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Characterization of Area Installing Combined Geothermal Systems : Hydrogeological Properties of Aquifer (복합지열시스템에 대한 부지특성화: 대수층의 수리지질학적 특성)

  • Mok, Jong-Koo;Park, Yu-Chul;Park, Youngyun;Kim, Seung-Kyum;Oh, Jeong-Seok;Seonwoo, Eun-Mi
    • The Journal of Engineering Geology
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    • v.27 no.3
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    • pp.293-304
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    • 2017
  • This study was performed in order to hydrogeological analysis of aquifer, which is a necessary part for evaluating the efficiency of the combined well and open-closed loops geothermal (CWG) systems. CWG systems have been proposed for the effective utilization of geothermal energy by combining open loop geothermal systems and closed loop geothermal systems. Small aperture CWG systems and large aperture CWG systems were installed at a green house land with water curtain facilities in Chungju City. Aquifer tests include pumping tests and step-drawdown tests were conducted to analyse hydrogeological characteristics of aquifer in the study area. The transmissivity was estimated in the range of $13.49{\sim}58.99cm^2/sec$, and the storativity was estimated in the range of $1.13{\times}10^{-5}{\sim}5.20{\times}10^{-3}$. The geochemical analysis showed $Ca^{2+}$ ion and ${HCO_3}^-$ ion were dominant in groundwater. The Langelier Saturation Index and the Ryznar Stability Index showed low scaling potential of groundwater. In the analysis of vertical water temperature change, the geothermal gradient was estimated as $2.1^{\circ}C/100m$, which indicated the aquifer was enough for geothermal systems. In conclusion, groundwater is rich, can stably use geothermal heat, and it is less likely to cause deterioration of thermal energy efficiency by precipitation of carbonate minerals in study area. Therefore, the study area is suitable for installation of the combined geothermal system.

Plasma Cholesterol-Lowering Effects of Alpiniae katsumadaii Extract as an Inhibiter of Pancreatic Cholesterol Esterase Activity (췌장 콜레스테롤 에스터레이즈 저해제인 초두구 추출물의 혈중 콜레스테롤 저해효과)

  • Kim, Hee-Sook;Kim, Ji-Young;Choi, Jong-Won;Huh, Young-Mi;Suh, Pann-Ghill;Ryu, Sung-Ho
    • Korean Journal of Food Science and Technology
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    • v.32 no.1
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    • pp.200-205
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    • 2000
  • Ethanol extract of Alpiniae Katsumadaii semen inhibited potently cholesterol esterase activity in vitro. Chloroform fraction of ethanol extract showed the stronger inhibitory effect than other solvent fractions-ethylacetate fraction, butanol fraction, and aqueous fraction. The chloroform frac ion of Alpiniae katsumadaii semen were studied as a candidator of plasma cholesterol lowering material in high cholesterol-fed rats. In high cholesterol-fed rats, the diet with chloroform fraction of 100 mg/kg and 150 mg/kg lowered not only plasma neutral lipids contents 25.9% and 26.5% but also plasma total cholesterol level 11.8% and 20.8%, respectively. Plasma HDL-cholesterol level and Atherogenic Index(AI) in Alpiniae chloroform fraction-fed rats were recovered as those level of normal rats.

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Reliability Analysis of Chloride Ion Penetration based on Level II Method for Marine Concrete Structure (해양 콘크리트 구조물에 대한 Level II 수준에서의 염소이온침투 신뢰성 해석)

  • Han, Sang-Hun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.12 no.6
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    • pp.129-139
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    • 2008
  • Due to uncertainty of numerous variables in durability model, a probalistic approach is increasing. Monte Carlo simulation (Level III method) is an easily accessible method, but requires a lot of repeated operations. This paper evaluated the effectiveness of First Order Second Moment method (Level II method), which is more convenient and time saving method than MCS, to predict the corrosion initiation in harbor concrete structure. Mean Value First Order Second Moment method (MV FOSM) and Advanced First Order Second Moment method (AFOSM) are applied to the error function solution of Fick's second law modeling chloride diffusion. Reliability index and failure probability based on MV FOSM and AFOSM are compared with the results by MCS. The comparison showed that AFOSM and MCS predict the similar reliability index and MV FOSM underestimates the probability of corrosion initiation by chloride attack. Also, the sensitivity of variables in durability model to corrosion initiation probability was evaluated on the basis of AFOSM. The results showed that AFOSM is a simple and efficient method to estimate the probability of corrosion initiation in harbor structures.

