• 제목/요약/키워드: Electrical explosion method

검색결과 69건 처리시간 0.023초

Characterization and Stability of Silver Nanoparticles in Aqueous Solutions

  • Bac, L.H.;Gu, W.H.;Kim, J.C.;Kim, B.K.;Kim, J.S.
    • 한국분말재료학회지
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    • 제19권1호
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    • pp.55-59
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    • 2012
  • In this work, the silver nanoparticles have been synthesized by electrical explosion of wire in three liquid mediums: deionized water (DIW), polyvinylpyrrolidone (PVP) and sodium dodecyl benzene sulfonate (SDBS) solutions. Absorption in the UV-visible region of these suspensions was measured in the range of 300-800 nm. A surface plasmon peak was observed at ~400 nm in all suspensions in measured wavelength range. Particle size was analyzed by transmission electron microscope. It showed that the particles had nearly spherical shape in all samples. The average particle sizes prepared in DIW, PVP and SDBS solution were 37, 31 and 27 nm, respectively. Stability of the suspensions was estimated by multiple light scattering method. The presence of PVP and SDBS surfactants in the exploding medium resulted in enhanced stability of the silver suspensions.

전기 폭팔법에 의한 Sn계 리튬이차전지용 음극 분말의 제조 및 전기 화학적 특성 (Synthesis and Electrochemical Properties of Sn-based Anode Materials for Lithium Ion Battery by Electrical Explosion Method)

  • 홍성현
    • 한국수소및신에너지학회논문집
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    • 제22권4호
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    • pp.504-511
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    • 2011
  • Nano-sized Sn powder was prepared by pulsed wire evaporation method. The Sn powder and carbon black were charged in jar and ball milled. The milling time was varied with 10 min., 1h, 2h, and 4h, respectively. The milled powders were dried and the shape and size were observed by FE-SEM. Nano-sized Sn powders were plastic-deformed and agglomerated by impact force of balls and heat generated during the SPEX milling. The agglomerated Sn powder also consisted of many nano-sized particles. Initial discharge capacities of milled Sn electrode powders with carbon powder were milled for 10 min., 1h, 2h, and 4h were 787, 829, 827, and 816 mAh/g, respectively. After 5 cycle, discharge capacities of Sn electrode powders with carbon powder milled for 10 min., 1h, 2h, and 4h decreased as 271, 331, 351, and 287 mAh/g, respectively. Because Sn electrode powders milled for 2h constist of uniform and fine size, the cyclability of coin cell made of this powders is better than others.

액중 전기선 폭발법을 이용한 Fe3O4/Fe/그래핀 나노복합체 분말의 제조 및 전기화학적 특성 (Fabrication of Fe3O4/Fe/Graphene nanocomposite powder by Electrical Wire Explosion in Liquid Media and its Electrochemical Properties)

  • 김유영;최지습;이회진;조권구
    • 한국분말재료학회지
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    • 제24권4호
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    • pp.308-314
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    • 2017
  • $Fe_3O_4$/Fe/graphene nanocomposite powder is synthesized by electrical wire explosion of Fe wire and dispersed graphene in deionized water at room temperature. The structural and electrochemical characteristics of the powder are characterized by the field-emission scanning electron microscopy, X-ray diffraction, Raman spectroscopy, field-emission transmission electron microscopy, cyclic voltammetry, and galvanometric discharge-charge method. For comparison, $Fe_3O_4$/Fe nanocomposites are fabricated under the same conditions. The $Fe_3O_4$/Fe nanocomposite particles, around 15-30 nm in size, are highly encapsulated in a graphene matrix. The $Fe_3O_4$/Fe/graphene nanocomposite powder exhibits a high initial charge specific capacity of 878 mA/g and a high capacity retention of 91% (798 mA/g) after 50 cycles. The good electrochemical performance of the $Fe_3O_4$/Fe/graphene nanocomposite powder is clearly established by comparison of the results with those obtained for $Fe_3O_4$/Fe nanocomposite powder and is attributed to alleviation of volume change, good distribution of electrode active materials, and improved electrical conductivity upon the addition of graphene.

유화유 생산의 적정 인화점에 관한 연구 (A Study on the Optimal Flash-Point of WDF Production)

  • 이진;김화성
    • 한국전기전자재료학회논문지
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    • 제33권4호
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    • pp.310-314
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    • 2020
  • Although waste oil derived fuel (WDF) production technology was developed under a government initiative ~10 years ago, it became stagnant owing to the small size of participating companies, residents' rejection of foul odor, and the nature of the technology for recycling waste that was avoided. However, this subject is under the spotlight again because of recent developments, such as garbage crisis. In particular, plastic is the most difficult waste to dispose of, with more than 4 million tons of plastic waste produced every year according to statistics from the Ministry of Environment. The most effective method for treating plastic waste is to produce WDF through low temperature thermal decomposition. The WDF includes several volatile ingredients that mostly limit the use of fuel for boilers, owing to safety concerns. In particular, flash point is legally stipulated because of secondary contamination in the distribution process and the risk of fire and explosion. It is required that external shipments (distribution) should be maintained in the range of at least 30~60℃ (excluding explosion prevention facilities) for diesel power generation. Therefore, this study seeks to find the flash point that is best suited to WDFs produced from plastic waste.

