• Title/Summary/Keyword: CrS

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Crystal Structure and Magnetic Properties of $(LaS)_xCrS_2(x{\approx}1.20)$ ($(LaS)_xCrS_2(x{\approx}1.20)$의 결정구조와 자기적 특성)

  • Jo, Nam-Ung;Yu, Gwang-Su;Jeong, Hyeong-Jin
    • Korean Journal of Materials Research
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    • v.4 no.6
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    • pp.704-709
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    • 1994
  • The $(LaS)_xCrS_2(x \approx 1.20$) of the incommensurate misfit layer was systhesized from reactant mixture of$La_S_3$,Cr and S at 1273K. Powder X-ray diffration of $(LaS)_xCrS_2(x \approx 1.20$) was indexed as a complex structure consisted with a monoclinic LaS-sublattice, a triclinic $CrS_{2}$-sublattice and their superlattice. The temperature dependence of sublattice dimension was investigated by the X-ray diffraction analysis at low temperature. The magnetic susceptibility of $(LaS)_xCrS_2(x \approx 1.20$) was measured between 77K and room temperature using a Faraday balance method. $(LaS)_xCrS_2(x \approx 1.20$) was paramagnetic on a $\sigma$-H plot at room temperature. The observed effective magnetic moment( p dr) was in fair agreement with the value calculated by spin-only contribution for $Cr^{3+}$ and spin and orbital contribution for $La^{3+}$.

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SIS로써 AMADEUS CRS 사례연구

  • 정기억
    • Proceedings of the Korea Association of Information Systems Conference
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    • 1998.10a
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    • pp.178-187
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    • 1998
  • 전략정보시스템의 성공사례로서 항상 제시하고 있는 것이 항공사의 CRS이다. 처음 CRS가 출현했을 때 항공사들은 CRS를 통해서 그렇지 않은 항공사에 비해 상당한 전략적 우위를 지킬 수 있었다. 그러나 현재의 경우 이러한 CRS의 전략적 활용의 예는 그다지 중 요한 의미를 갖지 못할 수 도 있다. 왜냐하면 이제 어느 항공사(서비스제공자)나 어느 여행 사(사용자)의 경우도 이러한 CRS를 활용하지 않는 경우는 없기 때문이다. 그렇다고 해서 CRS가 전략적 가치가 전혀 없다고 단정 지울 수 없다. 만일 특정의 CRS가 다른 CRS와의 차별화 된 기능을 갖고 있다면 그것은 충분한 전략적 가치가 있다고 볼 수 있다. 즉, 보다 다양한 기능, 광범위한 데이터 량, 풍부하게 제공되는 정보 그리고 사용상 편리성 등의 특 성을 가진 CRS는 전략적 의미가 있는 것이다. 본 연구는 이러한 입장에서 CRS의 차별화 된 전략적 특성을 파악하기 위하여 AMADEUS에 대한 사례연구를 수행하였다. 사례를 분석 한 결과 일부 차별적인 기능에 대해서는 전략적 특성을 갖고 있다고 볼 수 있었다.

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First-principles Study on Half-metallicity and Magnetism for Zinc-blende CrS(001) Surface (Zinc-blende 구조를 가진 CrS(001) 표면에서의 반쪽금속성과 자성에 대한 제일원리 연구)

  • Byun, Y.S.;Lee, J.I.
    • Journal of the Korean Magnetics Society
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    • v.15 no.5
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    • pp.257-260
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    • 2005
  • We investigated the half-metallicity and magnetism for the zinc-blende CrS(001) surfaces by use of the full-potential linearized augmented plane wave (FLAPW) method. We considered two-types of (001) surfaces terminated by Cr (Cr-Term) and S (S-Term) atoms, respectively. From the calculated layer-by-layer density of states, it is found that both of the systems retain the half-metallicity at the (001) surfaces. The calculated magnetic moment ($4.07\;{\mu}_B$) for the CrS(S) atom in Cr-Term is enhanced considerably compared to the bulk value ($3.61\;{\mu}_B$) while that ($3.15\;{\mu}_B$) of the Cr(S-1) in S-Term is much reduced.

