• Applied Chemistry for Engineering
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• v.32 no.3
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• pp.243-252
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• 2021

With increasingly strict requirements for advanced energy storage devices in electric vehicles (EVs) and stationary energy storage systems (EES), the development of lithium-ion batteries (LIBs) with high power density and safety has become an urgent task. Because the performance of LIBs is determined primarily by the physicochemical characteristics of its electrode material, TiO₂, owing to its excellent stability, high safety levels, and environmentally friendly properties, has received significant attention as an alternative material for the replacement of commercial carbon-based anode materials. In particular, self-organized TiO₂ micro and nanostructures prepared by anodization have been intensively investigated as promising anode materials. In this review, the mechanism for the formation of anodic TiO₂ nanotubes and microcones and the parameters that influence their morphology are described. Furthermore, recent developments in anodic TiO₂-based composites as anode electrodes for LIBs to overcome the limitations of low conductivity and specific capacity are summarized.

• Journal of Electrochemical Science and Technology
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• v.12 no.4
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• pp.458-464
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• 2021

Lithium ion batteries (LIBs) is a kind of rechargeable secondary battery, developed from lithium battery, lithium ions move between the positive and negative electrodes to realize the charging and discharging of external circuits. Zeolitic imidazolate frameworks (ZIFs) are porous crystalline materials in which organic imidazole esters are cross-linked to transition metals to form a framework structure. In this article, ZIF-67 is used as a sacrificial template to prepare nano porous carbon (NPC) coated cobalt nanoparticles. The final product Co/NPC composites with complete structure, regular morphology and uniform size were obtained by this method. The conductive network of cobalt and nitrogen doped carbon can shorten the lithium ion transport path and present high conductivity. In addition, amorphous carbon has more pores that can be fully in contact with the electrolyte during charging and discharging. At the same time, it also reduces the volume expansion during the cycle and slows down the rate of capacity attenuation caused by structure collapse. Co/NPC composites first discharge specific capacity up to 3115 mA h/g, under the current density of 200 mA/g, circular 200 reversible capacity as high as 751.1 mA h/g, and the excellent rate and resistance performance. The experimental results show that the Co/NPC composite material improves the electrical conductivity and electrochemical properties of the electrode. The cobalt based ZIF-67 as the precursor has opened the way for the design of highly performance electrodes for energy storage and electrochemical catalysis.

• Journal of the Korean Electrochemical Society
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• v.25 no.1
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• pp.22-31
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• 2022

Carbon nanomaterials are considered to be the materials of choice for the fabrication of electrochemical energy storage devices due to their stability, cost-effectiveness, well-established processing techniques, and superior performance compared to other active materials. In the present work, reduced graphene oxide (rGO) has been synthesized and used for the fabrication of a symmetric supercapacitor. The electrochemical performance of the fabricated supercapacitors with three different aqueous electrolytes namely 0.5 M H₂SO₄, 0.5 M H₃PO₄, and 1.0M Na₂SO₄ have been compared and analyzed. Among the three electrolytes, the highest areal specific capacitance of 14 mF/cm² was calculated at a scan rate of 5 mV/s observed with 0.5M H₃PO₄ electrolyte. The results were also confirmed from the charge/discharge results where the supercapacitor with 0.5M H₃PO₄ electrolyte delivered a specific capacitance of 11 mF/cm² at a current density of 0.16 mA/cm². In order to assess the stability of the supercapacitor with different electrolytes, the cells were subjected to continuous charge/discharge cycling and it was observed that acidic electrolytes showed excellent cyclic stability with no appreciable drop in specific capacitance as compared to the neutral electrolyte.

• Advances in nano research
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• v.15 no.1
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• pp.59-65
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• 2023

In this present article, the mechanical behavior of single-walled black phosphorene nanotubes (SW-αPNTs) is simulated using molecular dynamics (MD). The proposed model is subjected to the axial loading and the effects of morphological parameters, such as the mono-vacancy defect and strain rate on the tensile behavior of the zigzag and armchair SW-αPNTs are studied as a pioneering work. In order to assess the accuracy of the MD simulations, the stress-strain response of the current MD model is successfully verified with the efficient quantum mechanical approach of the density functional theory (DFT). Along with reproducing the DFT results, the accurate MD simulations successfully anticipate a significant variation in the stress-strain curve of the zigzag SW-αPNTs, namely the knick point. Predicting such mechanical behavior of SW-αPNTs may be an important design factor for lithium-ion batteries, supercapacitors, and energy storage devices. The simulations show that the ultimate stress is increased by increasing the diameter of the pristine SW-αPNTs. The trend is identical for the ultimate strain and stress-strain slope as the diameter of the pristine zigzag SW-αPNTs enlarges. The obtained results denote that by increasing the strain rate, the ultimate stress/ultimate strain are respectively increased/declined. The stress-strain slope keeps increasing as the strain rate grows. It is worth noting that the existence of mono-atomic vacancy defects in the (12,0) zigzag and (0,10) armchair SW-αPNT structures leads to a drop in the tensile strength by amounts of 11.1% and 12.5%, respectively. Also, the ultimate strain is considerably altered by mono-atomic vacancy defects.