Synthesis and Crystal Structure of Lead Iodide in the Sodalite Cavities of Zeolite A (LTA)

  • Kim, Seok-Han;Lim, Woo-Taik;Kim, Ghyung-Hwa;Lee, Heung-Soo;Heo, Nam-Ho
    • Bulletin of the Korean Chemical Society
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    • v.27 no.5
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    • pp.679-686
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    • 2006
  • The positions of $PbI _2$ molecule synthesized into the molecular-dimensioned cavities of $\mid K_6 (Pb _4I_2)(PbI_2) _{0.67}-(H_2O)_2\mid [Si _{12}Al _{12}O _{48}]$-LTA have been determined. A single crystal of $\mid Pb _6\mid [Si _{12}Al _{12}O _{48}]$-LTA, prepared by the dynamic ion-exchange of $\mid Na _{12}\mid [Si _{12}Al _{12}O _{48}]$-LTA with aqueous 0.05 M $Pb _(NO _3)_2$ and washed with deionized water, was placed in a stream of flowing aqueous 0.05 M KI at 294 K for three days. The resulting crystal structure of the product $( \mid K_6 (Pb _4I_2)(PbI_2) _{0.67}(H_2O)_2\mid [Si _{12}Al _{12}O _{48}]$-LTA, a = 12.353(1) $\AA$) was determined at 294 K by single-crystal X-ray diffraction in the space group Pm3 m. It was refined with all measured reflections to the final error index $R_1$ = 0.062 for 623 reflections which $F_o$ > 4$\sigma$($F_o$). 4.67 $Pb ^{2+}$ and six $K^+$ ions per unit cell are found at three crystallographically distinct positions: 3.67 $Pb ^{2+}$ and three $K^+$ ions on the 3-fold axes opposite six-rings in the large cavity, three $K^+$ ions off the plane of the eight-rings, and the remaining one $Pb ^{2+}$ ion lies opposite four-ring in the large cavity. 0.67 $Pb ^{2+}$ ions and 1.34 $I^-$ ions per unit cell are found in the sodalite units, indicating the formation of a $PbI _2$ molecule in 67% of the sodalite units. Each $PbI _2$ (Pb-I = 3.392(7) $\AA$) is held in place by the coordination of its one $Pb ^{2+}$ ion to the zeolite framework (a $Pb ^{2+}$ cation is 0.74 $\AA$ from a six-ring oxygens) and by the coordination of its two $I^-$ ions to $K^+$ ions through six-rings (I-K = 3.63(4) $\AA$). Two additional $I^-$ ions per unit cell are found opposite a four-ring in the large cavity and form $Pb _2K_2I^{5+}$ and $Pb _2K_2I^{3+}$ moieties, respectively, and two water molecules per unit cell are also found on the 3-fold axes in the large cavity.

Flame Retardant Synergistic Performance between Cyclic Diphosphonate Ester and Melamine in Polyamide 6 (Polymide 6에서 Cyclic Diphosphonate Ester와 Melamine의 난연 효과)

  • Wang, Xueli;Jiang, Jianming;Yang, Shenglin;Jin, Junhong;Li, Guang
    • Polymer(Korea)
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    • v.32 no.2
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    • pp.125-130
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    • 2008
  • A commercial cyclic diphosphonate ester (TPMP) and melamine (MA) was combined and added to polyamide 6 (PA6) to prepare the fire retardant PA6. An increase of the oxygen index to 28.6 as well as an improvement of the UL-94 classification to V-0 rating was observed. Cone measurements explained the rate of heat release (RHR) decreased and TGA showed the early decomposition and high solid residue due to co-addition of TPMP and MA, suggesting the occurrence of synergistic effect of TPMP and MA on fire resistance of PA6. The morphology of the char developed during combust ion showed the appearance of thick, intumescent cells on the surface of retardant PA6, which protects the underlying material from the action of the heat flux or flame and limits the diffusion of combustible volatile products towards the flame and oxygen.

Nonlinear optical properties of $TiO_{2}$ single crystal ($TiO_{2}$ 단결정의 비선형광학 특성)

  • 신재혁;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.5 no.3
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    • pp.240-249
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    • 1995
  • Rutile type of $TiO_{2}$ single crystal was grown by floating zone method in order to obtain the highly transparent and contamination-free single crystal. The linear refractive index of perpendicular and parallel to c-axis was measured as a function o f wavelength from 500 to 1000nm. The optical energy band gap was estimated as 2.99 eV from the absorption spectrum. The theoretical $\chi^{(3)}$} value of $TiO_{2}$ was discussed in comparison with that of $SiO_{2}$ quartz single crystal on the basis of semiempirical model. On the other hand, the second-hyperpolarizability, ${\gamma}({Ti}^{4+})$ was calculated in order to describe the effect of $Ti_{4}$ ion on the third order nonlinear optical properties.

