• Title/Summary/Keyword: Improved PD

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Performance Enhancement by Adaptation of Long Term Chronoamperometry in Direct Formic Acid Fuel Cell using Palladium Anode Catalyst

  • Kwon, Yong-Chai;Baik, S.M.;Han, Jong-Hee;Kim, Jin-Soo
    • Bulletin of the Korean Chemical Society
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    • v.33 no.8
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    • pp.2539-2545
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    • 2012
  • In the present study, we suggest a new way to reactivate performance of direct formic acid fuel cell (DFAFC) and explain its mechanism by employing electrochemical analyses like chronoamperometry (CA) and cyclic voltammogram (CV). For the evaluation of DFAFC performance, palladium (Pd) and platinum (Pt) are used as anode and cathode catalysts, respectively, and are applied to a Nafion membrane by catalyst-coated membrane spraying. After long DFAFC operation performed at 0.2 and 0.4 V and then CV test, DFAFC performance is better than its initial performance. It is attributed to dissolution of anode Pd into $Pd^{2+}$. By characterizations like TEM, Z-potential, CV and electrochemical impedance spectroscopy, it is evaluated that such dissolved $Pd^{2+}$ ions lead to (1) increase in the electrochemically active surface by reduction in Pd particle size and its improved redistribution and (2) increment in the total oxidation charge by fast reaction rate of the Pd dissolution reaction.

Sinapic Acid Ameliorates REV-ERB α Modulated Mitochondrial Fission against MPTP-Induced Parkinson's Disease Model

  • Lee, Sang-Bin;Yang, Hyun Ok
    • Biomolecules & Therapeutics
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    • v.30 no.5
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    • pp.409-417
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    • 2022
  • Parkinson's disease (PD) is the second most common neurodegenerative disease worldwide, and accumulating evidence indicates that mitochondrial dysfunction is associated with progressive deterioration in PD patients. Previous studies have shown that sinapic acid has a neuroprotective effect, but its mechanisms of action remain unclear. The neuroprotective effect of sinapic acid was assayed in a PD mouse model generated by the neurotoxin 1-methyl-4-phenyl-1,2,3,6-tetrahydropyridine (MPTP) as well as in SH-SY5Y cells. Target protein expression was detected by western blotting. Sinapic acid treatment attenuated the behavioral defects and loss of dopaminergic neurons in the PD models. Sinapic acid also improved mitochondrial function in the PD models. MPTP treatment increased the abundance of mitochondrial fission proteins such as dynamin-related protein 1 (Drp1) and phospho-Drp1 Ser616. In addition, MPTP decreased the expression of the REV-ERB α protein. These changes were attenuated by sinapic acid treatment. We used the pharmacological REV-ERB α inhibitor SR8278 to confirmation of protective effect of sinapic acid. Treatment of SR8278 with sinapic acid reversed the protein expression of phospho-Drp1 Ser616 and REV-ERB α on MPTP-treated mice. Our findings demonstrated that sinapic acid protects against MPTP-induced PD and these effects might be related to the inhibiting abnormal mitochondrial fission through REV-ERB α.

Fuzzy PD Speed Controller for Permanent Magnet Synchronous Motors

  • Jung, Jin-Woo;Choi, Han-Ho;Kim, Tae-Heoung
    • Journal of Power Electronics
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    • v.11 no.6
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    • pp.819-823
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    • 2011
  • This paper presents a fuzzy PD speed control scheme for the robust speed tracking of a permanent magnet synchronous motor (PMSM). Motivated by the common control engineering knowledge that transient performance can be improved if the P gain is big and the D gain is small in the beginning, a linearizing control scheme with a fuzzy PD controller is proposed. The global system stability is analyzed and the proposed control algorithm is implemented using a TMS320F28335 DSP. Simulation and experimental results are given to verify the effectiveness of the proposed method.

