• Title/Summary/Keyword: Determination Factor

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Trace Mercury Determination by Differential Pulse Anodic Stripping Voltammetry Using Polythiophene-Quinoline/Glassy Carbon Modified Electrode

  • Yoo, Kwang-Sik;Woo, Sang-Beom;Jyoung, Jy-Young
    • Bulletin of the Korean Chemical Society
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    • v.24 no.1
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    • pp.27-31
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    • 2003
  • A Polythiophene-quinoline/glassy carbon (PTQ/GC) modified electrode was developed for the determination of trace mercury in industrial waste water, natural water, soil, and other media. The electrode was prepared by the cyclic voltammetric polymerization of thiophene and quinoline on glassy carbon (GC) electrode by the potential application from -0.6 V to +2.0 V (50 mV/sec) in a solution of 0.1 M thiophene, quinoline and tetrabutyl ammonium perchlorate (TBAP) in acetonitrile. Optimum thickness of the polymer membrane on the GC electrode was obtained with 20 repeated potential cyclings. The redox behavior of Cu(Ⅱ) and Hg(Ⅱ) were almost identical on this electrode. The addition of 4-(2-pyridylazo)resorcinol (PAR) to the solution containing Cu(Ⅱ) and Hg(Ⅱ) allowed the separation of the components due to the formation of the Cu(Ⅱ)-PAR complex reduced at -0.8V, which was different from the Hg(Ⅱ) reduced at -0.5 V on a saturated calomel electrode (SCE). The calibration graph of Hg(Ⅱ) shows good linear relationship with the correlation factor of 0.9995 and the concentration gradient of 0.33 ㎂/㎠/ppb down to 0.4 ppb Hg. The method developed was successfully applied to the determination of mercury in samples such as river, waste water, and sea water.

Effects of Consumer Self-Determination Motivation and Service Quality on Purchase Intention of Omni-Channel Service in Omni-Channel Environment (옴니채널 환경에서 소비자의 자기결정 동기와 서비스품질이 옴니채널 서비스 구매의도에 미치는 영향)

  • Park, Joonyong;Kim, Ji Su;Kim, Renee B.
    • Journal of Information Technology Services
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    • v.18 no.4
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    • pp.23-38
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    • 2019
  • With the development of information and communication technology, logistics distribution systems and services have been improved, new types of services have been provided, and consumption patterns in consumer markets have also changed. In the domestic distribution market, the development of ICT technology, the spread of smart devices, and the growth of the e-commerce market have led to Omni-channel, a service that integrates offline channels and online channels. Omni-channel service aims to provide consumers with consistent and convenient service by integrating offline and online domain into one. Consumers can get integrated service on and offline. In this study, consumers' intention to use Omni-channel was examined by Self Determination Theory and SERVQUAL. The survey was conducted on Omni-channel user and the research model was composed of 2nd order factor model considering the characteristics of Omni-channel which provides integrated service based on the prior literature and PLS-SEM (partial least squares structural equation modeling).

A Review on the Methods of Sample Size Determination in Nursing Research (간호학 연구에서의 표본크기 결정 방법에 대한 고찰)

  • Lee, Jae-Won;Park, Mi-Ra;Lee, Jung-Bok;Lee, Sook-Ja;Park, Eun-Sook;Park, Young-Joo
    • Women's Health Nursing
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    • v.4 no.3
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    • pp.375-387
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    • 1998
  • In clinical trials of nursing research, the sample size determination is one of the most important factor. Although sample size must be considered at the design stage, it has been disregarded in most clinical trials. The power analysis is usually performed before study begins to compute sample size and the power can also be calculated at the end of study in order to justify study result. The power analysis is essential especially when the clinical trials can not show significant differences. In this paper, we review the statistical methods for power analysis and sample size formulae in nursing research. Sample size formulae and the corresponding examples are discussed according to the six types of studies ; mean for one sample, proportion for one sample, means in two samples, proportions in two samples, correlation coefficient and ANOVA.

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Factors Affecting Female Nursing Students' Intention to Control Drinking (간호학과 여학생의 절주의도 영향요인)

  • Song, Hyo-Suk;Lim, So Hee
    • Journal of the Korean Society of School Health
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    • v.32 no.2
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    • pp.116-124
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    • 2019
  • Purpose: This study was performed to measure the influence of drinking motives, drinking refusal self-efficacy, and self-determination on the intention to control drinking among nursing students. Methods: A cross-sectional survey was done with the participation of 258 nursing students attending four universities in G city. Data collection was conducted from May to June, 2018, using a self-report questionnaire. Data were analyzed using the t-test, ANOVA, $Scheff{\acute{e}}$ test, Pearson's correlation coefficients, and Hierarchical multiple regression. Results: The average scores for drinking motives, drinking refusal self-efficacy, self-determination, and intention to control drinking were 2.29, 4.54, 3.89, and 4.29 respectively. There were significant differences in the intention to control drinking according to grade, religion, and age of alcohol initiation. The factors influencing the intention to control drinking in nursing students were identified as self-determination (${\beta}=.24$), drinking refusal self-efficacy (${\beta}=.17$) and drinking motives (${\beta}=-.17$). This factor explained 26% of the nursing students' intention to control drinking. Conclusion: Therefore, it is necessary to develop a alcohol education program to improve the drinking culture of nursing college students and to improve their self-regulation skills in order to help them form a desirable drinking habit, and it is also necessary to apply the developed intervention program and test the effect.

