• Proceedings of the KIEE Conference
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• 2007.07a
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• pp.545-546
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• 2007

A hybrid system that uses a parallel combination of wind turbine and fuel cell is modeled. Wind energy source is characterized by its intermittent and variable nature. The output power generated by the fuel cell is stable and can be properly controlled. Therefore, fuel cell system can be added to the wind turbine system for the purpose of ensuring continuous power flow. Fuel cell helps to compensate power and regulate the frequency in power system. Simulation results show the effect of the hybrid system on power regulation. The excess power generated by the wind turbine was directed to an electrolyzer to generate hydrogen and the power deficit was compensated by the fuel cell.

• Transactions of the Korean hydrogen and new energy society
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• v.29 no.6
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• pp.606-619
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• 2018

This study focuses on the performance of hydrogen energy based hybrid system in terms of system reliability of electricity generation. With this aim to evaluate the off-grid system of photovoltaic (PV), wind turbine, electrolyzer, fuelcell, $H_2$ tank and storage batteries, 14 different sites in South Korea are simulated using HOMER. Performance analysis includes simulation on the different sites, verification of operational behaviors on regional and seasonal basis, and comparison among a control group. The result shows that the generation performance of hydrogen powered fuelcell is greatly affected by geographical change rather than seasonal effect. In addition, as the latitude of the hybrid systems location decrease, renewable power output and penetration ratio (%) increase under constant electrical load. Therefore, the hydrogen based hybrid system creates the stability of electricity generation, which best suits in the southern part of South Korea.

• New & Renewable Energy
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• v.18 no.1
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• pp.35-45
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• 2022

The renewable energy based MG is becoming one of the prominent solutions for greenhouse gas and constructing less power lines. However, how to procure the economics of MG considering the CO₂ emission and utility network impact is one of major issues as the proportion of renewable resource increases. This paper proposes the feasibility study scheme of campus MG and shows that the LCOE and CO₂ emission can be reduced by utilizing the excess power and introducing hydrogen system and plus DR. For this, the three cases: (a) adding the PV and selling excess power to utility, (b) producing and selling hydrogen using excess power, and (c) participating in plus DR are considered. For each case, not only the topology and component capacity of MG to secure economic feasibility, but also CO₂ emission and utility network effects are derived. If an electrolyzer with a capacity of 400 kW participates in plus DR for 3,730hours/year, the economic feasibility is securable if plus DR settlement and hydrogen sale price are more than 7.08¢/kWh and 8.3USD/kg or 6.25¢/kWh and 8.6USD/kg, respectively. For this end, continuous technical development and policy support for hydrogen system and plus DR are required.

• Advances in Energy Research
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• v.5 no.2
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• pp.107-128
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• 2017

Energy is a major component of almost all economic, production, and service activities, and rapid population growth, urbanization and industrialization have led to ever growing demand for energy. Limited energy resources and increasingly evident environmental effects of fossil fuel consumption has led to a growing awareness about the importance of further use of renewable energy sources in the countries energy portfolio. Renewable hydrogen production is a convenient method for storage of unstable renewable energy sources such as wind and solar energy for use in other place or time. In this study, suitability of 25 cities located in Iran's western region for renewable hydrogen production are evaluated by multi-criteria decision making techniques including TOPSIS, VIKOR, ELECTRE, SAW, Fuzzy TOPSIS, and also hybrid ranking techniques. The choice of suitable location for the centralized renewable hydrogen production is associated with various technical, economic, social, geographic, and political criteria. This paper describes the criteria affecting the hydrogen production potential in the study region. Determined criteria are weighted with Shannon entropy method, and Angstrom model and wind power model are used to estimate respectively the solar and wind energy production potential in each city and each month. Assuming the use of proton exchange membrane electrolyzer for hydrogen production, the renewable hydrogen production potential of each city is then estimated based on the obtained wind and solar energy generation potentials. The rankings obtained with MCDMs show that Kermanshah is the best option for renewable hydrogen production, and evaluation of renewable hydrogen production capacities show that Gilangharb has the highest capacity among the studied cities.

• Resources Recycling
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• v.25 no.2
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• pp.25-32
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• 2016

A electrodeposion behavior of tin was tested to recovery of tin metal from sulfate solution using a newly designed cyclone type electrolyzer. Parameters, such as flow rate, current density, tin and sulfuric acid concentration in the electrolyte were investigated. From the experimental results, a powered tin metal below $100{\mu}m$ can be obtained. As the increase of flow rate, current density and sulfuric acid concentration in the electrolyte, electrodeposition ratio of tin and current efficiency were increased. The electrodeposition ratio of tin was increased with the decrease of tin concentration in the electrolyte, but the current efficiency was decreased.

