mean ozone concentration. Ozone response and interference of criteria air pollutant($SO_2,\;NO_2$, CO) on a short term ozone passive sampler was tested through experimental chamber. The results show sulfamic acid added passive ozone sampler have good response in ozone exposure. Interference of $NO_2$ gas is larger than other two criteria gases.

• 한국환경보건학회지
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• 제32권2호
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• pp.171-178
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• 2006

The objectives of this study were to investigate the formation of trihalomethanes(THMs) and to compare the concentration level of THMs of swimming pools water by different disinfection methods such as chlorine, ozone-chlorine, and salt brine electrolysis generator (SBEG). The concentration of chloroform was the highest in the chlorine system, and the SBEG was the highest in the production of bromodichloromethane (BDCM), dibromochloromethane (DBCM) and bromoform. The average concentration of total trihalomethanes (TTHMs) in three disinfection systems were $64.5{\pm}27.4mg/l(SBEG),\;43.8{\pm}22.3mg/l(chlorine)$, and $30.6{\pm}16.1mg/l(ozone-chlorine)$, respectively. In chlorine and ozone-chlorine disinfection system, chloroform concentration was highest, followed by BDCN, then DBCM. In the SBEG, TTHMs was composed of 42% of chloroform, 28.9% of bromoform, 15.1% of BDCM and 14% of DBCM, respectively. The strongest correlation was obtained in the levels of chloroform and TTHMs in chlorine, and ozone-chlorine disinfection systems from both indoor and outdoor swimming pools ($r=0.989{\sim}0.999$, p<0.01). In the SBEG, the levels of BDCM and TTHMs showed a good correlation (r=0.913, p<0.01). In chlorine and ozone-chlorine disinfection systems at indoor swimming pools, pH, TOC and $KMnO_4$ consumption showed strong correlation with chloroform and TTHMs concentrations (p<0.01). In the SBEG, pH and TOC were also strongly correlated with chloroform (p<0.01). pH and TTHMs were correlated as well (p<0.05).

• 한국환경보건학회지
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• 제23권2호
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• pp.57-63
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• 1997

This study was carried out to find the adverse health effects of ozone by papers, the potential indoor sources of ozone by papers, and then the removal mechanism of ozone by experiments. The exposure of individuals to excessive levels of ozone both in the industrial and ambient environment is a continuing public health concern. Ozone indoors may play a role in generating secondary pollutants that may have adverse health effects. The removal efficiency of ozone was studied by (1) the effect of concentration on breakthrough time, (2) the effect of flow rate on breakthrough time, (3) the effect of adsorbent's weight on breakthrough time, (4) the effect of temperature on breakthrough time, (5) the application of Langmuir's isotherm equation in using activated carbon. The followings are the conclusions that were derived from this study. 1. In the effect of concentration on breakthrough time, the adsorption capacity of activated carbon was inversely proportional to ozone concentratuion (0.1, 0.2, 0.3 ppm). 2. In the effect of flow rate on breakthrough time, the service life of activated carbon was inversely proportional to flow rate (2, 8, 14l/min). 3. The difference in removal efficiency of ozone between weights(100 mg and 150 mg) was seen. And when weight of activated carbon was 100 mg and 150 mg, pressure loss was 4-5mmHg and 6-7mmHg, respectively. It is required to study relations among flow rate and adsorbent's weight and ventilation quantity, too. 4. Generally, Langmuir's equation, one of the oldest and most used frequently isotherm equation, applies to chemisorption. In case of ozone, when the weight of activated carbon was 70 mg and temperature 40, slope(1/a) was $6.25\times 10^{-1}$ and intercept(1/ab) was $1.9\times 10^{-4}$ (average r=0.94).