• Title/Summary/Keyword: Density of nanoparticle

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Evaluation of Absorbed Dose According to Nanoparticle Density During the Breast Cancer Brachytherapy (유방암 근접치료 시 나노입자의 밀도에 따른 흡수선량 평가)

  • Lee, Deuk-Hee;Nam, Ji-Hee;Kim, Jung-Hoon
    • Journal of radiological science and technology
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    • v.42 no.2
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    • pp.131-135
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    • 2019
  • The purpose of this study was to evaluate the efficacy of brachytherapy of breast cancer by dose assessment which a steady increased in Korea women. The dose assessment was performed using the MCNPX program, a MonteCarlo simulation technique. The sources used for brachytherapy was 192Ir. And nanoparticle which used for dose enhancement was gold. The density of nanoparticle was 7, 18 and 30 mg. Evaluation of absorbed dose according to distance is measured at a distance of 30, 50, 100 and 200 cm from the patient. As a result, The breast absorbed dose results increased in proportion to the density of nanoparticle. And the surrounding organs were not significantly different according to the density. But, in some organs, the absorbed dose decreased as the density of nanoparticles increased. Absorbed dose according to the distance was in inverse proportion to distance.

Evaluation of Absorbed Dose According to the Gold Nanoparticle Density in Prostate Cancer Brachytherapy (전립선암의 근접치료 시 금 나노입자 밀도에 따른 흡수선량평가)

  • Lee, Deuk-Hee;Kim, Jung-Hoon
    • Journal of the Korean Society of Radiology
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    • v.13 no.2
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    • pp.247-252
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    • 2019
  • This study was evaluated absorbed dose according to the gold nanoparticle density in prostate brachytherapy which was constantly occurred in Korean men. Absorbed dose evaluation was using MCNPX program which was applied Monte Carlo simulation. Source were applied $^{192}Ir$ which was temporary insertion source and $^{103}Pd$ which was permanently insertion source. And gold nanoparticle density was applied 0 mg, 7 mg, 18 mg and 30 mg. The prostate absorbed dose was increased in proportion to the density 2.95E-14 Gy/e to 4.42E-14 Gy/e in $^{192}Ir$ and showed the same tendency in $^{103}Pd$. And surrounding organ absorbed dose was inversely proportional to the density. Therefore using nanoparticle in brachytherapy was increased therapeutic ratio.

Study on Formation of Semitransparent Cu Nanoparticle Layers for Realizing Metal Nanoparticle-Dielectric Bilayer Structures (금속나노입자-유전체 이층 구조 구현을 위한 반투명 Cu 나노입자층 형성에 관한 연구)

  • Yoon, Hye Ryeon;Jo, Yoon Ee;Yoon, Hoi Jin;Lee, Seung-Yun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.6
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    • pp.460-464
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    • 2020
  • This study reports the fabrication and application of semitransparent Cu nanoparticle layers. Spin coating and subsequent drying of a Cu colloid solution were performed to deposit Cu nanoparticle layers onto Si and glass substrates. As the spin speed of the spin coating increases, the density of the nanoparticles on the substrate decreases, and the agglomeration of nanoparticles is suppressed. This microstructural variation affects the optical properties of the nanoparticle layers. The transmittance and reflectance of the Cu nanoparticle layers increase with increasing spin speed, which results from the trade-off between the exposed substrate area and surface coverage of the Cu nanoparticles. Since the glass substrates coated with Cu nanoparticle layers are semitransparent and colored, it is anticipated that the application of a Cu nanoparticle-dielectric bilayer structure to transparent solar cells will improve the cell efficiency as well as aesthetic appearance.

Pressure-infiltration of Fe3O4-nanoparticles Into Porous Silicon and a Packing Density Monitoring Technique (다공성실리콘내 Fe3O4 나노입자의 압력침착과 채움밀도 모니터링 방법)

  • Lee, Joo Hyeon;Lee, Jae Joon;Lee, Ki Won
    • Journal of Sensor Science and Technology
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    • v.24 no.6
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    • pp.385-391
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    • 2015
  • In this paper, we propose a new method to infiltrate $Fe_3O_4$-nanoparticles into a porous silicon film and a monitoring technique to detect packing density of nanoparticles within the film. Recently, research to use porous silicon as a drug carrier or a new functional sensor material by infiltrating $Fe_3O_4$-nanoparticles has been extensively performed. However, it is still necessary to enhance the packing density and to develop a monitoring technique to detect the packing density in real time. In this light, we forcibly injected a nanoparticle solution into a rugate-structured free-standing porous silicon (FPS) film by applying a pressure difference between the two sides of the film. We found that the packing density by the pressure-infiltration method proposed in this paper is enhanced, relative to that by the previous diffusion method. Moreover, a continuous shift in wavelength of the rugate reflectance peak measured from the film surface was observed while the nanoparticle solution was being injected. By exploiting this phenomenon, we could qualitatively monitor the packing density of $Fe_3O_4$-nanoparticles within the FPS film with the injection volume of the nanoparticle solution.

