• Title/Summary/Keyword: In-situ condition

Search Result 560, Processing Time 0.031 seconds

Enhancement of Dielectric Properties of Pb(La,Ti)$O_3$ Thin Films Using Two-step Process (Two-Step Process를 이용한 Pb(La,Ti)$O_3$ 박막의 유전특성 향상 연구)

  • Hur, Chang-Hoi;Lee, Sang-Yeol
    • Proceedings of the KIEE Conference
    • /
    • 2000.11c
    • /
    • pp.416-418
    • /
    • 2000
  • Thin films of phase-pure perovskite $(Pb_{0.72}La_{0.28})Ti_{0.93}O_3$ (PLT) were deposited in-situ onto Pt/Ti/$SiO_2$/Si substrates by pulsed laser deposition. We have systematically investigated the variation of grain sizes depending on the process condition. Both in-situ annealing and ex-situ annealing treatments have been compared depending on the annealing time. The grain sizes of PLT thin films were successfully controlled 260 to 350 nm by changing process parameters. Microstructural and electrical properties of the film were investigated by C-V measurement, leakage current measurement and SEM. Two-step process to grow $(Pb_{0.72}La_{0.28})Ti_{0.93}O_3$ (PLT) films was adopted and verified to be useful to enlarge the grain size of the film and to enhance the leakage current characteristics.

  • PDF

Effect of annealing of Pb(La,Ti)$O_3$ thin films by Pulsed laser deposition process (펄스 레이저 증착법으로 제작된 PLT박막의 열처리 효과 연구)

  • Hur, Chang-Hoi;Shim, Kyung-Suk;Lee, Sang-Yeol
    • Proceedings of the KIEE Conference
    • /
    • 2000.07c
    • /
    • pp.1483-1484
    • /
    • 2000
  • Dielectric thin films of PLT(Pb(La.Ti)O3) for the application of highly integrated memory devices have been deposited on Pt/Ti/SiO2/Si substrates in situ by pulsed laser deposition(PLD). We have systematically investigated the variation of grain sizes depending on the condition of post-annealing and the variation of deposition rate. Both in-situ annealing and ex-situ annealing have been compared depending on the annealing time. C-V measurement, ferroelectric properties, leakage current and SEM were performed to investigate the electrical properties and the microstructural properties of Pb(La,Ti)$O_3$ films.

  • PDF

Production Biodiesel via In-situ Transesterification from Chlorella sp. using Microwave with Base Catalyst

  • Kalsum, Ummu;Kusuma, Heri Septya;Roesyadi, Achmad;Mahfud, Mahfud
    • Korean Chemical Engineering Research
    • /
    • v.56 no.5
    • /
    • pp.773-778
    • /
    • 2018
  • In-situ transesterification of microalgae lipids using microwave irradiation has potential to simplify and accelerate biodiesel production, as it minimizes production cost and reaction time by direct transesterification of microalgae into biodiesel with microwave as a heating source. This study was conducted to research the effect of microwave irradiation with in-situ transesterification of microalgae under base catalyst condition. The process variables (reaction time, solvent ratio, microwave power) were studied using 2% of catalyst concentration. The maximum yield of FAME was obtained at about 32.18% at the reaction time of 30 min with biomass-methanol ratio 1:12 (w/v) and microwave power of 450 W. The GC MS analysis obtained that the main component of FAME from microalgal oils (or lipids) was palmitic acid, stearic acid and oleic acid. The results show that microwaves can be used as a heating source to synthesize biodiesel from microalgae in terms of major components resulting.

