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CHARACTERISTICS OF FIRE PROTECTIVE COATING THE TERNARY SOLUBLE SILICATE

  • Lee, Nae-Woo;Choi, Jae-Wook;Kim, Jeong-Hun
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 1997.11a
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    • pp.120-129
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    • 1997
  • The fire protective coating can reduce certain damages in case of fire, also conserve energy by thermal insulation and prevent corrosion and errosion in normal daily life by means of blocking thermal transfer, that were generally made of organic, inorganic and metallic materials as adiabatic coating. In case of inorganic material such as soluble silicate, it produces less toxic substances which are exposed to Ore, and have a plenty of raw material. Also inorganic thermal insulator is good in heat resistance. To develope such a excellent inorganic thermal insulator, the study of fire protective coating using the alkali silicate is necessary The principle of intumescence for alkali silicate is from rapid evolution of water in the coating material, the quantity of water in it is of course influenced on the degree of intumescence. The phenomenon of intumescence in ternary silicate is increased as the radius of ion is bigger, and this is caused by evolution of so many kinds of water. The individual degree of intumescence is ordered like this ; $K^+$ > $Na^+$ > $Li^+$ . The best protection effect is similarity found to intumescence of ternary silicate. The result of X-ray diffraction analysis indicates that $KHSi_2O_5$ is an important ingredient in K-silicate.

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Research Trends on Chemical Mechanical Polishing Using Ultraviolet Light (자외선 광을 활용하는 화학기계적 연마에 관한 연구 동향)

  • Lee, Hyunseop
    • Tribology and Lubricants
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    • v.38 no.6
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    • pp.247-254
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    • 2022
  • Chemical mechanical polishing (CMP) is a hybrid surface-polishing process that utilizes both mechanical and chemical energy. However, the recently emerging semiconductor substrate and thin film materials are challenging to process using the existing CMP. Therefore, previous researchers have conducted studies to increase the material removal rate (MRR) of CMP. Most materials studied to improve MRR have high hardness and chemical stability. Methods for enhancing the material removal efficiency of CMP include additional provision of electric, thermal, light, mechanical, and chemical energies. This study aims to introduce research trends on CMP using ultraviolet (UV) light to these methods to improve the material removal efficiency of CMP. This method, photocatalysis-assisted chemical mechanical polishing (PCMP), utilizes photocatalytic oxidation using UV light. In this study, the target materials of the PCMP application include SiC, GaN, GaAs, and Ru. This study explains the photocatalytic reaction, which is the basic principle of PCMP, and reviews studies on PCMP according to materials. Additionally, the researchers classified the PCMP system used in existing studies and presented the course for further investigation of PCMP. This study aims to aid in understanding PCMP and set the direction of future research. Lastly, since there have not been many studies on the tribology characteristics in PCMP, research on this is expected to be required.

Rate-capability response of graphite anode materials in advanced energy storage systems: a structural comparison

  • Farooq, Umer;Doh, Chil-Hoon;Pervez, Syed Atif;Kim, Doo-Hun;Lee, Sang-Hoon;Saleem, Mohsin;Sim, Seong-Ju;Choi, Jeong-Hee
    • Carbon letters
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    • v.17 no.1
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    • pp.39-44
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    • 2016
  • The work presented in this report was a detailed comparative study of the electrochemical response exhibited by graphite anodes in Li-ion batteries having different physical features. A comprehensive morphological and physical characterization was carried out for these graphite samples via X-ray diffraction and scanning electron microscopy. Later, the electrochemical performance was analyzed using galvanostatic charge/discharge testing and the galvanostatic intermittent titration technique for these graphite samples as negative electrode materials in battery operation. The results demonstrated that a material having a higher crystalline order exhibits enhanced electrochemical properties when evaluated in terms of rate-capability performance. All these materials were investigated at high C-rates ranging from 0.1C up to 10C. Such improved response was attributed to the crystalline morphology providing short layers, which facilitate rapid Li+ ions diffusivity and electron transport during the course of battery operation. The values obtained for the electrical conductivity of these graphite anodes support this possible explanation.