Packing Density Parameters of Palladium Nanoparticle Monolayers Fabricated via Spin-Coating Electrostatic Self-Assembly

  • An, Minshi;Hong, Jong-Dal;Cho, Kyung-Sang;Lee, Eun-Sung;Choi, Jae-Young
    • Bulletin of the Korean Chemical Society
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    • v.29 no.3
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    • pp.623-626
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    • 2008
  • Spin-coating electrostatic self-assembly (SCESA) is utilized to fabricate a single layer of carboxylic-acid-coated Pd nanoparticles (NPs) (D??5 nm) on an oppositely charged surface. The packing density of a NP monolayer formed on a rotating solid substrate (3000 rpm) was examined with regards to various parameters, including the particle concentration, the pH, and the ionic strength of the solution. Initially, the packing density grew exponentially with increases in the particle concentration, up to a maximum value (of 8.4 ´ 1011/cm2) at 1.2 wt%. The packing density was also found to increase drastically as the pH decreased and the ionic strength of the solution increased; these trends can be attributed to a reduction in the interparticle repulsions among the NPs in the solution and on the substrate. The best result of this study was achieved in a 1.2 wt% solution at pH 8; under these conditions, an NP monolayer with the highest density (namely, 1.6 ´ 1012/cm2) was obtained.

ZnO Nanoparticle Based Dye-Sensitized Solar Cells Devices Fabricated Utilizing Hydropolymer at Low Temperature (저온에서 Hydropolymer를 이용한 ZnO 나노입자 염료 감응형 태양전지)

  • Kwon, Byoung-Wook;Son, Dong-Ick;Park, Dong-Hee;Yang, Jeong-Do;Choi, Won-Kook
    • Korean Journal of Materials Research
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    • v.20 no.9
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    • pp.483-487
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    • 2010
  • To fabricate $TiO_2$ nanoparticle-based dye sensitized solar cells (DSSCs) at a low-temperature, DSSCs were fabricated using hydropolymer and ZnO nanoparticles composites for the electron transport layer around a low-temperature ($200^{\circ}C$). ZnO nanoparticle with 20 nm and 60 nm diameter were used and Pt was deposited as a counter electrode on ITO/glass using an RF magnetron sputtering. We investigate the effect of ZnO nanoparticle concentration in hydropolymer and ZnO nanoparticle solution on the photoconversion performance of the low temperature fabricated ($200^{\circ}C$) DSSCs. Using cis-bis(isothiocyanato)bis(2,20 bipyridy1-4,40 dicarboxylato) ruthenium (II) bis-tetrabutylammonium (N719) dye as a sensitizer, the corresponding device performance and photo-physical characteristics are investigated through conventional physical characterization techniques. The effect of thickness of the ZnO photoelectrode and the morphology of the ZnO nanoparticles with the variations of hydropolymer to ZnO ratio on the photoconversion performance are also investigated. The morphology of the ZnO layer after sintering was examined using a field emission scanning electron microscope (FE-SEM). 60 nm ZnO nanoparticle DSSCs showed an incident photon-to-current conversion efficiency (IPCE) value of about 7% higher than that of 20 nm ZnO nanoparticle DSSCs. The maximum parameters of the short circuit current density ($J_{sc}$), the open circuit potential ($V_{oc}$), fill factor (ff), and efficiency ($\eta$) in the 60 nm ZnO nanoparticle-based DSSC devices were 4.93 mA/$cm^2$, 0.56V, 0.40, and 1.12%, respectively.