In-situ EQCM Study on Growth of Polypyrrole Films Using Gold Electrodes Modified with Self-Assembled Monolayers in an Aqueous Solution (자기 집합 단분자막 개질 금 전극을 이용한 수용액 중 폴리피를 성장에 관한 In-situ EQCM 연구)

  • Seo, Kyoung--Ja;Jeon, Il-Cheol
    • Journal of the Korean Electrochemical Society
    • /
    • v.5 no.3
    • /
    • pp.143-152
    • /
    • 2002
  • The growth of Polypyrrole film has been investigated during electropolymerization in an aqueous solution on bare and SAM modified gold electrodes by in-situ EQCM and ex-situ AFM. According to the result of cyclic voltammetry measurements, in the case of a bare gold electrode, the electrochemical deposition of polypyrrole were dependent on the limiting oxidative potential, but not on scan numbers. When the limiting potential higher than 0.8 V was applied on the electrode, the amount of polypyrrole deposited on a gold electrode was rapidly increased and the abnormal mass change attributed to the rearrangement of polypyrrole films was observed as the scan number increased. The polypyrrole film Prepared on electrodes modified with 1-dodecanethiol SAM or thiophene SAM grew 3-dimensionally with the rearrangement of film. However, in the case of BPUS SAM, 2-dimensional layer-by-layer growth of film was observed without the rearrangement of film. AFM images showed films with chain-shaped and/ or donut-shaped polymers when grown rapidly and a wrinkled film at the steady state condition.

Capacitive Sensor for in situ Measurement of Deterioration of Car Engine Oil (자동차 엔진오일 열화상태 in situ 측정용 전기용량 센서)

  • Lee, R.D.;Kim, H.J.;Semenov, Yu. P.
    • Journal of Sensor Science and Technology
    • /
    • v.10 no.4
    • /
    • pp.266-272
    • /
    • 2001
  • A coil-type capacitive sensor on which the deterioration of the car engine oil can be in situ measured, has been developed. The sensor was designed to get over 10 pF at the limited space on the drain hole of the oil pan. The design factors for stable capacitance measurement such as coil diameter and winding condition, materials and configuration of the coil former, and shielding method, etc., were known by both computer simulation and experimental investigations. The dielectric properties measured by several sensors for an used sample oil were consisted within 0.25%. The sensor installed on the car having severe vibration, temperature and humidity fluctuation, even electromagnetic noise, has shown very distinguishable results.

  • PDF

LES Method Modeling and Fabrication of Al-TiB2 Composite by In-situ Melt Mixing Process (In-situ 용탕혼합 합성법에 의한 Al-TiB2 복합재료의 LES 기법 모델링 및 제조)

  • Park, Jungsu;Kim, Jonghoon;Ha, Manyoung;Park, Bongkyu;Park, Yongho;Park, Ikmin
    • Korean Journal of Metals and Materials
    • /
    • v.46 no.6
    • /
    • pp.382-389
    • /
    • 2008
  • To manufacture Al MMCs, in-situ melt mixing process is used because it is free from contamination, and it makes reinforcements homogeneously dispersed. Large eddy simulation method is used to find the optimum melt mixing condition. At the Re 3000, the most suitable mixing is occurred between Al-Ti and Al- B melts. The in-situ formed $TiB_2$ particles has the size varying from 40 nm to 130 nm, due to the increase of cooling rate, and exhibits a homogeneous dispersion. And the interface between reinforcement and matrix is clean. Both hardness and Young's modulus of this composite are improved with increasing the cooling rate.

Application of The Dynamic Cone Penetrometer for Strength Estimation of Pavement Foundation (현장에서의 동적관입시험을 이용한 노상토의 지지력 평가연구)

  • An, Ji-Hwan;Yang, Sung-Lin;Park, Hee-Mun;Kwon, Su-Ahn
    • International Journal of Highway Engineering
    • /
    • v.6 no.3 s.21
    • /
    • pp.17-26
    • /
    • 2004
  • The in-situ California Bearing Ratio (CBR) test has been widely used for evaluating the subgrade condition in asphalt concrete pavements. However, because the in-situ CBR test is expensive and takes plenty of time for operation, it is very difficult to figure out the in-situ characteristics of subgrade strength in detail. For faster and economical operation, the Dynamic Cone Penetrometer (DCP) has been often utilized for estimating the subgrade strength in the field. The relationship between the CBR value and DCP index obtained from the DCP testing has been studied using the laboratory and in-situ testing by other foreign researchers. The objective of this study is to determine the relationship between in-situ CBR value and DCP index of the subgrade materials used in Korea. The DCP index for evaluating the strength of subgrade materials produced in Korea is presented in this paper. Research results propose the regression equation to explain the relationship between the CBR and DCP tests. The in-situ CBR values of subgrade materials range from 20 to 45% indicating the good and sound subgrade condition.