Simulation on Electrical Properties of SiGe PD-SOI MOSFET for Improved Minority Carrier Conduction (소수운반자 전도 SiGe PD-SOI MOSFET의 전기적 특성에 대한 전산 모사)

  • Yang, Hyun-Deok;Choi, Sang-Sik;Han, Tae-Hyun;Cho, Deok-Ho;Kim, Jae-Yeon;Shim, Kyu-Hwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.21-22
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    • 2005
  • Partially-depleted Silicon on insulator metal-oxide-semiconductor field- effect transistors (PD-SOI MOSFETs) with Silicon-germanium (SiGe) layer is investigated. This structure uses SiGe layer to reduce the kink effect in the floating body region near the bottom channel/buried oxide interface. Among many design parameters influencing the performance of the device, Ge composition is presented most predominant effects, simulation results show that kink effect is reduced with increase the Ge composition. Because the bandgap of SiGe layer is reduced at higher Ge composition, the hole current between body and SiGe layer is enhanced.

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A Note on All Stabilizing PD Controllers for Continuous LTI Systems (연속선형계의 PD 안정화기의 전체 이득 셋 결정)

  • Kim, Keun-Sik;Kim, Young-C. Dattal
    • Proceedings of the KIEE Conference
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    • 2004.05a
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    • pp.10-12
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    • 2004
  • Recently, Datta at al. [1] have developed a metDattad of obtaining the complete set of stabilizing PI, PID controllers for a given LTI system, in which tDattase are determined by solving a set of linear inequalities parameterized by the proportional(P) gain. In this paper, we provide a note about Dattaw Datta's idea can be extended to the problem of finding all stabilizing PD controllers and about an improved metDattad that allows us to calculate the admissible range of P gain more rigorously. An illustrative example is given.

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Psychiatric Manifestation in Patients with Parkinson's Disease

  • Han, Ji Won;Ahn, Yebin D.;Kim, Won-Seok;Shin, Cheol Min;Jeong, Seong Jin;Song, Yoo Sung;Bae, Yun Jung;Kim, Jong-Min
    • Journal of Korean Medical Science
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    • v.33 no.47
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    • pp.300.1-300.17
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    • 2018
  • Parkinson's disease (PD) is the second most common neurodegenerative disorder. Although its major manifestation is motor symptoms, resulting from the loss of dopaminergic neurons in the substantia nigra, psychiatric symptoms, such as depression, anxiety, hallucination, delusion, apathy and anhedonia, impulsive and compulsive behaviors, and cognitive dysfunction, may also manifest in most patients with PD. Given that the quality of life - and the need for institutionalization - is so highly dependent on the psychiatric well-being of patients with PD, psychiatric symptoms are of high clinical significance. We reviewed the prevalence, risk factors, pathophysiology, and treatment of psychiatric symptoms to get a better understanding of PD for improved management.

Bimetallic Pd@Ni-mesoporous TiO2 nanocatalyst for highly improved and selective hydrogenation of carbonyl compounds under UV light radiation

  • Bathla, Aadil;Pal, Bonamali
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.486-496
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    • 2018
  • Bimetallic Pd@Ni nanostructure exhibited enhanced co-catalytic activity for the selective hydrogenation of benzaldehyde compare to their monometallic counterparts. Impregnation of these mono/bimetallic nanostructures on mesoporous $TiO_2$ leads to several surface modifications. The bimetallic PNT-3 ($Pd_3@Ni_1/mTiO_2$) exhibited large surface area ($212m^2g^{-1}$), and low recombination rate of the charge carriers ($e^--h^+$). The hydrogenation reaction was analyzed under controlled experiments. It was observed that under UV-light irradiations and saturated hydrogen atmosphere the bimetallic PNT-3 photocatalyst display higher rate constant $k=5.31{\times}10^{-1}h^{-1}$ owing to reduction in the barrier height which leads to efficiently transfer of electron at bimetallic/$mTiO_2$ interface.