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Molecular Characterization and Mitogenic Activity of a Lectin from Purse Crab Philyra Pisum

  • Na, Jong-Cheon;Park, Byung-Tae;Chung, Woo-Hyuk;Kim, Ha-Hyung
    • The Korean Journal of Physiology and Pharmacology
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    • v.15 no.4
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    • pp.241-244
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    • 2011
  • A lectin from the hemolymph of purse crab, Philyra pisum, was found to have anti-proliferative activity on human lung cancer cells by our laboratory. In this study, P. pisum lectin (PPL) was molecularly characterized including molecular mass, amino acid sequences, amino acid composition, and the effects of metal ions, temperature, and pH on the activity. We found that PPL showed mitogenic activity on human lymphocytes and BALB/c mouse splenocytes. The mitogenic activity (maximum stimulation index, $SI=9.57{\pm}0.59$) of PPL on human lymphocytes was higher than that of a standard well-known plant mitogen, concanavalin A (maximum $SI=8.80{\pm}0.59$). The mitogenic activity mediated by PPL is required for optimum dosing, and higher or lower concentrations caused decreases in mitogenic response. PPL also induced mitogenic activity on mouse splenocytes, however, the maximum SI ($1.77{\pm}0.09$) on mouse splenocytes of PPL was lower than that ($2.14{\pm}0.15$) of concanavalin A. In conclusion, PPL is a metal ion-dependent monomer lectin with mitogenic activity, and could be used as a lymphocyte or splenocyte stimulator.

An investigation on dicing 28-nm node Cu/low-k wafer with a Picosecond Pulse Laser

  • Hsu, Hsiang-Chen;Chu, Li-Ming;Liu, Baojun;Fu, Chih-Chiang
    • Journal of the Microelectronics and Packaging Society
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    • v.21 no.4
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    • pp.63-68
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    • 2014
  • For a nanoscale Cu/low-k wafer, inter-layer dielectric (ILD) and metal layers peelings, cracks, chipping, and delamination are the most common dicing defects by traditional diamond blade saw process. Sidewall void in sawing street is one of the key factors to bring about cracks and chipping. The aim of this research is to evaluate laser grooving & mechanical sawing parameters to eliminate sidewall void and avoid top-side chipping as well as peeling. An ultra-fast pico-second (ps) laser is applied to groove/singulate the 28-nanometer node wafer with Cu/low-k dielectric. A series of comprehensive parametric study on the recipes of input laser power, repetition rate, grooving speed, defocus amount and street index has been conducted to improve the quality of dicing process. The effects of the laser kerf geometry, grooving edge quality and defects are evaluated by using scanning electron microscopy (SEM) and focused ion beam (FIB). Experimental results have shown that the laser grooving technique is capable to improve the quality and yield issues on Cu/low-k wafer dicing process.

Status and Prospect of Test Methods of Quality Silicone Water Repellent for Protecting Reinforced Concrete

  • Sun, H.Y.;Yuan, Z.Y.;Yang, Z.;Shan, G.L.;Shen, M.X.
    • Corrosion Science and Technology
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    • v.16 no.3
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    • pp.141-150
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    • 2017
  • Impregnating with quality silicone water repellent on the concrete surface is an effective method of protecting concrete. Quality silicone water repellent has been widely used in the engineering profession because of its desirable properties such as hydrophobicity, keeping concrete breathable and preserving the original appearance of the concrete. The companies in China that produce silicone water repellent are listed. Test methods in the specifications or standards about silicone water repellent in China are summed. The test methods relative to durability of concrete impregnated with silicone water repellent (such as resistant to chloride ion penetration, resistant to alkali, resistance to freezing and thawing and weatherability etc.) and the constructive quality (such as water absorption rate, impregnating depth and the dry velocity coefficient etc.) are compared and analyzed. The results indicate that there are differences among test methods relative to different specifications with the same index and therefore, confusion has ensued when selecting test methods. All test methods with the exception of the method of water absorption rate by using a Karsten flask are not non-destructive methods or conducted in a laboratory. Finally, further research on silicone water repellent during application is proposed.

Topography Modeling and Simulation for the Complex Structures of ULSI Interconnects (복잡한 ULSI 배선 구조 생성을 위한 토포그래피 모델링 및 시뮬레이션)

  • Gwon, O-Seop;Yun, Seok-In;Kim, Yun-Tae;Yun, Im-Dae;Won, Tae-Yeong
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.39 no.4
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    • pp.26-34
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    • 2002
  • A dynamically-allocated topographical model, so-called cell advancing model, has been developed modifying the cell model. Memory requirements are reduced by dynamically allocating completed topography and material information only at surface cells, and setting other cells as a material index. In this paper, this model is presented and verified with applications to etching process by using the analytic model and Monte Carlo model for the incident ion flux, deposition process, and process integration. In case of DRAM cell fabrication process with 5,440,500(130$\times$155$\times$270) cells takes about 22MB memory to represent the topography.