  • PDF

Effect of Rock Discontinuities on Dynamic Shear Stress Wave (암반 불연속면이 동적 전단응력파에 미치는 영향)

  • Son, Moorak
    • Journal of the Korean GEO-environmental Society
    • /
    • v.19 no.12
    • /
    • pp.25-32
    • /
    • 2018
  • This paper investigates the effect of rock discontinuities on a shear stress wave that is induced by earthquake or blasting and provides the result of numerical parametric studies. The numerical tests of different conditions of rock and discontinuity have been carried out after confirming that the numerical approach is valid throughout a verification analysis from which the test results were compared with a theoretical solution. In-situ stress condition was considered as a rock condition and internal friction angle and cohesive value, which are the shear strength parameters, were considered as discontinuities condition. The joint inclination angle was also taken into account as a parameter. With the various conditions of different parameters, the test results showed that a shear stress wave propagating through a mass is highly influenced by the shear strength of discontinuities and the condition of joint inclination angle as well as in-situ stress. The study results indicate that when earthquake or blasting-induced dynamic loading propagates through a jointed rock mass or a stratified soil ground the effect of in-situ stress and discontinuities including a stratum boundary should be taken into account when evaluating the dynamic effect on nearby facilities and structures.

An Empirical Test of the Dynamic Optimality Condition for Exhaustible Resources -An Input Distance Function- (투입물거리함수를 통한 고갈자원의 동태적 최적이용 여부 검증)

  • Lee, Myunghun
    • Environmental and Resource Economics Review
    • /
    • v.15 no.4
    • /
    • pp.673-692
    • /
    • 2006
  • In order to test for the dynamic optimality condition for the use of nonrenewable resource, it is necessary to estimate the shadow value of the resource in situ. In the previous literatures, a time series for in situ price has been derived either as the difference between marginal revenue and marginal cost or by differentiating with respect to the quantity of ore extracted the restricted cost function in which the quantity of ore is quasi-fixed. However, not only inconsistent estimates are likely to be generated due to the nonmalleability of capital, but the estimate of marginal revenue will be affected by market power. Since firms will likely fail to minimize the cost of the reproducible inputs subject to market prices under realistic circumstances where imperfect factor markets, strikes, or government regulations are present, the shadow in situ values obtained by estimating the restricted cost function can be biased. This paper provides a valid methodology for checking the dynamic optimality condition for a nonrenewable resource by using the input distance function. Our methodology has some advantages over previous ones: only data on quantities of inputs and outputs are required; nor is the maintained hypothesis of cost minimization required; adoption of linear programming enables us to circumvent autocorrelated errors problem caused by use of time series or panel data. The dynamic optimality condition for domestic coal mining does not hold for constant discount rates ranging from 2 to 20 percent over the period 1970~1993. The dynamic optimality condition also does not hold for variable rates ranging from fourth to four times the real interest rate.

  • PDF

Condition Monitoring under In-situ Lubrication Status of Bearing Using Infrared Thermography (적외선열화상을 이용한 베어링의 실시간 윤활상태에 따른 상태감시에 관한 연구)

  • Kim, Dong-Yeon;Hong, Dong-Pyo;Yu, Chung-Hwan;Kim, Won-Tae
    • Journal of the Korean Society for Nondestructive Testing
    • /
    • v.30 no.2
    • /
    • pp.121-125
    • /
    • 2010
  • The infrared thermography technology rather than traditional nondestructive methods has benefits with non-contact and non-destructive testings in measuring for the fault diagnosis of the rotating machine. In this work, condition monitoring measurements using this advantage of thermography were proposed. From this study, the novel approach for the damage detection of a rotating machine was conducted based on the spectrum analysis. As results, by adopting the ball bearing used in the rotating machine applied extensively, an spectrum analysis with thermal imaging experiment was performed. Also, as analysing the temperature characteristics obtained from the infrared thermography for in-situ rotating ball bearing under the lubrication condition, it was concluded that infrared thermography for condition monitoring in the rotating machine at real time could be utilized in many industrial fields.