Acknowledgement
This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (2020R1I1A1A01064020).
References
- M. Madian, A. Eychmuller, and L. Giebeler, Current advances in TiO2-based nanostructure electrodes for high performance lithium ion batteries, Batteries, 4, 7 (2018). https://doi.org/10.3390/batteries4010007
- B. Scrosati and J. Garche, Lithium batteries: Status, prospects and future, J. Power Sources, 195, 2419-2430 (2010). https://doi.org/10.1016/j.jpowsour.2009.11.048
- X. Zuo, J. Zhu, P. Muller-Buschbaum and Y.-J. Cheng, Silicon based lithium-ion battery anodes: A chronicle perspective review, Nano Energy, 31, 113-143 (2017). https://doi.org/10.1016/j.nanoen.2016.11.013
- M. S. Whittingham, Lithium batteries and cathode materials, Chem. Rev., 104, 4271-4302 (2004). https://doi.org/10.1021/cr020731c
- J. W. Fergus, Recent developments in cathode materials for lithium ion batteries, J. Power Sources, 195, 939-954 (2010). https://doi.org/10.1016/j.jpowsour.2009.08.089
- J. Islam, F. I. Chowdhury, J. Uddin, R. Amin, and J. Uddin, Review on carbonaceous materials and metal composites in deformable electrodes for flexible lithium-ion batteries, RSC Adv., 11, 5958-5992 (2021). https://doi.org/10.1039/D0RA10229F
- C. Wang, A. J. Appleby, and F. E. Little, Charge-discharge stability of graphite anodes for lithium-ion batteries, J. Electroanal. Chem., 497, 33-46 (2001). https://doi.org/10.1016/S0022-0728(00)00447-2
- Y. Wu, C. Jiang, C. Wan, and E. Tsuchida, Effects of catalytic oxidation on the electrochemical performance of common natural graphite as an anode material for lithium ion batteries, Electrochem. Commun., 2, 272-275 (2000). https://doi.org/10.1016/S1388-2481(00)00022-9
- C. Uhlmann, J. Illig, M. Ender, R. Schuster, and E. Ivers-Tiffee, In situ detection of lithium metal plating on graphite in experimental cells, J. Power Sources, 279, 428-438 (2015). https://doi.org/10.1016/j.jpowsour.2015.01.046
- C. Zhang, S. Liu, Y. Qi, F. Cui, and X. Yang, Conformal carbon coated TiO2 aerogel as superior anode for lithium-ion batteries, Chem. Eng. J., 351, 825-831 (2018). https://doi.org/10.1016/j.cej.2018.06.125
- D. P. Opra, S. V. Gnedenkov, and S. L. Sinebryukhov, Recent efforts in design of TiO2 (B) anodes for high-rate lithium-ion batteries: A review, J. Power Sources, 442, 227225 (2019). https://doi.org/10.1016/j.jpowsour.2019.227225
- Z. Weng, H. Guo, X. Liu, S. Wu, K. Yeung, and P.K. Chu, Nanostructured TiO2 for energy conversion and storage, RSC Adv., 3, 24758-24775 (2013). https://doi.org/10.1039/c3ra44031a
- C. Huang, S.-X. Zhao, H. Peng, Y.-H. Lin, C.-W. Nan, and G.-Z. Cao, Hierarchical porous Li4Ti5O12-TiO2 composite anode materials with pseudocapacitive effect for high-rate and low-temperature applications, J. Mater. Chem. A, 6, 14339-14351 (2018). https://doi.org/10.1039/C8TA03172J
- Y. Wang, Y.-x. Zhang, W.-J. Yang, S. Jiang, X.-w. Hou, R. Guo, W. Liu, P. Huang, J. Lu, and H.-t. Gu, Enhanced rate performance of Li4Ti4O12 anode for advanced lithium batteries, J. Electrochem. Soc., 166, A5014 (2018). https://doi.org/10.1149/2.0041903jes
- S. Wang, P.-K. Lee, X. Yang, A. L. Rogach, A. R. Armstrong, and Y. Denis, Polyimide-cellulose interaction in Sb anode enables fast charging lithium-ion battery application, Mater. Today Energy, 9, 295-302 (2018). https://doi.org/10.1016/j.mtener.2018.06.007
- Z. F. Yin, L. Wu, H. G. Yang, and Y. H. Su, Recent progress in biomedical applications of titanium dioxide, PCCP, 15, 4844-4858 (2013). https://doi.org/10.1039/c3cp43938k
- F. Dachille, P. Simons, and R. Roy, Pressure-temperature studies of anatase, brookite, rutile and TiO2-II, Am. Min., 53, 1929-1939 (1968).
