• 제목/요약/키워드: Cu-alloy

검색결과 1,288건 처리시간 0.03초

Ag-Cu-Ti 브레이징 합금의 산화거동 (Oxidation Behavior of Ag-Cu-Tio Brazing Alloys)

  • 우지호;이동복;장희석;박상환
    • 한국세라믹학회지
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    • 제35권1호
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    • pp.55-65
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    • 1998
  • Ag-36.8a%Cu-7.4at%Ti 조성의 브레이징 합금을 Si3N4 기판위에 브레이징한 후 브레이징 합금의 산화거동을 대기중 400, 500, 600$^{\circ}C$에서 조사하였다. 브레이징 합금의 구성원소인 Ag는 산화되지 않고 Cu와 Ti가 산화되며, 산화거동은 포물선적 산화법칙을 따랐다. 브레이징 합금의 산화에 따른 활성화에너지는 80kj/ mol 으로서 소량 첨가된 활성원소인 Ti에 의하여 순수한 Cu의 산화시 활성화에너지보다 감소하였다. 산화 초기에 생성되는 외부산화물은 Cu이온의 외부확산에 의해 성장이 지배되는 Cu산화물로 구성되어 있었다. 산화기간이 경과함에 따라 외부산화물층 아래에서 Cu의 농도는 감소되고 Ag의 농도는 증가하는 농도구배가 발생하여, 브레이징 합금의 산화물은 Cu산화물층(CuO)/Ag잉여층/Cu산화물층(Cu2O)/Ag잉여층의 다층구조를 갖았다. 또한, 분위기중의 산소는 Cu산화물 및 Ag잉여층을 통해 브레이징 합금 내부로 확산되어 브레이징 합금내의 Ti와 반응하여 내부산화물 TiO2를 생성하였다.

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고온초전도 박막선재용 Ni-$W_{xat.%}$ 및 (Ni-$W_{3at.%}$)-$CU_{xat.%}$ 이축배향 금속 기판들의 자기적 특성 (Magnetic Properties of Both Ni-W and (Ni-3%W)-Cu Textured Substrates for ReBCO Coated Conductor)

  • 송규정;김태형;김호섭;고락길;하홍수;하동우;오상수;박찬;유상임;주진호;김민무;김찬중
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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    • pp.28-29
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    • 2006
  • The magnetic properties of a series of both annealed and as-rolled Ni-$W_y$ alloy tapes with compositions y = 0, 1, 3, and 5 at.%, were studied. To compare with Ni-W alloys, the magnetic properties of a series of both annealed and as-rolled $[Ni_{97at.%}W_{3at.%}]_{100-x}Cu_x$ alloy tapes with compositions x = 0, 1, 3, 5 and 7 at.%, were studied, as well. Both the isothermal mass magnetization M(H) of a series of samples, such as both Ni-W and [Ni-W]-Cu alloy tapes, at different fixed temperatures and M(T) in fixed field, were measured using a PPMS-9 (Quantum Design). The degree of ferromagnetism of Ni-$W_y$ alloys have reduced as W-content y increases. Both the saturation magnetization $M_{sat}$ and Curie temperature $T_c$ decrease linearly with W-content y, and both $M_{sat}$ and $T_c$ go to zero at critical concentration of $y_c$ ~ 9.50 at.% W. The effect of Cu addition on both the saturation magnetization $M_sat$ and Curie temperature $T_c$ decrease linearly with Cu-content x in $[Ni_{97at.%}W_{3at.%}]_{100-x}Cu_x$ alloy tapes with compositions x = 0, 1, 3, 5, and 7 at.%. The results confirm that [Ni-W]-Cu alloy tapes can have much reduced ferromagnetism as Cu-content x increases.

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원자력 발전소용 이종재 마찰용접의 최적화와 AE에 의한 실시간 평가에 관한 연구 (Study on Optimization of Dissimilar Friction Welding of Nuclear Power Plant Materials and Its Real Time AE Evaluation)

  • 권상우;오세규;유인종;황성필;공유식
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2000년도 추계학술대회 논문집
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    • pp.42-46
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    • 2000
  • In this paper, joints of Cu-1Cr-0.1Zr alloy to STS316L were performed by friction welding method. Cu-1Cr-0.1Zr alloy is attractive candidate as nuclear power plant material and exibit the best combination of high sts good electrical and thermal conductivity of any copper alloy examined. The stainless steel is a structural material who alloy acts as a heat sink material for the surface heat flux in the first wall. So, in this paper, not only the develop optimizing of friction welding with more reliability and more applicabililty but also the development of in-process rear quility(such as strength and toughness) evaluation technique by acoustic emission for friction welding of such nuclear component of Cu-1Cr-0.1Zr alloy to STS316L steel were performed.

