• Title/Summary/Keyword: Diffusion Coefficient

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A Numerical Analysis for Estimations of Osmotic Pressure of Colloidal Suspension and Gradient Diffusion Coefficient of Particles from Permeate Flux Experiments (투과플럭스 실험으로부터 콜로이드 서스펜션의 삼투압과 입자의 구배확산계수 산출을 위한 수치적 해석)

  • 전명석
    • Membrane Journal
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    • v.12 no.2
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    • pp.90-96
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    • 2002
  • A novel methodology on the calculations of osmotic pressure and gradient diffusion coefficient has been provided ill the present study, by applying a succinct numerical analysis on the experimental results. Although both the osmotic pressure and the gradient diffusion coefficient represent a fundamental characteristic in related membrane filtrations such as microfiltration and ultrafiltration, neither theoretical analysis nor experiments can readily determine them. The osmotic pressure of colloidal suspension has been successfully determined from a relationship between the data of the time-dependent permeate flux, their numerical accumulations, and their numerical derivatives. It is obvious that the osmotic pressure is gradually increased, as the particle concentration increases. The thermodynamic coefficient was calculated from the numerical differentiation of the correlation equation of osmotic pressure, and the hydrodynamic coefficient was evaluated from the previously developed relation for an ordered system. Finally, the estimated gradient diffusion coefficient, which entirely depends on the particle concentration, was compared to the previous results obtained from the statistical mechanical simulations.

The Comparison of Apparent Chloride Diffusion Coefficients in GGBFS Concrete Considering Sea Water Exposure Conditions (해양 폭로 환경에 따른 GGBFS 콘크리트의 겉보기 염화물 확산계수 비교)

  • Yoon, Yong-Sik;Jeong, Gi-Chan;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.2
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    • pp.18-27
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    • 2022
  • In this study, the time-dependent chloride ingress behavior in GGBFS concrete was evaluated considering marine exposure conditions and the properties of concrete mixtures. The concrete mixture for this study had 3 levels of water to binder ratio and the substitution rate of GGBFS, and outdoor exposure tests were performed considering submerged area, tidal area, and splash area. According to the evaluation results of diffusion coefficient considering properties of concrete mixtures, as the substitution rate of GGBFS increased, the decreasing rate of the diffusion coefficient decreased based on exposure periods of 730 days(2 years). As the evaluation result of the diffusion behavior according to the marine exposure conditions, the diffusion coefficient was evaluated in the order of submerged area, tidal area, and splash area. In tidal area, a relatively high diffusion coefficient was evaluated due to the repetition of wet and dry seawater. In this study, the effects of GGBFS substitution rate on the decreasing behavior of apparent chloride diffusion coefficient was analyzed in consideration of exposure conditions and periods. Linear regression analysis was performed with apparent chloride diffusion coefficient as output value and GGBFS substitution rate as input value. After 730 days of exposure, the effect of GGBFS on diffusion coefficient was significantly reduced. Even for OPC concrete, after 730 days, the diffusion coefficient was as low as that of GGBFS concrete, so the gradient of the regression equation decreased significantly. It is thought that improved durability performance for chloride ingress can be secured before 730 days through the use of GGBFS.

Prediction of Time-dependent Moisture Diffusion Coefficient in Early-age Concrete (초기재령 콘크리트의 시간 의존적인 수분확산계수 예측에 관한 연구)

  • Kang, Su-Tae;Kim, Jin-Keun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.9 no.4
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    • pp.141-148
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    • 2005
  • The nonlinear humidity distribution occurs due to the moisture diffusion when a concrete is exposed to an ambient air. This nonlinear humidity distribution induces shrinkage cracks on surfaces of the concrete. Because shrinkage cracks largely affect the durability and serviceability of concrete structures, the moisture diffusion in concrete must be investigated. The purpose of this paper is to propose a model of the moisture diffusion coefficient that governs moisture diffusion within concrete structures. To propose the model, numerical analysis was performed with several experiments. Because the moisture diffusion coefficient is changed with aging, especially at early ages, the proposed model includes aging effect by terms of the porosity as well as the humidity of concrete.

A Study on the Dry Shrinkage and Moisture Diffusion Coefficient of Polymer-Modified Mortars by the Moisture Diffusion (수분확산에 의한 폴리머 시멘트 모르터의 건조수축과 확산계수에 관한 연구)

  • 조영국;소양섭
    • Magazine of the Korea Concrete Institute
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    • v.8 no.5
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    • pp.145-154
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    • 1996
  • Polymer-modified mortars have an excellent water proofness and water retentivity. Therefore, the study on the moisture diffusion behavior- is very important. The purpose of' this study is to investigate the effects of relative humidity and moisture content in mortars on the moisture diffusion, and the relationship between the shrinkage and moisture diffusion coefficient of polymer-modified mortars cured at $20{\circ}C$ 50% R.H and 80% R.H. The pore size distribution of the polymer-modified mortars was also measured. From the test results, the relative humidity and moisture content in mortars influenced on the moisture diffusion of polymer-modified mortars. The shrinkage and moisture diffusion coefficient of polymer-modified mortars cured at $20{\circ}C$ 50% R.H. was bigger than that cured at $20{\circ}C$ 80% R.H.. and decreased with increasing polymer-cement ratio regardless of polymer type.