- R. van de Krol, A. Goossens, and J. Schoonman, Spatial extent of lithium intercalation in anatase TiO2, J. Phys. Chem. B, 103, 7151-7159 (1999). https://doi.org/10.1021/jp9909964
- H. Zhang and J. F. Banfield, Structural characteristics and mechanical and thermodynamic properties of nanocrystalline TiO2, Chem. Rev., 114, 9613-9644 (2014). https://doi.org/10.1021/cr500072j
- J. Macak, F. Schmidt-Stein, and P. Schmuki, Efficient oxygen reduction on layers of ordered TiO2 nanotubes loaded with Au nanoparticles, Electrochem. Commun., 9, 1783-1787 (2007). https://doi.org/10.1016/j.elecom.2007.04.002
- C. Bae, H. Yoo, S. Kim, K. Lee, J. Kim, M. M. Sung and H. Shin, Template-directed synthesis of oxide nanotubes: Fabrication, characterization, and applications, Chem. Mater., 20, 756-767 (2008). https://doi.org/10.1021/cm702138c
- M. G. Choi, Y.-G. Lee, S.-W. Song, and K. M. Kim, Lithium-ion battery anode properties of TiO2 nanotubes prepared by the hydrothermal synthesis of mixed (anatase and rutile) particles, Electrochim. Acta, 55, 5975-5983 (2010). https://doi.org/10.1016/j.electacta.2010.05.052
- S. Ribbens, V. Meynen, G. Van Tendeloo, X. Ke, M. Mertens, B. Maes, P. Cool, and E. Vansant, Development of photocatalytic efficient Ti-based nanotubes and nanoribbons by conventional and microwave assisted synthesis strategies, Microporous Mesoporous Mater., 114, 401-409 (2008). https://doi.org/10.1016/j.micromeso.2008.01.028
- L. B. Arruda, C. M. Santos, M. O. Orlandi, W. H. Schreiner, and P. N. Lisboa-Filho, Formation and evolution of TiO2 nanotubes in alkaline synthesis, Ceram. Int., 41, 2884-2891 (2015). https://doi.org/10.1016/j.ceramint.2014.10.113
- H. Tsuchiya, J. M. Macak, I. Sieber, and P. Schmuki, Self-organized high-aspect-ratio nanoporous zirconium oxides prepared by electrochemical anodization, Small, 1, 722-725 (2005). https://doi.org/10.1002/smll.200400163
- V. Zwilling, E. Darque-Ceretti, A. Boutry-Forveille, D. David, M.-Y. Perrin, and M. Aucouturier, Structure and physicochemistry of anodic oxide films on titanium and TA6V alloy, Surf. Interface Anal., 27, 629-637 (1999). https://doi.org/10.1002/(SICI)1096-9918(199907)27:7<629::AID-SIA551>3.0.CO;2-0
- D. Gong, C. A. Grimes, O. K. Varghese, W. Hu, R. Singh, Z. Chen, and E. C. Dickey, Titanium oxide nanotube arrays prepared by anodic oxidation, J. Mater. Res., 16, 3331-3334 (2001). https://doi.org/10.1557/JMR.2001.0457
- D.-J. Yang, H.-G. Kim, S.-J. Cho, and W.-Y. Choi, Thickness-conversion ratio from titanium to TiO2 nanotube fabricated by anodization method, Mater. Lett., 62, 775-779 (2008). https://doi.org/10.1016/j.matlet.2007.06.058
- H. Tsuchiya, J. M. Macak, L. Taveira, E. Balaur, A. Ghicov, K. Sirotna, and P. Schmuki, Self-organized TiO2 nanotubes prepared in ammonium fluoride containing acetic acid electrolytes, Electrochem. Commun., 7, 576-580 (2005). https://doi.org/10.1016/j.elecom.2005.04.008
- H. Tsuchiya, J. M. Macak, A. Ghicov, L. Taveira, and P. Schmuki, Self-organized porous TiO2 and ZrO2 produced by anodization, Corros. Sci., 47, 3324-3335 (2005). https://doi.org/10.1016/j.corsci.2005.05.041