First-principles Study on the Half-metallicity and Magnetism of the (001) Surfaces of (AlP)1/(CrP)1 Superlattice ((AlP)1/(CrP)1 초격자계에서 (001) 표면의 자성과 반쪽금속성에 대한 제일원리 연구)

  • Bialek, Beata;Lee, Jae Il
    • Journal of the Korean Magnetics Society
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    • v.25 no.6
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    • pp.175-179
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    • 2015
  • The half-metallicity and magnetism of the (001) surfaces of $(AlP)_1/(CrP)_1$ superlattice were investigated by means of FLAPW (Full-potential Liniarized Augmented Plane Wave) method. We considered four types of (001) surface termination, i.e., Al(S)-, Cr(S)-, P(S)Al(S-1)- and P(S)Cr(S-1)-term systems. We found that only Cr(S)-term system maintains the half-metallicity at the surface as only this system has the calculated magnetic moment of integer number of bohr magnetons. The magnetic moment of Cr(S) atom in the system was $3.02{\mu}_B$ which was increased from the bulk value by the effects of band narrowing and increased spin-splitting at the surface. The electronic density of states of the P(S) atom in the P(S)Al(S-1)-term showed very sharp surface states due to the broken $p_z$ bonds at the surface. We found there is still a strong p-d hybridization between the P(S) and Cr(S-1) layers in the P(S)Cr(S-1)-term which causes a considerable increase of magnetic moment of P(S) atom.

Synthesis of CdxZn1-xS@MIL-101(Cr) Composite Catalysts for the Photodegradation of Methylene Blue

  • Yang, Shipeng;Peng, Siwei;Zhang, Chunhui;He, Xuwen;Cai, Yaqi
    • Nano
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    • v.13 no.10
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    • pp.1850118.1-1850118.17
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    • 2018
  • Nanoparticles of the semiconductor catalyst $Cd_xZn_{1-x}S$ were embedded into the metal organic framework MIL-101(Cr) to obtain $Cd_xZn_{1-x}S@MIL-101$(Cr) nanocomposites. These materials not only possess high surface areas and mesopores but also show good utilization of light energy. The ultraviolet-visible diffuse reflectance patterns of $Cd_xZn_{1-x}S@MIL-101$(Cr) nanocomposites showed that $Cd_{0.8}Zn_{0.2}S@MIL-101$(Cr) possessed good visible light response ability among the synthesized nanocomposites. The photocatalytic performance of the $Cd_xZn_{1-x}S@MIL-101$(Cr) nanocomposites were tested via degradation and mineralization of methylene blue in neutral water solution under light irradiation using a 300W xenon lamp. As a result, using $Cd_{0.8}Zn_{0.2}S@MIL-101$(Cr) as a catalyst, 99.2% of methylene blue was mineralized within 30 min. Due to the synergistic effect of adsorption by the MIL-101(Cr) component and photocatalytic degradation provided by the $Cd_{0.8}Zn_{0.2}S$ component, the $Cd_{0.8}Zn_{0.2}S@MIL-101$(Cr) catalyst displayed superior photocatalytic performance relative to $Cd_{0.8}Zn_{0.2}S$ and MIL-101(Cr). Furthermore, $Cd_{0.8}Zn_{0.2}S@MIL-101$(Cr) possessed excellent stability during photodegradation and exhibited good reusability. The remarkable photocatalytic performance of $Cd_{0.8}Zn_{0.2}S@MIL-101$(Cr) is likely due to the effective transfer of electrons and holes at the heterojunction interfaces.

The Significance of Serum $Beta_2-Microglobulin$ Measurement in Various Renal Diseases (각종(各種) 신질환(腎疾患)에서의 혈청(血淸) $\beta_2-microglobulin$ 측정(測定)의 의의(意義))

