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http://dx.doi.org/10.1016/j.jiec.2018.07.023

Bimetallic Pd@Ni-mesoporous TiO2 nanocatalyst for highly improved and selective hydrogenation of carbonyl compounds under UV light radiation  

Bathla, Aadil (School of Chemistry and Biochemistry, Thapar Institute of Engineering & Technology)
Pal, Bonamali (School of Chemistry and Biochemistry, Thapar Institute of Engineering & Technology)
Publication Information
Journal of Industrial and Engineering Chemistry / v.67, no., 2018 , pp. 486-496 More about this Journal
Abstract
Bimetallic Pd@Ni nanostructure exhibited enhanced co-catalytic activity for the selective hydrogenation of benzaldehyde compare to their monometallic counterparts. Impregnation of these mono/bimetallic nanostructures on mesoporous $TiO_2$ leads to several surface modifications. The bimetallic PNT-3 ($Pd_3@Ni_1/mTiO_2$) exhibited large surface area ($212m^2g^{-1}$), and low recombination rate of the charge carriers ($e^--h^+$). The hydrogenation reaction was analyzed under controlled experiments. It was observed that under UV-light irradiations and saturated hydrogen atmosphere the bimetallic PNT-3 photocatalyst display higher rate constant $k=5.31{\times}10^{-1}h^{-1}$ owing to reduction in the barrier height which leads to efficiently transfer of electron at bimetallic/$mTiO_2$ interface.
Keywords
Bimetallic-nanocatalyst; Co-catalytic activity; Mesoporous $TiO_2$; Pd@Ni/$mTiO_2$ nanocomposites; Photo-catalytic hydrogenation;
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1 A.-G. Boudjahem, A. Redjel, T. Mokrane, J. Ind. Eng. Chem. 18 (2012) 303.   DOI
2 B. Li, G.-S. Hu, L.-Y. Jin, X. Hong, J.-Q. Lu, M.-F. Luo, J. Ind. Eng. Chem. 19 (2013) 250.   DOI
3 H.-y. Jiang, S.-s. Zhang, B. Sun, Catal. Lett. 148 (2018) 1336.   DOI
4 R.L. Oliveira, C.S. Oliveira, R. Landers, C.R. Correia, ChemistrySelect 3 (2018) 535.   DOI
5 Y. Liu, Z. Wang, W. Fan, Z. Geng, L. Feng, Ceram. Int. 40 (2014) 3887.   DOI
6 D.K. Pallotti, L. Passoni, P. Maddalena, F. Di Fonzo, S. Lettieri, J. Phys. Chem. C 121 (2017) 9011.   DOI
7 N. Zhang, S. Liu, X. Fu, Y.-J. Xu, J. Phys. Chem. C 115 (2011) 9136.   DOI
8 J. Kaur, R. Singh, B. Pal, J. Mol. Catal. A 397 (2015) 99.   DOI
9 J. Prakash, P. Kumar, R. Harris, C. Swart, J. Neethling, A.J. van Vuuren, H. Swart, Nanotechnology 27 (2016) 355707.   DOI
10 S. De, J. Zhang, R. Luque, N. Yan, Energy Environ. Sci. 9 (2016) 3314.   DOI
11 C. Su, L. Liu, M. Zhang, Y. Zhang, C. Shao, CrystEngComm 14 (2012) 3989.   DOI
12 A.L. Luna, D. Dragoe, K. Wang, P. Beaunier, E. Kowalska, B. Ohtani, D. Bahena Uribe, M.A. Valenzuela, H. Remita, C. Colbeau-Justin, J. Phys. Chem. C 121 (2017) 14302.   DOI
13 N. Chen, D. Deng, Y. Li, X. Liu, X. Xing, X. Xiao, Y. Wang, Sci. Rep. 7 (2017) 7692.   DOI
14 R.A. Rather, D. Pooja, P. Kumar, S. Singh, B. Pal, J. Clean. Prod. 175 (2018) 394.   DOI
15 N. Perret, F. Cardenas-Lizana, M.A. Keane, Catal. Commun. 16 (2011) 159.   DOI
16 S. Flores, O. Rios-Bernij, M. Valenzuela, I. Cordova, R. Gomez, R. Gutierrez, Top. Catal. 44 (2007) 507.   DOI
17 S. Singh, R. Prajapat, R.A. Rather, B. Pal, Arab. J. Chem. (2018), doi:http://dx.doi.org/10.1016/j.arabjc.2018.04.002 (in press).   DOI