- Y. Li, Q. Ma, J. Han, L. Ji, J. Wang, J. Chen, and Y. Wang, Controllable preparation, growth mechanism and the properties research of TiO2 nanotube arrays, Appl. Surf. Sci., 297, 103-108 (2014). https://doi.org/10.1016/j.apsusc.2014.01.086
- S. Sreekantan, K. A. Saharudin, and L. C. Wei, Formation of TiO2 nanotubes via anodization and potential applications for photo-catalysts, biomedical materials, and photoelectrochemical cell, IOP Conf. Ser. Mater. Sci. Eng., IOP Publishing, pp. 012002 (2011).
- D. Regonini, C. R. Bowen, A. Jaroenworaluck, and R. Stevens, A review of growth mechanism, structure and crystallinity of anodized TiO2 nanotubes, Mater. Sci. Eng. R Rep., 74, 377-406 (2013). https://doi.org/10.1016/j.mser.2013.10.001
- M. Lohrengel, Thin anodic oxide layers on aluminium and other valve metals: High field regime, Mater. Sci. Eng. R Rep., 11, 243-294 (1993). https://doi.org/10.1016/0927-796X(93)90005-N
- A. Jaroenworaluck, D. Regonini, C. R. Bowen, R. Stevens, and D. Allsopp, Macro, micro and nanostructure of TiO2 anodised films prepared in a fluorine-containing electrolyte, J. Mater. Sci., 42, 6729-6734 (2007). https://doi.org/10.1007/s10853-006-1474-9
- H. Yoo, M. Kim, Y.-T. Kim, K. Lee, and J. Choi, Catalyst-doped anodic TiO2 nanotubes: Binder-free electrodes for (photo) electrochemical reactions, Catalysts, 8, 555 (2018). https://doi.org/10.3390/catal8110555
- G. Thompson, Porous anodic alumina: Fabrication, characterization and applications, Thin Solid Films, 297, 192-201 (1997). https://doi.org/10.1016/S0040-6090(96)09440-0
- S. Berger, S. P. Albu, F. Schmidt-Stein, H. Hildebrand, P. Schmuki, J. S. Hammond, D. F. Paul, and S. Reichlmaier, The origin for tubular growth of TiO2 nanotubes: A fluoride rich layer between tube-walls, Surf. Sci., 605, L57-L60 (2011). https://doi.org/10.1016/j.susc.2011.06.019
- S. Garcia-Vergara, P. Skeldon, G. Thompson, and H. Habazaki, A flow model of porous anodic film growth on aluminium, Electrochim. Acta, 52, 681-687 (2006). https://doi.org/10.1016/j.electacta.2006.05.054
- J. M. Macak, H. Tsuchiya, L. Taveira, S. Aldabergerova, and P. Schmuki, Smooth anodic TiO2 nanotubes, Angew. Chem. Int. Ed., 44, 7463-7465 (2005). https://doi.org/10.1002/anie.200502781
- H. Tsuchiya, J. M. Macak, A. Ghicov, A. S. Rader, L. Taveira, and P. Schmuki, Characterization of electronic properties of TiO2 nanotube films, Corros. Sci., 49, 203-210 (2007). https://doi.org/10.1016/j.corsci.2006.05.009
- T. Froschl, U. Hormann, P. Kubiak, G. Kucerova, M. Pfanzelt, C. K. Weiss, R. Behm, N. Husing, U. Kaiser, and K. Landfester, High surface area crystalline titanium dioxide: Potential and limits in electrochemical energy storage and catalysis, Chem. Soc. Rev., 41, 5313-5360 (2012). https://doi.org/10.1039/c2cs35013k
- R. Kirchgeorg, M. Kallert, N. Liu, R. Hahn, M. S. Killian, and P. Schmuki, Key factors for an improved lithium ion storage capacity of anodic TiO2 nanotubes, Electrochim. Acta, 198, 56-65 (2016). https://doi.org/10.1016/j.electacta.2016.03.009
