• Title/Summary/Keyword: Homogeneous Solution

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Miscibility of Branched Polycarbonate Blends with Poly(ethylene-co-1,4-dimethyl cyclohexane terephthalate) Copolyesters

  • Song, Jeong-Oh;Jeon, Mi-Young;Kim, Chang-Keun
    • Macromolecular Research
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    • v.15 no.7
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    • pp.640-645
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    • 2007
  • The phase behavior of branched polycarbonate (BPC) blends with poly(ethylene terephthalate-co-1,4-dimethyl cyclohexane terephthalate) copolyesters (PECT), as well as their rheological properties, were assessed. Even though BPC blends with PECT prepared by solvent casting proved to be immiscible, BPC and PECT copolyesters containing 1,4-dimethyl cyclohexane (CHDM) from 32 to 80 mole% formed homogeneous mixtures upon heating. The homogenization temperatures of the blends decreased with increasing CHDM content in PECT. The interaction energies of the BPC-PECT pairs calculated from the phase boundary in accordance with the lattice-fluid theory were positive and also decreased with increasing CHDM content in PECT. It was shown that the phase homogenization of these blends occurs upon heating when the combinatorial entropy term, which is favorable for miscibility, overcomes unfavorable energetic terms at elevated temperatures. A novel product, which is not limited by the drawbacks of linear polycarbonate (PC) and evidences processability superior to that of the PC/PECT blends, can be developed via the blending of BPC and PECT.

3-D Axisymmetric Fluid-Structure-Soil Interaction Analysis Using Mixed-Fluid-Element and Infinite-Element (혼합형 유체요소와 무한요소를 이용한 3차원 축대칭 유체-구조물-지반 상호작용해석)

  • 김재민;장수혁;윤정방
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 1999.10a
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    • pp.257-266
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    • 1999
  • This paper presents a method of seismic analysis for a cylindrical liquid storage structure on/in horizontally layered half.space considering the effects of the interior fluid and exterior soil medium in the frequency domain. To capture the essence of fluid-structure-soil interaction effects effectively, a mixed finite element with two-field (u, p) approximation is employed to model the compressive inviscid fluid, while the structure and soil medium are presented by the 3-D axisymmetric finite elements and dynamic infinite elements. The present FE-based method can be applied to the system with complex geometry of fluid region as well as with inhomogeneous near-field soil medium, since it can directly model both the fluid and the soil. For the purpose of verification, dominant peak frequencies in transfer functions for horizontal motions of cylindrical fluid storage tanks with rigid massless foundation on a homogeneous viscoelastic half.space are compared with those by two different added mass approaches for the fluid motion. The comparison indicates that the Present FE-based methodology gives accurate solution for the fluid-structure-soil interaction problem. Finally, as a demonstration of versatility of the present study, a seismic analysis for a real-scale LNG storage tank embedded in layered half.space is carried out, and its member forces along the height of the structure are compared with those by an added mass approach developed by the present writers.

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Monetary Policy Independence and Bond Yield in Developing Countries

  • ANWAR, Cep Jandi;SUHENDRA, Indra
    • The Journal of Asian Finance, Economics and Business
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    • v.7 no.11
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    • pp.23-31
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    • 2020
  • This paper investigates the impact of monetary policy independence shock on bond yield by allowing for heterogeneous coefficients in the model based on panel data for 19 developing countries using quarterly data from 1991 to 2016. First, we estimate the model using conventional panel VAR estimation with the assumption of homogeneous coefficients across countries. Second, by performing Chow and Roy-Zellner tests to check the homogeneity assumption, we find that the assumption does not hold in the model. Third, we apply a mean-group estimation for panel VAR as a solution for heterogeneity panel model. The results reveal that central bank independence is effective in reducing bond yield with the maximum at period 6 after the shock. Shock one standard deviation bond yield has a negative effect on consumption and investment. We determine that central bank independence has a contradictory effect on real activity; a negative effect on consumption but a positive influence on investment for the first two years after the shock. Additionally, we split our sample into three groups to make the subgroups pool. Our empirical result shows that monetary policy independence shock reduces bond yield. Meanwhile, the response of economic activity to bond yield varies for all three groups.