Determination of the Effective Buckling Length of Rahmen (라멘구조물의 유효좌굴장 결정)

  • 경용수;진만식;김문영
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2004.04a
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    • pp.185-192
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    • 2004
  • The goal of this paper is to determine the accurate effective length factor(K factor) for buckling design of plane frames and to point out the practical limitations of the alignment chart which provides the approximate effective length factor. At present, the most general method to obtain K factors is to use the alignment chart which is given in the form of nomograph in LRFD-AISC specification commentaries. However it should be realized that various simplifications and assumptions were used in obtaining the alignment chart. Therefore, a simple but effective method to obtain accurate K-factors through the stability analysis of plane frames is developed in this study. To demonstrate the accuracy and effectiveness of the present scheme, K-factors by system buckling analysis of frames are calculated and compared with those calculated by the alignment chart.

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Determination of Thermal Dtress Intensity Factors for the Interface Crack under Vertical Uniform Heat Flow (수직 균일 열유동하에 있는 접합 경계면 균열의 열응력세기계수 결정)

  • 이강용;설창원
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.15 no.1
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    • pp.201-208
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    • 1991
  • In case that an interface crack exists in an infinite two-dimensional elastic bimaterial, the crack surface is insulated under traction free and the uniform heat flow vertical to the crack from infinite boundary is given. Temperature and stress potentials are obtained by using complex variable approach to solve Hilbert problems. The results are used to obtain thermal stress intensity factors. Only mode I thermal stress intensity factor occurs in case of the homogeneous material. Otherwise, mode I and II thermal stress intensity factor is much smaller than one of mode II.

DEFAULT BAYESIAN INFERENCE OF REGRESSION MODELS WITH ARMA ERRORS UNDER EXACT FULL LIKELIHOODS

  • Son, Young-Sook
    • Journal of the Korean Statistical Society
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    • v.33 no.2
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    • pp.169-189
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    • 2004
  • Under the assumption of default priors, such as noninformative priors, Bayesian model determination and parameter estimation of regression models with stationary and invertible ARMA errors are developed under exact full likelihoods. The default Bayes factors, the fractional Bayes factor (FBF) of O'Hagan (1995) and the arithmetic intrinsic Bayes factors (AIBF) of Berger and Pericchi (1996a), are used as tools for the selection of the Bayesian model. Bayesian estimates are obtained by running the Metropolis-Hastings subchain in the Gibbs sampler. Finally, the results of numerical studies, designed to check the performance of the theoretical results discussed here, are presented.

Adaptive Modeling by Determination Algorithm of Optimal Time-varying Convergence Factor (최적한 시변 수렴인자 결정법에 의한 적응 모델링)

  • Ahn, Doo-Soo;Kim, Jong-Boo;Kim, Jae-Il;Yim, Kook-Hyun
    • Proceedings of the KIEE Conference
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    • 1992.07a
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    • pp.327-329
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    • 1992
  • This Paper presents an algorithm for improvement of convergence in Adaptive Filter. The proposed algorithm employes the time-varying Convergence Factor to Block LMS adaptation algorithm. Computer simulation for Adaptive Modeling of time-invarying and time-varying unknown systems has been performed. Performance comparisons between LMS, BLMS algorithms which have fixed Convergence factors obtained by trial and error and the proposed algorithm which has time-varying Convergence Factor show that the proposed algorithm is superior to LMS and BLMS algorithm with respect to speed and accuracy of adaptation.

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Determination of Stress Intensity Factor for the Crack in Anisotropic Solids Using the Finite Element Method (유한요소법에 의한 이방성재료내 균열의 응력확대계수 결정)

  • Lim, W.K.;Jin, Y.K.;Kang, S.J.
    • Proceedings of the KSME Conference
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    • 2001.11a
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    • pp.234-239
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    • 2001
  • The stress intensity factors have been widely used in numerical studies of crack growth direction. However in many cases, omissive terms of the series expansion are quantitatively significant, so we consider the computation of such terms. For this purpose, we used the finite element method with isometric quadratic quarter-point elements. For examples, infinite square plate with a slant crack subjected to a uniaxial load is analyzed. The numerical analysis were performed for the wide range of crack tip element lengths and inclined angles. The numerical results obtained are compared with the theoretical solutions. Also they were accurate and efficient.

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Evaluation of the Plastic η-Factor Considering Strength Mismatch in a Narrow Gap Welding Part (I) (협계용접부 강도 불균일을 고려한 소성 η계수 평가 (I))

  • Huh, Yong;Kim, Hyung-Ick;Seon, Kwang-Sang;Koo, Jae-Mean;Seok, Chang-Sung
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.6
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    • pp.504-511
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    • 2008
  • This study evaluated the influence of the strength mismatch of HAZ for a plastic ${\eta}$-factor, which is the principle parameter determining the plastic portion of J-integral to assess the fracture toughness of the weldment. The specimen of tensile and hardness test was manufactured from the piping applying narrow-gap welding, and the mechanical properties of weldment, HAZ and a base metal were obtained. To perform the finite element analysis according to the ratio of strength mismatch, the material properties was chosen with the change of strength using the determination method of Ramberg-Osgood constant. Also, the influence of the strength mismatch of HAZ was determined using finite element analysis by those properties.