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BCuP계 합금의 쌍롤주조시 주조특성과 미세조직에 미치는 주입온도의 영향 (Effect of Pouring Temperature on the Casting Characteristics and Microstructure of Twin-roll Cast BCuP Alloy)

  • 주대헌;김명호
    • 한국주조공학회지
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    • 제21권4호
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    • pp.232-238
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    • 2001
  • Experimental study on the twin roll strip casting of BCuP-5(Cu-15wt%Ag-wt5%P) alloy was carried out using laboratory scale horizontal type twin roll caster. In this study, among the various operating parameters, such as tundish angle, contact angle, pouring temperature, roll speed, presetting gap of the rolls and kinds of roll and tundish materials, effect of pouring temperature for strip casting of BCuP-5 alloy which has long freezing range of about $170^{\circ}C$ was mainly investigated. BCuP-5 alloy strip was successfully produced when pouring molten metal at lower temperature than its liquidus temperature. Microstructure of the cast strip consists of primary Cu and eutectic. Especially the size of primary Cu phase increased with decreasing of pouring temperature.

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과냉각 액상 구간에서 Cu-based BMG 합금의 결정화와 변형 거동 (Deformation and crystallization of Cu-base BMG alloy in the supercooled liquid region)

  • 박은수;이주호;김휘준;배정찬;허무영
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2007년도 추계학술대회 논문집
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    • pp.143-145
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    • 2007
  • The correlation between crystallization and deformation behavior in the supercooled liquid region (SLR) of a $Cu_{54}Ni_{6}Zr_{22}Ti_{18}$ bulk metallic glass (BMG) alloy is investigated by compression tests, differential scanning calorimetry (DSC), electron energy loss spectrometry (EELS) and high resolution transmission electron microscopy (HRTEM). In the SLR, This BMG alloy was strongly depended on the deformation temperature and the alloy exhibits important change in deformation behavior after a given time which is directly connected to the development of crystallization. Compressive stress impeded decomposition and consequently retarded forming of nano-crystal, which led to enlarge the homogeneous deformation region of the BMG alloy in SLR during compression test.

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Deposition of Cu-Ni films by Magnetron Co-Sputtering and Effects of Target Configurations on Film Properties

  • Seo, Soo-Hyung;Park, Chang-Kyun;Kim, Young-Ho;Park, Jin-Seok
    • KIEE International Transactions on Electrophysics and Applications
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    • 제3C권1호
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    • pp.23-27
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    • 2003
  • Structural properties of Cu-Ni alloy films, such as preferred orientation, crystallite size, in-ter-planar spacing, cross-sectional morphology, and electrical resistivity, are investigated in terms of tar-get configurations that are used in the film deposition by means of magnetron co-sputtering. Two different target configurations are considered in this study: a dual-type configuration in which two separate tar-gets (Cu and Ni) and different bias types (RF and DC) are used and a Ni-on-Cu type configuration in which Ni chips are attached to a Cu target. The dual-type configuration appears to have some advantages over the Ni-on-Cu type regarding the accurate control of atomic composition of the deposited Cu-Ni alloy. However, the dual-type-produced film exhibits a porous and columnar structure, the relatively large internal stress, and the high electrical resistivity, which are mainly due to the relatively low mobility of adatoms. The affects of thermal treatment and deposition conditions on the structural and electrical properties of dual-type Cu-Ni films are also discussed.

열처리 온도에 따른 SnO2/Cu(Ni)/SnO2 다층구조 투명전극의 전기·광학적 특성 (A Study on the Electrical and Optical Properties of SnO2/Cu(Ni)/SnO2 Multi-Layer Structures Transparent Electrode According to Annealing Temperature)

  • 정지원;공헌;이현용
    • 한국전기전자재료학회논문지
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    • 제32권2호
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    • pp.134-140
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    • 2019
  • Oxide ($SnO_2$)/metal alloy (Cu(Ni))/oxide ($SnO_2$) multilayer films were fabricated using the magnetron sputtering technique. The oxide and metal alloy were $SnO_2$ and Ni-doped Cu, respectively. The structural, optical, and electrical properties of the multilayer films were investigated using X-ray diffraction (XRD), ultraviolet-visible (UV-vis) spectrophotometry, and 4-point probe measurements, respectively. The properties of the $SnO_2/Cu(Ni)/SnO_2$ multilayer films were dependent on the thickness and Ni doping of the mid-layer film. Since Ni atoms inhibit the diffusion and aggregation of Cu atoms, the grain growth of Cu is delayed upon Ni addition. For $250^{\circ}C$, the Haccke's figure of merit (FOM) of the $SnO_2$ (30 nm)/Cu(Ni) (8 nm)/$SnO_2$ (30 nm) multilayer film was evaluated to be $0.17{\times}10^{-3}{\Omega}^{-1}$.