A 2-D Model for the Potential Distribution and Threshold Voltage of Fully Depleted Short-Channel Ion-Implanted Silicon MESFET's

  • Jit, S.;Morarka, Saurabh;Mishra, Saurabh
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.5 no.3
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    • pp.173-181
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    • 2005
  • A new two dimensional (2-D) model for the potential distribution of fully depleted short-channel ion-implanted silicon MESFET's has been presented in this paper. The solution of the 2-D Poisson's equation has been considered as the superposition of the solutions of 1-D Poisson's equation in the lateral direction and the 2-D homogeneous Laplace equation with suitable boundary conditions. The minimum bottom potential at the interface of the depletion region due to the metal-semiconductor junction at the Schottky gate and depletion region due to the substrate-channel junction has been used to investigate the drain-induced barrier lowering (DIBL) and its effects on the threshold voltage of the device. Numerical results have been presented for the potential distribution and threshold voltage for different parameters such as the channel length, drain-source voltage, and implanted-dose and silicon film thickness.

A New Approach for the Solution of Multi-Dimensional Neutron Kinetics Equations in LWR's (경수로에 대한 다차원 노심 동특성 방정식의 해를 구하기 위한 새로운 방법 개발)

  • Song, Jae-Woong;Kim, Jong-Kyung
    • Nuclear Engineering and Technology
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    • v.24 no.3
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    • pp.252-262
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    • 1992
  • The intent of this study is to develop an efficient calculation method which can be used to analyze the heterogeneous time-dependent reactor problems. By using the nodal theory one can not only reduce the calculational efforts, but accurately determine the group dependent flux densities averaged over the entire homogeneous nodes. This method uses correction factors(called“discontinuity factors”) in a rigorous manner to obtain the relationship between the node-averaged flux and the surface-averaged fluxes and currents. The discontinuity factors are calculated from the node-averaged fluxes, diffusion coefficients, and the discontinuity factors of the previous time step. The test results for two benchmark problems demonstrate the accuracy and efficiency of the method developed for the transient application in which assembly-size nodes can be used.

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An Estimation of Springing Responses for Recent Ships

  • Park In-Kyu;Lee Soo-Mok;Jung Jong-Jin;Yoon Myung-Cheol
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2004.11a
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    • pp.173-178
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    • 2004
  • The estimation of springing responses for recent ships are carried out and application to a ship design are described. To this aim, springing effects on hull girder were re-evaluated including non-linear wave excitations and torsional vibrations of the hull. The Timoshenko beam model was used to calculate stress distribution on the hull girder by the superposition method. The strip method was employed to calculate the hydrodynamic forces and moments on the hull. In order to remove the irregular frequencies, we adopted 'rigid lid' on the hull free surface level and added asymptotic interpolation along the high frequency range. Several applications to the existing ships were carried out. They are Bishop and Price's container ship, S-175 container ship, large container, VLCC and ore carrier. One of them is compared with ship measurement result while another with that of model test. Comparison between analytical solution and numerical one for homogeneous beam type artificial ship shows good agreement. It is found that most springing energy came from high frequency waves for the ships having low natural frequency and North Atlantic route etc. Therefore, the high frequency tail of the wave spectrum should be increased by $\omega^{-3}\;instead\;of\;\omega^{-4}\;or\;\omega^{-5}$ for springing calculation.

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Effects of Coating Conditions on the Thickness and Morphology of Alumina- or Carbon-Coated Layers on SiC Whiskers (알루미나 또는 카본 코팅 SiC 휘스커의 코팅층 두께 및 형상에 미치는 코팅조건의 영향)

  • 배인경;장병국;조원승;최상욱
    • Journal of the Korean Ceramic Society
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    • v.36 no.5
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    • pp.513-520
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    • 1999
  • Alumina-coated SiC whiskers wee prepared by the calcination (1150$^{\circ}C$, 1h, Ar) of the alumina hydrate layer which was precipitated homogeneously on whisker surface from a solution of Al2(SO4)3 and urea as a precipitant. In addition carbon coated SiC whiskers were prepared by the pyrolysis (1000$^{\circ}C$, 4h Ar) of phenolic resin coated whisker. The effects of coating conditions on the thickness and morphology of the coated layers were examined by SEM and TEM. It was found that Al2O3-coating layers become thinner and more uniform with decreasing the Al2(SO4)3 concentration. Thin (0.075-0.1$\mu\textrm{m}$) and uniformly alumina-coating layers were obtained at the Al2(SO4)3 concentration 0.010mol/l. On the other han carbon-coating layers were uniform but very thin (5-16 nm) in thickness. For thicker carbon-coating layers ethanol as a disperse medium was found to be more efficient compared tousing acetone.