18 W.G. Menezes, B. Neumann, V. Zielasek, K. Thiel, M. Baumer, ChemPhysChem 14 (2013) 1577.   DOI
19 M. Han, H. Zhang, Y. Du, P. Yang, Z. Deng, React. Kinet. Mech. Catal. 102 (2010) 393.
20 M. Glatz, B. Stoger, D. Himmelbauer, L.F. Veiros, K. Kirchner, ACS Catal. 8 (2018) 4009.   DOI
21 R.M. Mironenko, O.B. Belskaya, T.I. Gulyaeva, M.V. Trenikhin, A.I. Nizovskii, A.V. Kalinkin, V.I. Bukhtiyarov, A.V. Lavrenov, V.A. Likholobov, Catal. Today 279 (2017) 2.   DOI
22 X. Jiang, N. Koizumi, X. Guo, C. Song, Appl. Catal. B 170 (2015) 173.
23 S. Fu, C. Zhu, Q. Shi, H. Xia, D. Du, Y. Lin, Nanoscale 8 (2016) 5076.   DOI
24 X. Fu, Y. Liu, W. Yao, Z. Wu, Catal. Commun. 83 (2016) 22.   DOI
25 L. Luo, Z. Duan, H. Li, J. Kim, G. Henkelman, R.M. Crooks, J. Am. Chem. Soc. 139 (2017) 5538.   DOI
26 J. Zhang, K. Gao, S. Wang, W. Li, Y. Han, RSC Adv. 7 (2017) 6447.   DOI
27 C.-H. Hao, X.-N. Guo, Y.-T. Pan, S. Chen, Z.-F. Jiao, H. Yang, X.-Y. Guo, J. Am. Chem. Soc. 138 (2016) 9361.   DOI
28 L. Fu, W. Cai, A. Wang, Y. Zheng, Mater. Lett. 142 (2015) 201.   DOI
29 R.A. Rather, S. Singh, B. Pal, Appl. Catal. B 213 (2017) 9.   DOI
30 P. Sharma, Y. Sasson, Green Chem. 19 (2017) 844.   DOI
31 R.A. Rather, S. Singh, B. Pal, J. Catal. 346 (2017) 1.   DOI
32 J. Archana, S. Harish, M. Sabarinathan, M. Navaneethan, S. Ponnusamy, C. Muthamizhchelvan, M. Shimomura, H. Ikeda, D. Aswal, Y. Hayakawa, RSC Adv. 6 (2016) 68092.   DOI
33 Z.-Q. Li, Y.-P. Que, L.-E. Mo, W.-C. Chen, Y. Ding, Y.-M. Ma, L. Jiang, L.-H. Hu, S.-Y. Dai, ACS Appl. Mater. Interfaces 7 (2015) 10928.   DOI
34 T. Sreethawong, S. Yoshikawa, Catal. Commun. 6 (2005) 661.   DOI
35 J. Xia, G. He, L. Zhang, X. Sun, X. Wang, Appl. Catal. B 180 (2016) 408.   DOI
36 Y. Ping, J. Zhang, T. Xing, G. Chen, R. Tao, K.-H. Choo, J. Ind. Eng. Chem. 58 (2018) 74.   DOI
37 S. Kang, K.S. Yoo, Y. Chung, Y. Kwon, J. Ind. Eng. Chem. 62 (2018) 329.   DOI
38 Q. Wu, C. Zhang, B. Zhang, X. Li, Z. Ying, T. Liu, W. Lin, Y. Yu, H. Cheng, F. Zhao, J. Colloid Interface Sci. 463 (2016) 75.   DOI
39 A. Bathla, B. Pal, ChemistrySelect 3 (2018) 4738.   DOI
40 L. Liu, F. Gao, P. Concepcion, A. Corma, J. Catal. 350 (2017) 218.   DOI
41 S. Rana, S.B. Jonnalagadda, RSC Adv. 7 (2017) 2869.   DOI
42 A. Monga, R.A. Rather, B. Pal, Sol. Energy Mater. Sol. Cells 172 (2017) 285.   DOI
43 P. Natarajan, H.A. Khan, S. Yoon, K.-D. Jung, J. Ind. Eng. Chem. 63 (2018) 380.   DOI
44 S. Cattaneo, S.J. Freakley, D.J. Morgan, M. Sankar, N. Dimitratos, G.J. Hutchings, Catal. Sci. Technol. 8 (2018) 1677.   DOI
45 A. Monga, A. Bathla, B. Pal, Sol. Energy 155 (2017) 1403.   DOI
46 L. Rout, A. Kumar, R.S. Dhaka, G.N. Reddy, S. Giri, P. Dash, Appl. Catal. A 538 (2017) 107.   DOI
47 C.-H. Liu, R.-H. Liu, Q.-J. Sun, J.-B. Chang, X. Gao, Y. Liu, S.-T. Lee, Z.-H. Kang, S.-D. Wang, Nanoscale 7 (2015) 6356.   DOI
48 A. Monga, B. Pal, Colloids Surf. A 481 (2015) 158.   DOI
49 Y. Chen, H. Lim, Q. Tang, Y. Gao, T. Sun, Q. Yan, Y. Yang, Appl. Catal. A 380 (2010) 55.   DOI
50 T. Jayesh, K. Itika, G.R. Babu, K.R. Rao, R. Keri, A.H. Jadhav, B. Nagaraja, Catal. Commun. 106 (2018) 73.   DOI