- H. Han, T. Song, E.-K. Lee, A. Devadoss, Y. Jeon, J. Ha, Y.-C. Chung, Y.-M. Choi, Y.-G. Jung, and U. Paik, Dominant factors governing the rate capability of a TiO2 nanotube anode for high power lithium ion batteries, ACS Nano, 6, 8308-8315 (2012). https://doi.org/10.1021/nn303002u
- M. Wagemaker, W. J. Borghols, and F. M. Mulder, Large impact of particle size on insertion reactions. A case for anatase LixTiO2, J. Am. Chem. Soc., 129, 4323-4327 (2007). https://doi.org/10.1021/ja067733p
- S. Ivanov, L. Cheng, H. Wulfmeier, D. Albrecht, H. Fritze, and A. Bund, Electrochemical behavior of anodically obtained titania nanotubes in organic carbonate and ionic liquid based Li ion containing electrolytes, Electrochim. Acta, 104, 228-235 (2013). https://doi.org/10.1016/j.electacta.2013.04.115
- W.-H. Ryu, D.-H. Nam, Y.-S. Ko, R.-H. Kim, and H.-S. Kwon, Electrochemical performance of a smooth and highly ordered TiO2 nanotube electrode for Li-ion batteries, Electrochim. Acta, 61, 19-24 (2012). https://doi.org/10.1016/j.electacta.2011.11.042
- H.-T. Fang, M. Liu, D.-W. Wang, T. Sun, D.-S. Guan, F. Li, J. Zhou, T.-K. Sham, and H.-M. Cheng, Comparison of the rate capability of nanostructured amorphous and anatase TiO2 for lithium insertion using anodic TiO2 nanotube arrays, Nanotechnology, 20, 225701 (2009). https://doi.org/10.1088/0957-4484/20/22/225701
- J. Gao, G. Qiu, H. Li, M. Li, C. Li, L. Qian, and B. Yang, Boron-doped graphene/TiO2 nanotube-based aqueous lithium ion capacitors with high energy density, Electrochim. Acta, 329, 135175 (2020). https://doi.org/10.1016/j.electacta.2019.135175
- R. Menendez, P. Alvarez, C. Botas, F. Nacimiento, R. Alcantara, J. L. Tirado, and G. F. Ortiz, Self-organized amorphous titania nanotubes with deposited graphene film like a new heterostructured electrode for lithium ion batteries, J. Power Sources, 248, 886-893 (2014). https://doi.org/10.1016/j.jpowsour.2013.10.019
- N. y. Kim, G. Lee, and J. Choi, Fast-charging and high volumetric capacity anode based on Co3O4/CuO@ TiO2 composites for lithium-ion batteries, Chem. Eur. J., 24, 19045-19052 (2018). https://doi.org/10.1002/chem.201804313
- B. Heo, J. Ha, Y.-T. Kim, and J. Choi, 10 ㎛-thick MoO3-coated TiO2 nanotubes as a volume expansion regulated binder-free anode for lithium ion batteries, J. Ind. Eng. Chem., 96, 364-370 (2021). https://doi.org/10.1016/j.jiec.2021.05.003
- D. Kim, K. Lee, P. Roy, B. I. Birajdar, E. Spiecker, and P. Schmuki, Formation of a non-thickness-limited titanium dioxide mesosponge and its use in dye-sensitized solar cells, Angew. Chem., 121, 9490-9493 (2009). https://doi.org/10.1002/ange.200904455
- D. Kowalski, D. Kim, and P. Schmuki, TiO2 nanotubes, nanochannels and mesosponge: Self-organized formation and applications, Nano Today, 8, 235-264 (2013). https://doi.org/10.1016/j.nantod.2013.04.010