Noise reduction method using mean curvature diffusion (평균곡률 확산을 이용한 잡음감소 기법)

  • Ye Chul-Soo;Chung Hun-Suk;Kim Seong-Jong;Hyun Deuk-Chang
    • 한국컴퓨터산업교육학회:학술대회논문집
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    • 2003.11a
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    • pp.87-94
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    • 2003
  • Anisotropic diffusion is a selective smoothing technique that promotes smoothing within a region instead of smoothing across boundaries. In anisotropic diffusion, the rate of smoothing is controlled by the local value of the diffusion coefficient chosen to be a function of the local image gradient magnitude. El-Fallah and Gary E. Ford represented the image as a surface and proved that setting the inhomogeneous diffusion coefficient equal to the inverse of the magnitude of the surface normal results in surface evolving speed that is proportional to the mean curvature of the image surface. This model has the advantage of having the mean curvature diffusion (MCD) render invariant magnitude, thereby preserving structure and locality. In this paper, the proposed MCD model efficiently reduces diffusion coefficient at the thin edges using the smoothness of the surface.

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Design of diffusers in consideration of scattering and diffusion characteristics (확산 지향성을 고려한 확산체의 설계)

  • Kim, Yong-Hee;Kim, Jae-Ho;Kim, Jeong-Jun;Jeon, Jin-Yong
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2008.04a
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    • pp.21-24
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    • 2008
  • This study proposes a optimized shape of diffuser profile through investigating the scattering and diffusion characteristics of diffusers. The scattering coefficient according to ISO 17497-1 evaluates uniformity of reverberant sound field of late reflections, while the diffusion coefficient according to AES-4id-2001 evaluates polar response of early reflections. Thus both scattering and diffusion characteristics should contribute to design shape of diffusers to maximize physical performance. To find out design method, the previous results on hemisphere diffusers are reviewed. The frequency characteristics of scattering coefficients depended on the structural height of the diffusers, while amount of scattering coefficients depended on the surface coverage density of the diffusers. However absorptive properties also increased with augment of surface coverage density, thus optimum coverage density should be considered. For the directional diffuser, three types of 2D-diffusers are proposed; semicylinder of h=5mm, semi-truncated cone of h=5-25mm and semicylinder of h=25mm. As results, diffusers with the maximum height of 25mm show the highest scattering coefficients, while diffuser of h=5mm shows high scattering coefficients only at the high-frequency bands. Diffusion coefficient will be investigated for diffusive properties of the early reflection.

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Evaluation of the Durability at RC Structure with Surface Finishing Materials using FEM Analysis. (FEM 해석을 통한 표면마감재 시공 RC 구조물의 내구성 평가)

  • Lee, Seong-Min;Lee, Han-Seoung;Kim, Dong-Seok;Lee, Woo-Jin
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.269-272
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    • 2006
  • Chloride ion diffusion is the most important thing of occuring deterioration in RC structure. So it is important to decide the precise chloride ion diffusion coefficient in order to predict the durability life in RC structure. The purpose of this study is to analyze the established data, which are restricted by chloride diffusion coefficient, and to calculate chloride ion diffusion coefficient using RCPT test. To examine the prediction of the concrete structure durability by an FEM analysis and the chloride diffusion coefficient as a variable. Each surface finishing materials were effective on the increment of chloride penetration resistance, but showed a little different effect depending on the type of surface finishing material.

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A study on the Effect of Curing time on the Chloride ion Diffusion Coefficient in Concrete with Portland Cement and Ground Granulated blast-furnace slag (고로슬래그미분말 혼입 콘크리트의 양생재령이 염소이온 확산계수에 미치는 영향에 관한 연구)

  • Lee, Woo-Jin;Lee, Han-Seung;Song, Soo-Sang
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.249-252
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    • 2004
  • Chloride ion diffusion is the most important thing of occuring deterioration in RC structure. According to establish data, the curing time in concrete reduce the chloride ion diffusion coefficient. The purpose of this study is to make clear through experience on the effect of curing time on the chloride ion diffusion coefficient in concrete with Portland cement and ground granulated blast-furnance slag and a propose the standard of chloride ion diffusion coefficient in concrete.

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The Measurement of Diffusion Coefficient of Fission Gases in Urania with Respect to O/M Ratio (화학당량에 따른 우라니아의 핵분열 기체 확산 계수 측정)

  • 김희문;박광헌;김봉구;주용선;김건식;송근우;홍권표;강영환
    • Journal of the Korean institute of surface engineering
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    • v.36 no.1
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    • pp.99-107
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    • 2003
  • The diffusion coefficient of Xe-133 was obtained from an annealing test. The specimens were made from a UO$_2$ single crystal powder with natural enrichment. Weight and grain size were 300mg and ($23\mu\textrm{m}$, respectively. Oxygen potentials were obtained from an oxygen sensor. Released fractions were obtained from both results of gamma scans and quantitative analysis with MCNP code, The annealing test was performed at three temperatures at once. Diffusion coefficients of Xe-133 were calculated using slope of Booth theory in each O/M ratios. Activation energy and the pre-exponential factor of the diffusion coefficient were obtained. The activation energy of near stoichiomeric $UO_2$ is 310 kJ/mol. The measured values of near stoichiometric $UO_2$ are very close to other data available. Diffusion coefficients increase with hyper-stoichiometry, due to higher concentration of cation vacancies.

Enhanced vertical diffusion coefficient at upper layer of suspended sediment concentration profile

  • Kim, Hyoseob;Jang, Changhwan;Lhm, Namjae
    • Ocean Systems Engineering
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    • v.2 no.4
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    • pp.289-295
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    • 2012
  • Assume fluid eddy viscosity in the vertical direction is parabolic. Sediment particles diffuse with the given fluid eddy viscosity. However, when the vertical diffusion coefficient profile is computed from the suspended sediment concentration profile, the coefficient shows lager values than the fluid mixing coefficient values. This trend was explained by using two sizes of sediment particles. When fine sediment particles like wash load are added in water column the sediment mixing coefficient looks much larger than the fluid mixing coefficient.