  • Koong, Sung-Soo;Oh, Ha-Yong;Han, Jin-Suk;Lee, Jung-Sang
    • The Korean Journal of Nuclear Medicine
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    • v.19 no.1
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    • pp.127-136
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    • 1985
  • To evaluate change of serum $beta_2-microglobulin$ concentration$(s\beta_2-MG)$ and the usefulness of $s\beta_2-MG$ and $s\beta_2-MG/serum$ creatinine concentration(sCr) ratio in various renal diseases, $s\beta_2-MG$ and sCr were measured in 25 normal controls and 90 patients of various renal diseases(16 cases of glomerulonephritis, 12 cases of acute renal failure, 8 cases of chronic renal failure, 24 cases of nephrotic syndrome, 15 cases of tubulointerstitial diseases and 15 cases of lupus nephritis) using $Phadebas^\circledR$ $Beta_2-Micro$ Test kits. The results were as follows; 1) In normal control, the mean value of $s\beta_2-MG$ was $1.65{\pm}0.41mg/l$ and the mean value of $s\beta_2-MG/sCr$ ratio was $0.14{\pm}0.05$. 2) In various renal diseases, the mean value of $s\beta_2-MG$ was $6.74{\pm}5.47mg/l$. The mean value of $s\beta_2-MG/sCr$ ratio was $0.24{\pm}0.11$ and significantly elevated than that of normal control. (p<0.05) 3) The correlation between $s\beta_2-MG$ and sCr in glomerular and tubulointerstitial disease was log $s\beta_2-MG-0.90$ log sCr-0.48 and its correlation coefficient was 0.78(p<0.05). 4) In glomerular disease, the correlation between $s\beta_2-MG$ and sCr was log $s\beta_2-MG-0.89$ log sCr-0.46(r - 0.76) and in tubulointerstitial disease, it was log, $s\beta2-MG-0.95$ log sCr-0.59 (r-0.87). There was no significant difference between the two groups(p<0.05). 5) Among 32 cases of glomerular and tubulointerstitial disease patients, whose sCr was within normal range, 17 cases showed elevated $s\beta_2-MG$. The mean values of $s\beta_2-MG/sCr$ ratio in these patients was $0.30{\pm}0.14$ and significantly elevated than that of normal control(p<0.05). 6) In 15 cases of lupus nephritis, 12 cases showed elevated $s\beta_2-MG$ with normal sCr and 12 cases showed elevated $s\beta_2-MG/sCr$ ratio. With above results, it was found that the $s\beta_2MG$ can be used as an index of glomerular filtration rate as in the case of sCr and that $s\beta_2-MG/sCr$ ratio can be used as a tool in early detection of slightly decreased glomerular filtration rate and in detection of the renal disease of increased $\beta_2-MG$ production.

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A Study on the Behaviour of High Temperature Corrosion of Fe-22Cr-5Al-X(X=Zr,Y) (Fe-22Cr-5Al-X(X=Zr,Y)합금의 고온 부식거동에 관한 연구)

  • Lee, Byeong-U;Park, Heung-Il;Kim, Jung-Seon;Lee, Gwang-Hak;Kim, Heung-Sik
    • Korean Journal of Materials Research
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    • v.7 no.10
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    • pp.898-907
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    • 1997
  • Fe-22Cr-5AI-X(X=Zr, Y)합금을 1143K, 고온 황화(P$s_{2}$=1.11x$10^{-7}$atm, P$O_{s}$ =3.11x$10^{-20atm}$) 및 황화/산화 (P$s_{2}$=8.31x$10^{-8}$atm, P$O_{s}$ =3.31x$10^{-18atm}$) 환경의 복합가스 분위기에서 1-30시간동안 노출하여 합금표면에 형성된 부식층을 관찰하여 SEM/EDS로 분석하였다. Fe-22Cr-5AI합금은 고온 부식환경에서 부식 생성물의 성장은 포물선법칙을 따르고 주요 성분은 결함이 많고 다공질인 철과 크롬의 황화물[(Fe, Cr)Sx]이므로 고온 내식성이 감소하였다. Zr을 1wt%첨가한 Fe-22Cr-5AI합금의 고온 부식거동은 Y을 1wt%첨가한 합금과 비슷한 거동을 나타내었다. 황화환경에서는 Cr의 선택 황화에 의한 크롬 황화물(CrS)이 생성되고 노출시간의 경과에 따라 (Fe, Cr)Sx나 (Cr, Fe)Sx 등의 황화물의 성장으로 고온 내식성이 감소하였다. 그러나 황화/산화환경에서는 초기에는 알루미늄산화물(A $I_{2}$ $O_{3}$)및 지르코늄산화물(Zr $O_{2}$)등이 생성되어 보호적이었으나 15시간이후 부터 (Fe, Cr)Sx나 (Cr, Fe)Sx 의 황화물의 성장으로 고온 내식성이 감소하였다.