- O. Rhee, G. Lee, and J. Choi, Highly ordered TiO2 microcones with high rate performance for enhanced lithium-ion storage, ACS Appl. Mater. Interfaces, 8, 14558-14563 (2016). https://doi.org/10.1021/acsami.6b03099
- J. Park, G. Lee, and J. Choi, Key anodization factors for determining the formation of TiO2 microcones vs nanotubes, J. Electrochem. Soc., 164, D640 (2017). https://doi.org/10.1149/2.1601709jes
- D. Li, D. Chen, J. Wang, and P. Liang, Effect of acid solution, fluoride ions, anodic potential and time on the microstructure and electronic properties of self-ordered TiO2 nanotube arrays, Electrochim. Acta, 207, 152-163 (2016). https://doi.org/10.1016/j.electacta.2016.04.002
- J. M. Macak, H. Tsuchiya, and P. Schmuki, High-aspect-ratio TiO2 nanotubes by anodization of titanium, Angew. Chem. Int. Ed., 44, 2100-2102 (2005). https://doi.org/10.1002/anie.200462459
- J. Park and J. Choi, Formation of well dispersed TiO2 microcones; the 20% surface occupation, Appl. Surf. Sci., 448, 212-218 (2018). https://doi.org/10.1016/j.apsusc.2018.04.033
- K. Lee, A. Mazare, and P. Schmuki, One-dimensional titanium dioxide nanomaterials: nanotubes, Chem. Rev., 114, 9385-9454 (2014). https://doi.org/10.1021/cr500061m
- K. Indira, U.K. Mudali, T. Nishimura, and N. Rajendran, A review on TiO2 nanotubes: Influence of anodization parameters, formation mechanism, properties, corrosion behavior, and biomedical applications, J. Bio. Tribocorros., 1, 1-22 (2015).
- Y. T. Kim, J. H. Youk, and J. Choi, Inverse-direction growth of TiO2 microcones by subsequent anodization in HClO4 for increased performance of lithium-ion batteries, ChemElectroChem, 7, 1248-1255 (2020). https://doi.org/10.1002/celc.202000114
- J. Park, S. Kim, G. Lee, and J. Choi, RGO-coated TiO2 microcones for high-rate lithium-ion batteries, ACS Omega, 3, 10205-10210 (2018). https://doi.org/10.1021/acsomega.8b00926
- H. Yoo, G. Lee, and J. Choi, Binder-free SnO2-TiO2 composite anode with high durability for lithium-ion batteries, RSC Adv., 9, 6589-6595 (2019). https://doi.org/10.1039/C8RA10358E
- A. Yerokhin, L. Snizhko, N. Gurevina, A. Leyland, A. Pilkington, and A. Matthews, Discharge characterization in plasma electrolytic oxidation of aluminium, J. Phys. D: Appl. Phys., 36, 2110-2120 (2003). https://doi.org/10.1088/0022-3727/36/17/314
- L. Snizhko, A. Yerokhin, A. Pilkington, N. Gurevina, D. Misnyankin, A. Leyland, and A. Matthews, Anodic processes in plasma electrolytic oxidation of aluminium in alkaline solutions, Electrochim. Acta, 49, 2085-2095 (2004). https://doi.org/10.1016/j.electacta.2003.11.027
- G. Lee, S. Kim, S. Kim, and J. Choi, SiO2/TiO2 composite film for high capacity and excellent cycling stability in lithium-ion battery anodes, Adv. Funct. Mater., 27, 1703538 (2017). https://doi.org/10.1002/adfm.201703538
- J. Wu, X. He, G. Li, J. Deng, L. Chen, W. Xue, and D. Li, Rapid construction of TiO2/SiO2 composite film on Ti foil as lithium-ion battery anode by plasma discharge in solution, Appl. Phys. Lett., 114, 043903 (2019). https://doi.org/10.1063/1.5083686