• 공업화학
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• 제30권1호
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• pp.81-87
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• 2019

에너지화 열가소성 탄성체 제조에 사용될 수 있는 새로운 계열의 glycidyl azide polymer (GAP)을 모색하기 위해 전구체인 poly(epichlorohydrin) (PECH)에 친핵체인 아지드기와 알콕시 및 알킬 아민을 도입하여 4가지 GAP copolymer polyol을 합성하고 물성에 대하여 고찰하였다. 이 GAP copolymer 합성반응은 이종의 친핵체를 1단계 반응으로 동시에 치환하여 미반응 sodium azide가 남지 않는 친환경적이며 효율적인 합성법으로 평가할 수 있다. 역개폐 짝풀림(inverse gated decoupling) $^{13}C$ NMR 분석법과 Fourier transform infrared (FT-IR) 분석법으로 상대적 치환율을 정량적으로 분석하였으며 반응 진행도를 모니터링 하였다. 합성된 GAP copolymer의 유리전이온도와 분자량은 differential scanning calorimetry (DSC)와 gel permeation chromatography (GPC)로 분석하였다. 합성된 poly($GA_{0.8}-butoxide_{0.2}$), poly($GA_{0.7}-n-butylamine_{0.3}$), poly($GA_{0.7}-dipropylamine_{0.3}$), poly($GA_{0.7}-morpholine_{0.3}$)의 유리전이온도는 $-39^{\circ}C$에서 $-26^{\circ}C$ 범위의 값을 나타내었다.

• 한국고분자학회지:고분자과학과기술
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• 제15권3호
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• pp.317-326
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• 2004

광자 (photon)를 이용하여 정보의 전달, 표시, 감지 그리고 저장이 가능한 다양한 형태의 소자들은 현재 그 주를 이루고 있는 전자 (electron)가 매개인 소자를 대체할 수 있는 가능성을 가지고 활발히 연구되고 있다. 전자의 움직임은 재료 내에 주기적으로 배열되어 있는 원자나 분자의 결정구조에 의해 제어된다. 이는 전도밴드 (conduction band)와 원자가 밴드(valance band) 사이에 존재하는 전자 밴드갭 (electronic band gap)을 조절함으로써 가능하다. 이와 유사한 개념으로 광자의 움직임은 유전체의 주기적인 배열을 통해서 가능함이 제안되었다. 규칙적인 유전체의 결정구조를 가진 재료에 빛이 조사되었을 때, 그 재료를 통과하지 못하는 특정파장이 결정되며 이를 광자 밴드갭 (photonic band gap: PBG)이라 한다. (중략)

• 한국재료학회:학술대회논문집
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• 한국재료학회 2007년도 춘계학술발표대회 및 제12회 신소재 심포지엄
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• pp.29.1-29.1
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• 2007

• 한국진공학회:학술대회논문집
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• 한국진공학회 2010년도 제39회 하계학술대회 초록집
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• pp.261-261
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• 2010

Photonic band gap (PBG) materials have been of great interest due to their potential applications in science and technology. Their applications can be further extended when PBG becomes tunable against various chemical and electrical stimuli. In recent, it was found that tunable photonic band gap materials can be achieved by incorporating stimuli-responsive smart gels into PBG materials. For example, the characteristic volume phase transition of gels in response to the various external stimuli including temperature, pH, ionic strength, solvent compositions and electric field were recently combined with the unique optical properties of photonic crystals to form unprecedented highly responsive optical components. Since these responsive photonic crystals are capable of reversibly converting chemical or electrical energy into characteristic optical signals, they have been considered as a good platform for label-free chemical or biological detection, actuators or optical switches as well as a model system for investigating gel swelling behavior. Herein, we report block copolymer photonic gels self-assembled from polystyrene-b-poly (2-vinyl pyridine) (PS-b-P2VP) block copolymers. In this talk, we are going to demonstrate that selective swelling of lamellar structure can be effectively utilized for fabricating PBG materials with extremely large tunability. Optical properties and their applications will be discussed.

• 한국염색가공학회지
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• 제14권2호
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• pp.109-109
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• 2002

A study has been made of the dry-jet-wet spinning of PAN copolymer fibers using 60% aqueous zinc chloride solution as solvent and 25∼40% aqueous zinc chloride solution as non-solvent. The technological characteristics of this method were that small streams of dope were extruded from the die and allowed to pass through a short distance of air gap(about 10mm) before entering the spinning bath for full coagulation. This work showed the importances which coagulation condition, stretch ratio and fiber tenacity up to 10.5 g/d could be obtained with elongation of 11∼16%. Individual fibers were evaluated on the basis of density and mechanical properties such as tenacity and elongation etc.