Assessment of vertical root fracture using cone-beam computed tomography

  • Moudi, Ehsan;Haghanifar, Sina;Madani, Zahrasadat;Alhavaz, Abdolhamid;Bijani, Ali;Bagheri, Mohammad
    • Imaging Science in Dentistry
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    • v.44 no.1
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    • pp.37-41
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    • 2014
  • Purpose: The aim of this study was to investigate the accuracy of cone-beam computed tomography (CBCT) in the diagnosis of vertical root fractures in a tooth with gutta-percha and prefabricated posts. Materials and Methods: This study selected 96 extracted molar and premolar teeth of the mandible. These teeth were divided into six groups as follows: Groups A, B, and C consisted of teeth with vertical root fractures, and groups D, E, and F had teeth without vertical root fractures; groups A and D had teeth with gutta-percha and prefabricated posts; groups B and E had teeth with gutta-percha but without prefabricated posts, and groups C and F had teeth without gutta-percha or prefabricated posts. Then, the CBCT scans were obtained and examined by three oral and maxillofacial radiologists in order to determine the presence of vertical root fractures. The data were analyzed using IBM SPSS 20.0 (IBM Corp., Armonk, NY, USA). Results: The kappa coefficient was $0.875{\pm}0.049$. Groups A and D showed a sensitivity of 81% and a specificity of 100%; groups E and B, a sensitivity of 94% and a specificity of 100%; and groups C and F, a sensitivity of 88% and a specificity of 100%. Conclusion: The CBCT scans revealed a high accuracy in the diagnosis of vertical root fractures; the accuracy did not decrease in the presence of gutta-percha. The presence of prefabricated posts also had little effect on the accuracy of the system, which was, of course, not statistically significant.

Degradation of the Herbicide Butachlor by Laboratory-synthesized Nanoscale $Fe^0$ in Batch Experiments

  • Kim, Hyang-Yeon;Kim, In-Kyung;Han, Tae-Ho;Shim, Jae-Han;Kim, In-Seon
    • Journal of Applied Biological Chemistry
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    • v.49 no.3
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    • pp.101-105
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    • 2006
  • Degradation of the herbicide butachlor was investigated using laboratory-synthesized zerovalent iron ($Fe^0$). The synthesized zerovalent iron was determined to be nanoscale powder by scanning electron microscopic analysis. To investigate degradation of butachlor using the synthesized nanoscale zerovalent iron, time-course batch experiments were conducted by treating the solution of butachlor formulation with the iron. More than 90% degradation of butachlor was observed by iron treatment within 24 h. The synthesized nanoscale zerovalent iron showed an increase in particle aggregation in the batch tests. Green rust formation and a pH drop in solutions were observed, suggesting that the oxidation of the iron occurred. When the iron was extracted with dichloromethane, a negligible concentration was found in the extract, suggesting that butachlor did not bind to the iron particles. GC/MS analysis detected the dechlorinated product as a major degradation product of butachlor in the solutions. The data indicate that laboratory-synthesized zerovalent iron functioned as a reductant to remove electron-withdrawing chlorine, giving the dechlorinated product.

Studies on the Changes of Oligosaccharide Contents in Rehmanniae Radix preparata According to Various Processing methods (포제에 따른 숙지황(熟地黃)의 당(糖) 성분 변화 연구)

  • Choi, Ho-Young;Kwon, Seung-Ro;Kim, Hyo-Geun;Ham, In-Hye;Lee, Jae-Jun;Lee, Je-Hyeon;Hong, Seon-Pyo;Kim, Do-Hoon
    • The Korea Journal of Herbology
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    • v.22 no.4
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    • pp.261-270
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    • 2007
  • Objective : The 5-HMF was not index material suitable to do the quality control of Rehmanniae Radix Preparata. In this study, We estimated the changes of oligosaccharide contents in Rehmanniae Radix Preparata using high-performance anion-exchange chromatography with pulsed amperometric detection(HPAEC-PAD). Methods : The analysis of oligosaccharide was conducted by HPAEC-PAD with Carbopac PA1, $250{\times}4mm$, 5um, and Carbopac PA1 guard column. Column temperature was kept at $30^{\circ}C$. Elution was carried out at 1000 ${\mu}l/min$ with 70mM NaOH and the injection volume was $10{\mu}l$. Each component was detected by PAD. Results : Nine constituents were found from merchandising Rehmanniae Radix Preparata(MR), while seven constituents were found in various processed Rehmanniae Radix Preparata. Not all constituents were defined but stachyose and raffinose were found in all cases. And The most common constituents of Rehmanniae radix was stachyose. In the course of processing, most of stachyose and raffinose were decreased. Stachyose was decreased slowly in the course of processing with rice wine(RR), amomi and rice wine(AR), and crataegi and rice wine(CR). However stachyose was decreased rapidly in the course of processing with fresh rehmannia juice(FR). The method with crataegi and rice wine(CR) showed the smallest decrease of stachyose. And processing method with crataegi and rice wine(CR) showed the most abundant amount for stachyose after the nineth processing. Conclusion : The changes of oligosaccharides in the course of processing were a very important direct barometers to do the quality control and set up a standard of Rehmanniae Radix Preparata.