Research of Novel Water Cooling Jacket for Explosion-proof Motor

  • Wang, Yu;He, Huiming;Bai, Baodong
    • Journal of international Conference on Electrical Machines and Systems
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    • 제3권1호
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    • pp.67-71
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    • 2014
  • The well tightness of the coal mining water-cooling explosion-proof motor results in difficult heat dissipation, high hydraulic pressure is needed to increase the cooling effect. However, high hydraulic pressure may lead motor shell to deform, which makes it difficult to change the motor and maintain the motor unit. The method of adding keyhole caulk weld spots on the outer cooling water jacket was proposed to solve the problem. Based on the elasticity mechanics equations and the principle of finite element method the stresses and the deformations of the traditional and novel outer cooling water jacket were calculated separately. A hydraulic pressure experiment of the both cooling water jackets was constructed. Obviously, the stress and the deformation of the novel cooling water jacket are lower. The experimental result is consistent with the simulation results. It is effective to reduce the stress and the deformation of the cooling water jacket by adding the keyhole caulk weld spots.

One-step Physical Method for Synthesis of Cu Nanofluid in Ethylene Glycol

  • Bac, L.H.;Yun, K.S.;Kim, J.S.;Kim, J.C.;Rhee, C.K.
    • 한국분말재료학회지
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    • 제17권6호
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    • pp.464-469
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    • 2010
  • The Cu nanofluid in ethylene glycol was prepared by electrical explosion of wire, a novel one-step method. The X-ray diffraction, field emission scanning electron microscope and transmission electron microscope were used to study the properties of Cu nanoparticles. The results showed that the nanoparticles were consisted of pure face-centered cubic structure and near spherical shape with average grain size of 65 nm. Ultraviolet-visible spectroscopy (UV-Vis) confirmed Cu nanoparticles with a single absorbance peak of Cu surface plasmon resonance band at 600 nm. The nanofluid was found to be stable due to high positive zeta potential value, +51 mV. The backscattering level of nanofluid in static stationary was decreased about 2% for 5 days. The thermal conductivity measurement showed that Cu-ethylene glycol nanofluid with low concentration of nanoparticles had higher thermal conductivity than based fluid. The enhancement of thermal conductivity of nanofluid at a volume fraction of 0.1% was approximately 5.2%.

Design of Adaptive Neural Tracking Controller for Pod Propulsion Unmanned Vessel Subject to Unknown Dynamics

  • Mu, Dong-Dong;Wang, Guo-Feng;Fan, Yun-Sheng
    • Journal of Electrical Engineering and Technology
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    • 제12권6호
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    • pp.2365-2377
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    • 2017
  • This paper addresses two interrelated problems concerning the tracking control of pod propulsion unmanned surface vessel (USV), namely, the modeling of pod propulsion USV, and tracking controller design. First, based on MMG modeling theory, the model of pod propulsion USV is derived. Furthermore, a practical adaptive neural tracking controller is proposed by backstepping technique, neural network approximation and adaptive method. Meanwhile, unlike some existing tracking methods for surface vessel whose control algorithms suffer from "explosion of complexity", a novel neural shunting model is introduced to solve the problem. Using a Lyapunov functional, it is proven that all error signals in the system are uniformly ultimately bounded. The advantages of the paper are that first, the underactuated characteristic of pod propulsion USV is proved; second, the neural shunting model is used to solve the problem of "explosion of complexity", and this is a combination of knowledge in the field of biology and engineering; third, the developed controller is able to capture the uncertainties without the exact information of hydrodynamic damping structure and the sea disturbances. Numerical examples have been given to illustrate the performance and effectiveness of the proposed scheme.

수소충전소 폭발위험장소 완화를 위한 확산차단벽 최적화 설계 (Optimization of Designing Barrier to Mitigate Hazardous Area in Hydrogen Refueling Stations)

  • 안승효;오세현;김은희;이준서;마병철
    • 한국수소및신에너지학회논문집
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    • 제34권6호
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    • pp.734-740
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    • 2023
  • Hydrogen emphasis on safety management due to its high potential for accidents from wide explosive limits and low ignition energy. To prevent accidents, appropriate explosion-proof electrical equipment with installed to safe management of ignition sources. However, designing all facilities with explosion-proof structures can significantly increase costs and impose limitations. In this study, we optimize the barrier to effectively control the initial momentum in case of hydrogen release and form the control room as a non-hazardous area. We employed response surface method (RSM), the barrier distance, width and height of the barrier were set as variables. The Box-Behnken design method the selection of 15 cases, and FLACS assessed the presence of hazardous area. Analysis of variance (ANOVA) analysis resulting in an optimized barrier area. Through this methodology, the workplace can optimize the barrier according to the actual workplace conditions and classify reasonable hazardous area, which is believed to secure safety in hydrogen facilities and minimize economic burden.

부정합조건 외란을 갖는 비선형 시스템의 퍼지 외란 관측기 기반 다중 슬라이딩 평면 제어 (Fuzzy Disturbance Observer based Multiple Sliding Surface Control of Nonlinear Systems with Mismatched Disturbance)

  • 이상윤;서형근;현창호;박민용
    • 한국지능시스템학회논문지
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    • 제24권4호
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    • pp.385-391
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    • 2014
  • 본 논문은 부정합조건 외란을 갖는 비선형 시스템을 제어하기 위하여 퍼지 외란 관측기 기반 다중 슬라이딩 평면 제어 기법을 제안한다. 부정합조건에서도 제어 대상이 평형점으로 수렴할 수 있도록 다중 슬라이딩 평면 기법을 사용하여 제어기를 설계한다. 더불어, 퍼지 외란 관측기를 도입함으로써 다중 슬라이딩 평면 제어의 문제점인 항의 복잡성 (Explosion of terms)을 해결하고, 기존 슬라이딩 모드 제어 상에서 불연속 신호를 사용해서 일어나는 채터링(Chattering)을 제거한다. 제안된 시스템의 안정성은 리아프노브 안정성 이론을 이용하여 증명한다. 제안한 방법의 성능 우수성을 보이기 위해 모의실험을 통하여 비선형 외란 관측기 기반 슬라이딩 모드 제어기의 성능과 비교 분석한다.