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Corrosion of Fe-(8.5~36.9) wt% Cr Alloys at 600~800℃ in (N2, H2S, H2O)-Mixed Gases (Fe-(8.5~36.9) wt% Cr합금의 600~800℃, (N2,H2S,수증기)-혼합 가스분위기에서의 부식)

  • Kim, Min Jung;Lee, Dong Bok
    • Korean Journal of Metals and Materials
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    • v.50 no.3
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    • pp.218-223
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    • 2012
  • Fe-(8.5, 18.5, 28.3, 36.9) wt% Cr alloys were corroded between 600 and $800^{\circ}C$ for up to 70 h in a 1 atm gas mixture that consisted of 0.0242 atm of $H_2S$, 0.031 atm of water vapor, and 0.9448 atm of nitrogen gas. Their corrosion resistance increased with an increment in the Cr content. The Fe-8.5%Cr alloy corroded fast, forming thick, fragile, nonadherent scales that consisted primarily of an outer FeS layer and an inner (Fe, Cr, O, S)-mixed layer. The outer FeS layer grew into the air by the outward diffusion of $Fe^{2+}$ ions, whereas the inner mixed layer grew by the inward diffusion of oxygen and sulfur ions. At the interface of the outer and inner scales, voids developed and cracking occurred. The Fe-(18.5, 28.3, 36.9)% Cr alloys displayed much better corrosion resistance than the Fe-8.5Cr alloy, because thin $Cr_2O_3$ or $Cr_2S_3$ scales formed.

Effects of Cr Underlayer on Microstructural and Magnetic Properties of Sputtered CoNiCr/Cr, CoCrTa/Cr Films (Cr underlayer가 Sputter 증착한 CoNiCr/Cr, CoCrTa/Cr longitudinal 자기기록매채의 미세구조와 자성특성에 미치는 영향)

  • Park, S.C.;Ahn, B.T.;Im, H.B.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1992.11a
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    • pp.7-10
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    • 1992
  • CoNiCr/Cr and CoCrTa/Cr for longitudinal magnetic recording media were. prepared on Coming 7059 glass by RF magnetron sputtering. The thickness of Cr underlayer was varied from 500 to $3000{\AA}$ and. that of magnetic layer was $700{\AA}$. Coercivity and squareness were measured using V.S.M.(vibrating sample magnetometer). The coercivity of films increased with increasing Cr thickness when the films were unannealed. The coercivity of the films annealed in a 10 mtorr vacuum increased initially with annealing time and then saturated with further increase in annealing time. The coercivity value difference between the unannealed and annealed films increased with increasing the thickness of Cr underlayer No significant change was found in squareness after anneal, regardless of Cr underlayer thickness.

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Phonetic Realization of Aspiration of Stops in English /Cr/ and /sCr/ Clusters and their Syllable Structure at the Phonetic Level: a Comparison between Two Speaker Groups (영어의 /Cr/과 /sCr/ 자음군 내 폐쇄음의 기식성 실현과 음성 단위의 음절구조: 두 화자집단 간 비교)

  • Sohn, Hyang-Sook
    • Phonetics and Speech Sciences
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    • v.6 no.3
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    • pp.121-130
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    • 2014
  • This study investigates the acoustic property of aspiration realized in English voiceless stops of /Cr/ and /sCr/ clusters. VOT is measured from stops in these clusters produced by two groups; one from native speakers of English and the other from Korean native speakers. Aspiration of stops in different types of clusters is compared to various phonological factors such as location of stress, syllable type, and position in word. Pursuing the idea that phonetic realization is correlated with phonological representation, attempts are made to account for the gradient nature of aspiration of stops on the basis of syllable structure at the phonetic level, which may vary in the wake of resyllabification. Voiceless stops in /Cr/ and /sCr/ clusters are further compared to results obtained in the previous study on /sC/ cluster. Variations in aspiration are also characterized in terms of segmental precedence relation of stops in the clusters, namely, post-[s], pre-[r], or both.