• 한국염색가공학회지
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• 제14권2호
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• pp.33-39
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• 2002

A study has been made of the dry-jet-wet spinning of PAN copolymer fibers using 60% aqueous zinc chloride solution as solvent and 25∼40% aqueous zinc chloride solution as non-solvent. The technological characteristics of this method were that small streams of dope were extruded from the die and allowed to pass through a short distance of air gap(about 10mm) before entering the spinning bath for full coagulation. This work showed the importances which coagulation condition, stretch ratio and fiber tenacity up to 10.5 g/d could be obtained with elongation of 11∼16%. Individual fibers were evaluated on the basis of density and mechanical properties such as tenacity and elongation etc.

• 공업화학
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• 제31권3호
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• pp.284-290
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• 2020

Energetic thermoplastic elastomers (ETPEs) based on glycidyl azide polymer (GAP) and carboxylated GA copolymers [GAP-ETPE and poly(GA-carboxylate)-ETPEs] were synthesized using isophorone diisocyanate (IPDI), dibutyltin dilaurate (DBTDL), 1,4-butanediol (1,4-BD), and soft segment oligomers such as GAP and poly(GA-carboxylate). The synthesized GAP-ETPE and poly(GA-carboxylate)-ETPEs were characterized by Fourier transform infrared (FT-IR), gel permeation chromatography (GPC), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), universal testing machine (UTM), calorimetry and sensitivity towards friction and impact. DSC and TGA results showed that the introduction of carboxylate group in GAP helped to have better thermal properties. Glass transition temperatures of poly(GA-carboxylate)-ETPEs decreased from -31 ℃ to -33 ℃ compared to that of GAP-ETPE (-29 ℃). The first thermal decomposition temperature in poly(GA_0.8-octanoate_0.2)-ETPE (242 ℃) increased in comparison to that of GAP-ETPE (227 ℃). Furthermore, from calorimetry data, poly(GA-carboxylate)-ETPEs exhibited negative formation enthalpies (-6.94 and -7.21 kJ/g) and higher heats of combustion (46713 and 46587 kJ/mol) compared to that of GAP-ETPE (42,262 kJ/mol). Overall, poly(GA-carboxylate)-ETPEs could be good candidates for a polymeric binder in solid propellant due to better energetic, mechanical and thermal properties in comparison to those of GAP-ETPE. Such properties are beneficial to application and processing of ETPE.

• Bulletin of the Korean Chemical Society
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• 제30권4호
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• pp.951-954
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• 2009

• 공업화학
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• 제30권6호
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• pp.673-680
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• 2019

GAP 및 GAP-co-BO계 에너지 함유 열가소성 탄성체(ETPE)의 하드세그먼트 함량을 30~45% 범위에서 변화시켜 합성하여 열적 특성 및 기계적 특성을 비교 연구하여 고찰하였다. FTIR 분석 결과로부터 GAP-co-BO계 ETPE와 GAP계 ETPE는 하드세그먼트 함량이 증가함에 따라 수소결합을 형성하는 능력이 증가하였으며 GAP-co-BO계 ETPE의 수소 결합 능력이 GAP계 ETPE보다 크게 나타났다. DSC와 DMA 분석 결과로부터 GAP계 ETPE의 유리전이온도(T_g)는 하드세그먼트 함량이 증가함에 따라 증가하였으나, GAP-co-BO계 ETPE의 유리전이온도(T_g)는 하드세그먼트가 증가하여도 유사한 값을 유지하였다. 상온 storage modulus는 GAP-co-BO계 ETPE의 값이 GAP계 ETPE 값보다 더 크게 나타났다. 이러한 거동은 GAP-co-BO계 ETPE 내의 하드세그먼트와 소프트세그먼트의 강한 상분리 거동의 결과로 볼 수 있다. 그 결과 GAP-co-BO계 ETPE는 GAP계 ETPE보다 더 큰 파단강도와 더 낮은 파단신율 값을 나타냈다.

• 한국염색가공학회지
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• 제34권1호
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• pp.27-37
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• 2022

In this study, a study and interpretation of the spinning process in copolymerized aramid spinning was conducted. In order to proceed with the spinning process modeling and analysis, the spinning process was modeled through the physical property modeling of the spinning solution and the structural modeling of the spinneret, and structural stability and flow of the spinneret for this spinning were analyzed. After modeling the spinning solution and the spinneret in a virtual space, the pack pressure and flow rate when the spinning solution was discharged were simulated. Macroscopically, the structural stability of the spinneret was confirmed at the standard pack pressure (100 kg·f/cm²), and microscopically, the flow rate and pressure drop data of the spinning solution according to the L/D(Length (L)/Diameter (D)) value were analyzed. Based on the research and development of virtual engineering modeling and analysis, we present the possibility of changing the shape and mechanical properties of copolymer aramid fibers according to the spinning process.