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A Study on the Dielectric Properties of $SrTiO_3$ Sintered Body Synthesized by Oxalate Method (수산염법으로 합성한 $SrTiO_3$ 소결체의 유전특성에 관한 연구)

  • 김병호;이만규;김석우
    • Journal of the Korean Ceramic Society
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    • v.28 no.3
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    • pp.215-224
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    • 1991
  • The synthesis of SrTiO3 powders having high purity and homogeneous submicron particle size was attempted by the oxalate method. The microstructure and dielectric properties of SrTiO3 based boundary layer capacitor (BLC) were investigated. Strontium titanyl oxalate[SrTiO(C2O4)2.4H2O] was prepared from the mixing solution of (Sr, Ti) using oxalic acid(H2C2O4) as a precipitating agent at 8$0^{\circ}C$. The crystalline SrTiO3 powder was obtained by thermal decomposition of the precipitate above $600^{\circ}C$. The crystalline SrTiO3 powder containing Nb2O5 as a dopant, TiO2 and SiO2 as additives was sintered at 1360~144$0^{\circ}C$ in the reducing atmosphere to get semiconductive SrTiO3. Insulating material containing PbO-Bi2O3-B2O3 frit was printed on the sintered semiconductive SrTiO3 and fired at 120$0^{\circ}C$ for 2h to get the grain boundary diffusion.

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Electrical Properties of PZT/$BaTiO_3$/PZT Multilayer Thick Films (PZT/$BaTiO_3$/PZT 다층 후막의 유전특성)

  • Nam, Sung-Pill;Lee, Sung-Gap;Bae, Seon-Gi;Lee, Young-Hie
    • Proceedings of the KIEE Conference
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    • 2006.10a
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    • pp.123-124
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    • 2006
  • The sandwiched PZT/$BaTiO_3$/PZT thick films were fabricated by two different methods thick films of the PZT by screen printing method on alumina substrateselectrodes with Pt, thin films of $BaTiO_3$ by the spin-coating method on the PZT thick films and once more thick films of the PZT by the screen printing method on the $BaTiO_3$ layer. The structural and the dielectric properties were investigated for effect of various stacking sequence of sol-gel prepared $BaTiO_3$ coating solution at interface of the PZT thick films, The insertion of BaTi03 interlayer yielded the PZT thick films with homogeneous and dense grain structure with the number of $BaTiO_3$ layers. The leakage current density of the $PZT/BaTiO_3-1$ film is less that $4.41{\times}10^{-9}A/cm^2$ at 5 V.

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Synthesis and Characterization of CdSe/CdS/N-Acetyl-L-Cysteine/Quercetin Nano-Composites and Their Antibacterial Performance

  • Wang, Kunjie;Li, Mingliang;Li, Hongxia;Guan, Feng;Zhang, Deyi;Feng, Huixia;Fan, Haiyan
    • Journal of the Korean Chemical Society
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    • v.59 no.2
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    • pp.136-141
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    • 2015
  • We have discovered that quercetin, once coated on the CdSe and CdSe-CdS quantum dots (QDs), becoming highly water soluble. In the present work, we have successfully synthesized CdSe/CdS/N-Acetyl-L-Cysteine(NAC)/Quercetin nano-composites in the aqueous solution. The products were characterized using UV-vis spectroscopy, X-ray powder diffraction, fluorescence spectroscopy, and Fourier transform infrared spectroscopy. The transmission electron microscopy (TEM) tests indicated that our nano-composite products are highly stable with homogeneous particle size and great monodispersity. Quercetin coated nano-composite CdSe/CdS/NAC/Quercetin showed different fluorescence behavior from that of CdSe/CdS/NAC. Most amazingly, the synthesized CdSe/CdS/NAC/Quercetin nano-composite exhibits strong antibacterial activity. The combination of the strong fluorescence and its antibacterial activity makes the quercetin modified quantum dots as a potential candidate for cancer targeted therapy and other cancer treatments.