• Journal of Electrochemical Science and Technology
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• v.8 no.1
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• pp.7-14
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• 2017

This study aims to examine the influences of substrates/diffusion layers (DL) and oxygen reduction reaction catalysts ($M_{ORR}$) on the performance of $M_{ORR}/IrO_2$/DL-type bifunctional oxygen electrodes for use in polymer electrolyte membrane (PEM)-type unitized regenerative fuel cells (URFC). The $M_{ORR}/IrO_2$/DL electrodes were prepared via two sequential steps: anodic electrodeposition of $IrO_2$ on various DLs and fabrication of $M_{ORR}$ layers (Pt, Pd, and Pt-Ru) by spraying on $IrO_2/DL$. Experiments using different DLs, with Pt as the $M_{ORR}$, revealed that the roughness factor of the DL mainly determined the electrode performance for both water electrolyzer (WE) and fuel cell (FC) operations, while the contributions of porosity and substrate material were insignificant. When Pt-Ru was utilized as the $M_{ORR}$ instead of Pt, WE performance was enhanced and the electrode performance was assessed by analyzing round-trip efficiencies (${\varepsilon}_{RT}$) at current densities of 0.2 and $0.4A/cm^2$. As a result, using Pt-Ru instead of Pt alone provided better ${\varepsilon}_{RT}$ at both current densities, while Pd resulted in very low ${\varepsilon}_{RT}$. Improved efficiency was related to the additional catalytic action by Ru toward ORR during WE operation.

• Journal of Electrochemical Science and Technology
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• v.8 no.1
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• pp.61-68
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• 2017

Electrochemical conversion of $CO_2$ and production of $H_2$ were attempted on a three-dimensionally ordered, porous metal organic framework (MOF-74) in which transition metals (Co, Ni, and Zn) were impregnated. A lab-scale proton exchange membrane-based electrolyzer was fabricated and used for the reduction of $CO_2$. Real-time gas chromatography enabled the instantaneous measurement of the amount of carbon monoxide and hydrogen produced. Comprehensive calculations, based on electrochemical measurements and gaseous product analysis, presented a time-dependent selectivity of the produced gases. M-MOF-74 samples with different central metals were successfully obtained because of the simple synthetic process. It was revealed that Co- and Ni-MOF-74 selectively produce hydrogen gas, while Zn-MOF-74 successfully generates a mixture of carbon monoxide and hydrogen. The results indicated that M-MOF-74 can be used as an electrocatalyst to selectively convert $CO_2$ into useful chemicals.

• Applied Chemistry for Engineering
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• v.22 no.2
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• pp.125-132
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• 2011

A unitized regenerative fuel cell (URFC) as a next-generation fuel cell technology was considered in the study. URFC is a mandatory technology for the completion of the hybrid system with the fuel cell and the renewable energy sources, and it can be expected as a new technology for the realization of hydrogen economy society in the $21^{st}$ century. Specifically, the recent research data and results concerning the polymer electrolyte membrane for the URFC technology were summarized in the study. The prime requirements of polymer electrolyte membrane for the URFC applications are high proton conductivity, dimensional stability, mechanical strength, and interfacial stability with the electrode binder. Based on the performance of the polymer electrolyte membrane, the URFC technology combining the systems for the production, storage, utilization of hydrogen can be a new research area in the development of an advanced technology concerning with renewable energy such as fuel cell, solar cell, and wind power.

• Korean Chemical Engineering Research
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• v.60 no.1
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• pp.34-50
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• 2022

Since the Paris climate agreement, reducing greenhouse gases has been the most important global issue. In particular, it is necessary to reduce fossil fuels in the mobility sector, which accounts for a significant portion of total greenhouse gas emissions. In this paper, we investigated the economic feasibility of green mobility energy supply chains, which supply hydrogen as fuel to hydrogen vehicles based on electricity from renewable energy sources. The design and operation costs were analyzed by evaluating nine scenarios representing various combinatorial possibilities such as renewable energy generation, hydrogen production through water electrolytes, hydrogen storage and hydrogen refueling stations. Simulation calculations were made using Homer Pro, widely used commercial software in the field. The experience gained in this study could be further utilized to construct actual hydrogen energy systems.

• Journal of the Korean institute of surface engineering
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• v.55 no.3
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• pp.180-186
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• 2022

The production of hydrogen via water electrolysis (i.e., green hydrogen) using renewable energy is key to the development of a sustainable society. However, most current electrocatalysts are based on expensive precious metals and require the use of highly purified water in the electrolyte. We demonstrated the preparation of a non-precious metal catalyst based on CuCo₂O₄ (CCO) via simple electrodeposition. Further, an optimization process for electrodeposition potential, solution concentration and electrodeposition method was develop for a catalyst-substrate integrated electrode, which indicated the highly electrocatalytic performance of the material in electrochemical tests and when applied to an anion exchange membrane water electrolyzer.