Thermal Stability and the Effect of Substrate Temperature on the Structural and Magnetic Properties of Pd/Co Multilayer Films (Pd/Co 다층박막의 구조 및 자기적 특성에 미치는 기판온도 및 열적안정성에 관한 연구)

  • 허용철;김상록;이성래;김창수
    • Journal of the Korean Magnetics Society
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    • v.3 no.4
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    • pp.298-304
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    • 1993
  • The effects of the substrate temperature and the Pd underlayer on the structure and the magnetic properties of Pd/Co multilayer films prepared by the thermal evaporation were studied. As the substrate temperature increases up to $150^{\circ}C$, the crystallinity of sublayers, (111) texture and the interface sharpness of Pd/Co multilayers were improved due to the enhanced mobility of adatoms. As results of that, the perpendicular and surface anisotropy energies were increased but the coercivity was decreased because the pinning sites of domain wall decreased due to the grain growth. The grain size of the multilayers increased with Pd underlyer thickness. Thermal degradation was enhanced at above $200^{\circ}C$ due to interdiffusion at the Pd/Co interface. The intensity of the main diffraction peak rapidly decayed in the initial stage of aging and then decreased slowly. The rapid change of the intensity in the initial stage was speculated to be due to the structural relaxation phenomena and the later stage change was due to the interdiffusion. The activation energy for the interdiffusion in Pd4/Co1 multilayers was 14.9 KCal/mole.K.

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Effects of Breathing, Meditation and Qigong on the Impairable Dysfunction of Olfactory Sense in the Parkinson's Disease (파킨슨 병(PD)의 후각기능 장애에 대한 호흡 명상 기공 효과)

  • An, So Jung
    • Journal of Naturopathy
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    • v.9 no.2
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    • pp.37-45
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    • 2020
  • Purpose: Symptoms of idiopathic Parkinson's disease (PD) include tremors, bradykinesia, and rigidity. The purpose was to explore the effects of breathing, meditation and qigong on the improving of insight, behavior, mood discomfort, depression, anxiety, and olfactory dysfunction, which are PD non-motor symptoms. Methods: Three stages of An's-4444 healing breathing, An's Gwanjeong healing meditation, and healing qigong performed 12 times for 80 minutes at a time in subjects with PD (11 patients), and pre- and post-measurements compared and evaluated. Results: The Integrated Parkinson's Rating Scale (UPDRSI) for mood discomfort after 12 healings was 69%. The Depression Scale (61%) for HAMD, and 64% for Anxiety (HAMA)), and the smell identification test (TSI) for a trial for olfactory dysfunction, improved to 82%, respectively. However, the numerical values after one month after 12 healing were almost same in all four scales. This means that the healing effect maintained until after one month. Conclusions: An's healing breathing, meditation and qigong therapy significantly improved insight, behavior, and mood discomfort, and non-motor symptoms such as depression, anxiety, and olfactory dysfunction. These results suggest that An's breathing, meditation and qigong therapy are valuable as a primary therapy to improve and heal non-motor symptoms in Parkinson's disease patients. Further research in biomedical science is needed.

Improved Weighted-Collaborative Spectrum Sensing Scheme Using Clustering in the Cognitive Radio System (클러스터링 기반의 CR시스템에서 가중치 협력 스펙트럼 센싱 기술의 개선연구)

  • Choi, Gyu-Jin;Shon, Sung-Hwan;Lee, Joo-Kwan;Kim, Jae-Moung
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.7 no.6
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    • pp.101-109
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    • 2008
  • In this paper, we introduce clustering scheme to calculate probability of detection which is practically required for conventional weighted-collaborative sensing technique. We also propose an improved weighted-collaborative spectrum sensing scheme using new weight generation algorithm to achieve better performance in Cognitive Radio systems. We calculate Pd in each cluster which is a CR users group with similar channel situation. New weight factor is generated using square sum of all cluster's Pds. Simulations under slow fading show that we can get better total detection probability and lower false alarm rate when PU (Primary User) suddenly terminates their transmission.

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