$In_2O_3$ nanoparticle 첨가에 따른 a-IGZO channel 층의 성분 및 결정학적 특성 변화

  • Lee, Min-Jeong;Gang, Ji-Yeon;Lee, Tae-Il;Myeong, Jae-Min
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.112.1-112.1
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    • 2012
  • 산화물 기반의 TFT (Thin Film Transistor) 는 유리, 금속, 플라스틱 등 기판 종류에 상관없이 균일한 제작이 가능하며, 상온 및 저온에서 대면적으로 제작이 가능하고, 저렴한 비용으로 제작 가능하다는 장점 때문에 최근 많은 연구가 이루어지고 있다. 현재 TFT 물질로 많이 연구되고 있는 산화물 중 가장 많은 연구가 이루어진 ZnO 기반의 TFT는mobility와 switching 속도에서 우수한 특성을 보이나, 트렌지스터의 안정성이 떨어지는 것으로 보고되고 있다. 그러나 a-IGZO의 경우 결정학적으로 비정질이며, 상온 및 저온에서 대면적으로 제작이 가능하고, 높은 전자 이동도의 특성을 가지고 있는 장점 때문에 최근 차세대 산화물 트렌지스터로 각광받고 있다. IGZO 물질의 경우 s 오비탈의 중첩으로 인해 높은 전자 이동도의 특성을 가지며, IGZO 물질 내 전자의 이동은 IGZO의 조성과 구조적 특성에 영향을 받는다. IGZO 물질의 구성 성분은 $In_2O_3$, $Ga_2O_3$, ZnO 성분으로 이루어져 있으며, $In_2O_3$의 경우 주로 carrier 를 생성하고 IGZO TFT의 mobility를 향상시키는 물질로 알려져 있다. 본 연구에서는 $In_2O_3$ nanoparticle의 density를 조절하여 첨가함으로써 IGZO TFT 소자 특성에 미치는 평가를 진행하였다. $In_2O_3$ nanoparticle의 density변화에 따른 interparticle spacing과 IGZO계면 사이의 미세구조와 전기적인 특성간의 상관관계를 연구하기 위하여 IGZO TFT 특성은 HP 4145B 측정을 통하여 확인하였고, $In_2O_3$ nanoparticle의 분포와 결정성은 AFM과 XRD, TEM을 통해 분석하고 In2O3 nanoparticle의 유무에 따른 IGZO channel 층의 조성 변화를 STEM과 AES를 통해 비교 및 분석하였다.

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Preparation of Gold Nanoisland Arrays from Layer-by-Layer Assembled Nanoparticle Multilayer Films

  • Choi, Hyung-Y.;Guerrero, Michael S.;Aquino, Michael;Kwon, Chu-Hee;Shon, Young-Seok
    • Bulletin of the Korean Chemical Society
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    • v.31 no.2
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    • pp.291-297
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    • 2010
  • This article introduces a facile nanoparticle self-assembly/annealing method for the preparation of nanoisland films. First, nanoparticle-polymer multilayer films are prepared with layer-by-layer assembly. Nanoparticle multilayer films are then annealed at $~500^{\circ}C$ in air to evaporate organic matters from the films. During the annealing process, the nanoparticles on the solid surface undergo nucleation and coalescence, resulting in the formation of nanostructured gold island arrays. By controlling the overall thickness (number of layers) of nanoparticle multilayer films, nanoisland films with various island density and different average sizes are obtained. The surface property of gold nanoisland films is further controlled by the self-assembly of alkanethiols, which results in an increased surface hydrophobicity of the films. The structure and characteristics of these nanoisland film arrays are found to be quite comparable to those of nanoisland films prepared by vacuum evaporation method. However, this self-assembly/annealing protocol is simple and requires only common laboratory supplies and equipment for the entire preparation process.

Fabrication and Characterization of PCL/TiO2 Nanoparticle 3D Scaffold (PCL/TiO2 Nanoparticle 3차원 지지체 제조 및 특성 평가)

  • Kim, Jung-Ho;Lee, Ok Joo;Sheikh, Faheem A.;Ju, Hyung Woo;Moon, Bo Mi;Park, Hyun Jung;Park, Chan Hum
    • Polymer(Korea)
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    • v.38 no.2
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    • pp.150-155
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    • 2014
  • Polycaprolactone (PCL) is a synthetic biodegradable polymer with excellent mechanical properties. $TiO_2$ (titanium dioxide) has a hydrophilic, high density and excellent biocompatibility. In this work, we produced three-dimensional porous scaffolds with PCL and $TiO_2$ nanoparticles using a salt-leaching method. Physical properties of the scaffolds were analyzed by FE-SEM, FTIR, TGA and compressive strength. Interestingly, the addition of $TiO_2$ nanoparticles decreased the water absorption and swelling ratio of the porous scaffolds. However, the compressive strength was increased by $TiO_2$. CCK-8 assay, which is generally used for the analysis of cell growth, shows that $TiO_2$ nanoparticles have no cytotoxicity. Taken together, we suggest that the PLC/$TiO_2$-scaffold can be used for biomedical applications.

Memory Characteristics of Pt Nanoparticle-embedded MOS Capacitors Fabricated at Room Temperature

  • Kim, Sung-Su;Cho, Kyoung-Ah;Kwak, Ki-Yeol;Kim, Sang-Sig
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.3
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    • pp.162-164
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    • 2012
  • In this study, we fabricate Pt nanoparticle (NP)-embedded MOS capacitors at room temperature and investigate their memory characteristics. The Pt NPs are separated from each other and situated between the tunnel and control oxide layers. The average size and density of the Pt NPs are 4 nm and $3.2{\times}10^{12}cm^{-2}$, respectively. Counterclockwise hysteresis with a width of 3.3 V is observed in the high-frequency capacitance-voltage curve of the Pt NP-embedded MOS capacitor. Moreover, more than 93% of the charge remains even after $10^4$ s.