• Nuclear Engineering and Technology
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• v.26 no.1
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• pp.19-31
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• 1994

The objective of this study is to conduct a thermal-hydraulic analysis on the spent fuel pool and to evaluate a parametric effect for the thermal-hydraulic analysis of spent fuel pool. The selected parameters are the Reynolds Number and the gap flow through the oater gap between fuel cell and fuel bundle. The simplified flow network for a path of fuel cells is used to analyze the natural circulation phenomenon. In the flow network analysis, the pressure drop for each assembly from the entrance of the fuel rack to the exit of the fuel assembly is balanced by the driving head due to the density difference between the pool fluid and the average fluid in each spent fuel assembly. The governing equations ore developed using this relation. But, since the parameters(flow rate, pressure loss coefficient, decay heat, density)are coupled each other, iteration method is used to obtain the solution. For the analysis of the YGN 3&4 spent fuel rack, 12 channels are considered and the inputs such as decay heat and pressure loss coefficient are determined conservatively. The results show the thermal-hydraulic characteristics(void fraction, density, boiling height)of the YGN 3&4 spent fuel rack. There occurs small amount of boiling in the cells. Fuel cladding temperature is lower than 343.3$^{\circ}C$. The evaluation of parametric effect indicates that flow resistances by geometric effect are very sensitive to Reynolds number in the transition region and the gap flow is negligible because of the larger flow resistance in the gap flow path than in the fuel bundle.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2003.05a
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• pp.366-369
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• 2003

High T$_{c}$ superconducting lines will be applied as key materials in the areas of power transmission line; magnetic levitation of vehicle; magnetic separation; magnetic energy storage and marine propulsion. A combination method of electrophoresis deposition and zone-melting for preparation of YBaCuO tape is proposed. The submicron particle powder of YBaCuO made by sol-gel method is used in the electrophoresis process. A 40~50${\mu}{\textrm}{m}$ thickness of YBaCuO film on Ag plate could be deposited in about three minutes. After deposition the film is rolled and heat treated in order to increase the density and the adhesion of the film to the Ag plate. Silver(Ag) and lead oxide(PbO) were added in the YBaCuO powder in order to reduce its melting point. The YBaCuO coating with controlled Ag and PbO contents was preliminarily zone-melted at about 945$^{\circ}C$.>.

• Proceedings of the KIPE Conference
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• 2011.07a
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• pp.253-254
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• 2011

본 논문에서는 고 전력밀도 및 저가형으로 구성 가능한 새로운 구조의 계통 연계형 태양광 인버터 시스템을 제안한다. 제안 시스템은 태양전지의 최대 전력점 추종기능과 배터리의 충 방전 기능을 단일 전력단으로 구성함으로써, 고 전력밀도 및 저가격형 시스템 구성이 가능하다. 또한, 제안 시스템은 배터리를 링크 캐패시터에 직렬 연결함으로써 링크 캐패시터의 전압 스트레스를 배터리 전압만큼 저감할 수 있으므로 가격저감 효과가 크다. 최종적으로 제안 시스템의 우수성과 신뢰성 검증을 위하여 1.5kW급 태양광 인버터 시스템의 시작품을 제작하였고, 이를 이용한 실험결과를 바탕으로 제안 시스템의 타당성을 검증한다.

• IEMEK Journal of Embedded Systems and Applications
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• v.7 no.4
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• pp.201-207
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• 2012

Currently, NAND Flash memory has been widely used in consumer storage devices due to its non-volatility, stability, economical feasibility, low power usage, durability, and high density. However, a high capacity of NAND flash memory causes the high power consumption and the low performance. In the convention memory research, a hierarchical filter mechanism can archive an effective performance improvement in terms of the power consumption. In order to attain the best filter structure for NAND flash memory, we selected a direct-mapped filter, a victim filter, a fully associative filter and a 4-way set associative filter for comparison in the performance analysis. According to the results of the simulation, the fully associative filter buffer with a 128byte fetching size can obtain the bet performance compared to another filter structures, and it can reduce the energy*delay product(EDP) by about 93% compared to the conventional NAND Flash memory.

• Bulletin of the Korean Chemical Society
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• v.34 no.12
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• pp.3722-3726
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• 2013

Covalent functionalization of a $Zn_{12}O_{12}$ nano-cage with $CO_2$ molecule in terms of energetic, geometry, and electronic properties was investigated by density functional theory method. For chemisorption configurations, the adsorption energy of $CO_2$ on the $Zn_{12}O_{12}$ nano-cage for the first $CO_2$ was calculated -1.25 eV with a charge transfer of 1.00|e| from the nano-cage to the $CO_2$ molecule. The results show that $CO_2$ molecule was significantly detected by pristine $Zn_{12}O_{12}$ nano-cage, therefore the nano-cage can be used as $CO_2$ storage. Also, more efficient binding could not be achieved by increasing the $CO_2$ concentration. For Physisorption configurations, HOMO-LUMO gap of the configurations has not changed, while slight changes have been observed in the chemisorption configurations.

• Journal of Magnetics
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• v.19 no.3
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• pp.237-240
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• 2014

For heat-assisted magnetic recording, magnetization reversal probabilities of nano-Pt/MnSb multilayer film with perpendicular magnetic anisotropy under thermal pulse activation were investigated numerically by solving the Landau-Lifshift Gilbert Equation. Magnetic parameters of nano-Pt/MnSb multilayer were used with anisotropy energy of $3{\times}10^5$ erg/cc and saturation magnetization of 2100 G, which offer more than 10 y data stability at room temperature. Scheme of driven magnetic field and thermal pulse on writing mechanism was designed closely to real experiment. This study found that the chosen material is potential to be used as a high density magnetic storage that requires low writing field less than two-hundreds Oersted through definite heating and cooling interval. The possibility of writing data with a zero driven magnetic field also became an important result. Further study is recommended on the thickness of media and thermal pulse design as the essential parameters of the reversal magnetization.