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A Study on the Improvement of Marine Pollution Response Education Program of Korea Coast Guard Academy - Focusing on Comparison between Domestic and Foreign Curriculums - (해양경비안전교육원 해양오염방제교육 프로그램 개선에 관한 연구 - 유류오염 방제 교육과정에 대한 국내외 비교를 중심으로 -)

  • Choi, Hyun Kue
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.23 no.4
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    • pp.365-375
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    • 2017
  • Approximately 250 marine pollution accidents involving oil and HNS spills are reported every year in the Republic of Korea. It is necessary that a strengthen of specialization of marine pollution response personnel on marine pollution response due to a diminution of damage when a major oil and HNS spill incident occurred, as in the case of the M/V Heibei Spirit and the M/V Maritime Maisie. In regard to this, the International Maritime Organization (IMO) has planned to revise the OPRC Model Training Course to strengthen expertise for oil spill incident responses. Through a comparison of curriculum with the Korea Coast Guard Academy (KCGA) program, a revised IMO Model Course and the OSRL training institute, this study recommends the following improvements for the education program of the KCGA in response to oil spills. This study suggests several options in line with this approach to revise the oil spill response education curriculum, exercise, discussions and making materials. Accreditation of the KCGA as an institute that provides an IMO Model training course developed according to the revised IMO Model Course material is proposed.

A Study on the Resistance of Freezing-Thawing for the Material of Concrete or Asphalt Using Smashed Rock (쇄석을 이용한 콘크리트 및 아스팔트용 재료의 동결융해 저항성)

  • Kim, Young-Su;Bang, In-Ho;Heo, No-Young;Lee, Jea-Ho;Choi, Jeong-Ho
    • Journal of the Korean GEO-environmental Society
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    • v.3 no.2
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    • pp.35-47
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    • 2002
  • Soil and rock were yielded during construction of subway in Taegu. Produced rock is a kind of a sedimentary rock with low strength and low durability of shrinkage. So it is difficult using for resources engineering. But in our country, it is very important to use material resources due to lack of natural resources. In this study, after cracking sedimentary rock like black shale and red shale, they are compared with granite which usually used road constriction field to investigate property of use for road construction. Consequently, the engineering character of origin rock is satisfactory, but the soundness test, black shale and red shale are less than KS 12.9%, 37.5% respectively. The result of concrete freezing-thawing test shows that the strength among three materials is not a wide difference but red shale has relatively low strength. The result of asphalt freezing-thawing test with 50 cycles indicates that the stability of red shale in lower than KS 484~561kg on base course, 336~375kg on surface course respectively. A further research should be needed for propriety to the material of shale.

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The Effects of Learning When We Use "Swatch" as Studying Material in Economics Class of Highschool Curriculum - Centered on "Cloth" Contents in Highschool Home Economics Class - (고등학교 가정교과에서 옷감실물을 학습자료로 활용한 경우의 학습효과 - 고등학교 가정 교과 "옷감"내용을 중심으로 -)

  • 이순희;김병미
    • Journal of Korean Home Economics Education Association
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    • v.13 no.2
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    • pp.15-24
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    • 2001
  • The purpose of this study is to find out practical teaching material about$\boxdr$Cloth$\boxul$part of home economics course in highschool and prove it's effect on learning as the result of applying to teaching and learning activities. The objects of this study were 144 first grade students of Puyo girl's high school located in Puyo county of Chung-nam province. They were identified to have the same quality through such inspections as intelligence quotient and previous scholastic ability test. Experiment group is composed of 72 students of two class in first grade and those students utilized swatch. Controlled group is also made up of 72 students like experiment group and they didn't use swatch. The procedure of this study was as follows : First we collected the real clothing material which was necessary in $\boxdr$Cloth$\boxul$part of high school home economics and made teaching plan that could be used to make use of swatch. In this study. we first seek the averages and variations to know how much is the influence of using real things as the studying materials on the class. Then we verified the level of attention to compare and the level of student's schoolwork accomplishment. interest and attitude between experiment group that used the swatch and controlled group who didn't use those material. The result of this study are as follow : 1) After using swatch. students'attitude toward receiving information was getting better. 2) Students'interest toward$\boxdr$Cloth$\boxul$part was getting higher. 3) Scholastic accomplishment of experimental group became higher than that of controlled group.

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Automation of Fuel Filter Manufacturing Process Via IT Convergence (IT융합기반의 연료필터 제조공정 자동화)

  • Yun, Suck-Chang;Han, Woo-Hyun;Yoon, Dal-Hwan
    • Journal of IKEEE
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    • v.19 no.1
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    • pp.64-72
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    • 2015
  • In this paper, we have developed the gantry automation system via information technology (IT) to improve the productivity of fuel filter manufacturing process. The monitoring system of manufacturing process plays an important role in analyzing the defective products as well as improving the production yield rate. The experimental results of 3 months with 10000 samples validate that the error rate is decreased from 0.65 % to 0.45 %. Also, the defect of raw material is decreased via monitoring of material tools which can notify the time for replacement and accurate insertion of raw materials to the loader. The productivity is increased by reducing the process time from 94.7 sec to 78.8 sec per raw material through comparing the whole manufacturing courses : from inserting of raw material to outcome of product. The process time is decreased by 20.2 % by automation of inserting and outcome course. Moreover, safety of worker as well as reduction of transfer time are highly related with increase of productivity.