• 제목/요약/키워드: Composites materials

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탄소강화 탄소나노튜브 섬유 복합소재 연구 동향 (A Review of Carbon-Reinforced Carbon Nanotube Fibers Composites)

  • 이동주;류성우;구본철
    • Composites Research
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    • 제32권3호
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    • pp.127-133
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    • 2019
  • 탄소나노튜브는 이론적인 기계적, 전기적 물성이 우수함에도 불구하고 아직까지 그 수준에 도달하고 있지 않다. 특히나 인장 강도는 10% 미만의 수준 정도에 그치고 있어 이를 보안하기 위한 연구가 활발히 진행되고 있다. 기계적 강도를 향상하기 위한 방법으로는 긴 탄소나노튜브의 합성, 배향 외에 화학적 가교, 수소결합, 고분자 함침 등의 방법이 연구되고 있다. 본 총설 논문에서는 탄소소재의 전구체인 폴리아크릴로니트릴(PAN), 폴리도파민(PDA)을 탄소나노튜브 섬유에 코팅 또는 함침하여 탄화 공정을 거쳐 고강도 고전도성 탄소나노튜브 섬유/탄소 복합소재를 제조하는 연구를 소개하고자 한다.

산화그래핀을 적용한 고반응성 Al/CuO 나노복합재 제조 및 분석 (Fabrication and Characterization of Highly Reactive Al/CuO Nano-composite using Graphene Oxide)

  • 임예슬
    • 한국분말재료학회지
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    • 제26권3호
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    • pp.220-224
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    • 2019
  • The aluminum (Al)/copper oxide (CuO) complex is known as the most promising material for thermite reactions, releasing a high heat and pressure through ignition or thermal heating. To improve the reaction rate and wettability for handling safety, nanosized primary particles are applied on Al/CuO composite for energetic materials in explosives or propellants. Herein, graphene oxide (GO) is adopted for the Al/CuO composites as the functional supporting materials, preventing a phase-separation between solvent and composites, leading to a significantly enhanced reactivity. The characterizations of Al/CuO decorated on GO(Al/CuO/GO) are performed through scanning electron microscopy, transmission electron microscopy, and energy dispersive X-ray spectroscopy mapping analysis. Moreover, the functional bridging between Al/CuO and GO is suggested by identifying the chemical bonding with GO in X-ray photoelectron spectroscopy analysis. The reactivity of Al/CuO/GO composites is evaluated by comparing the maximum pressure and rate of the pressure increase of Al/CuO and Al/CuO/GO. The composites with a specific concentration of GO (10 wt%) demonstrate a well-dispersed mixture in hexane solution without phase separation.

Experimental Investigation of Mechanical and Tribological Characteristics of Al 2024 Matrix Composite Reinforced by Yttrium Oxide Particles

  • Hamada, Mohanad Lateef;Alwan, Ghazwan Saud;Annaz, Abdulkader Ahmed;Irhayyim, Saif Sabah;Hammood, Hashim Shukur
    • 한국재료학회지
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    • 제31권6호
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    • pp.339-344
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    • 2021
  • Composite materials offer distinct and unique properties that are not naturally inherited in the individual materials that make them. One of the most attractive composites to manufacture is the aluminum alloy matrix composite, because it usually combines easiness of availability, light weight, strength, and other favorable properties. In the current work, Powder Metallurgy Method (PMM) is used to prepare Al2024 matrix composites reinforced with different mixing ratios of yttrium oxide (Y2O3) particles. The tests performed on the composites include physical, mechanical, and tribological, as well as microstructure analysis via optical microscope. The results show that the experimental density slightly decreases while the porosity increases when the reinforcement ratio increases within the selected range of 0 ~ 20 wt%. Besides this, the yield strength, tensile strength, and Vickers hardness increase up to a 10 wt% Y2O3 ratio, after which they decline. Moreover, the wear results show that the composite follows the same paradigm for strength and hardness. It is concluded that this composite is ideal for application when higher strength is required from aluminum composites, as well as lighter weight up to certain values of Y2O3 ratio.

액상가압공정으로 제조된 탄탈륨 연속섬유 강화 비정질 복합재료의 미세조직과 기계적 성질 (Microstructure and Mechanical Properties of Tantalum-Continuous-Fiber-Reinforced Amorphous Matrix Composites Fabricated by Liquid Pressing Process)

  • 이규홍;이상복;이상관;이성확
    • 대한금속재료학회지
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    • 제46권7호
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    • pp.403-411
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    • 2008
  • Zr-based amorphous alloy matrix composites reinforced with tantalum continuous fibers were fabricated by liquid pressing process, and their microstructures and mechanical properties were investigated. About 60 vol.% of tantalum fibers were homogeneously distributed inside the amorphous matrix, which contained a small amount of polygonal crystalline particles. The ductility of the tantalum-continuous-fiber-reinforced composite under tensile or compressive loading was dramatically improved over that of the monolithic amorphous alloy, while maintaining high strength. The consequential observation of the tensile deformation and fracture behavior of the composite showed the formation of multiple shear bands and multiple necking, crack deflection in the amorphous matrix, and obstruction of crack propagation by ductile fibers, thereby resulting in very high tensile elongation of 7.2%. These findings suggested that the liquid pressing process was useful for the development of amorphous matrix composites with improved ductility.

용융가압함침공정으로 제조된 TiC 세라믹 입자 강화 철강복합재의 염수환경에서의 부식 특성 (Corrosion Behaviors of TiC Ceramic Particulate Reinforced Steel Composites Fabricated by Liquid Pressing Infiltration Process in Salt Water Environment)

  • 이영환;고성민;신상민;조승찬;김양도;김정환;이상관;이상복
    • Composites Research
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    • 제33권5호
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    • pp.251-255
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    • 2020
  • 본 연구에서는 용융가압함침공정을 이용하여 제조된 TiC 세라믹 입자강화 철강복합재를 제조하고 상용구상흑연주철과 비교를 위하여 미세조직 분석 및 경도 등 기초물성과 선박 해양 분야등의 적용가능성 검토를 위하여 염수환경에서의 부식 특성에 관한 연구를 진행하였다. 염수환경에서의 부식특성 비교 결과 구상흑연주철 대비 부식전위와 부식전류밀도 모두 낮은 값을 나타내었고, 낮은 연간부식률을 통하여 TiC-Fe 금속복합재의 내식성이 더 뛰어난 것을 확인하였다.

BCB Resin-BNT 복합 기판 소재의 제조 및 특성 평가 (Preparation and Characterization of BCB Resin-BNT Composite Substrate Materials)

  • 김운용;전명표;조정호;김병익;이용현;명성재;한익현;신동욱
    • 한국세라믹학회지
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    • 제44권5호
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    • pp.179-183
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    • 2007
  • BCB $Resin-BaNd_2Ti_4O_{12}$(BNT) composites with BNT contents were prepared by tape casting method and epoxy resin-BNT composites were prepared by using heating press. Their dielectric properties and microstructures were investigated. The dielectric properties such as dielectric constant and dielectric loss at 1 MHz for epoxy resin-BNT composites and BCB resin-BNT composites are improved with an increase of BNT volume fraction. The dielectric constant of the Epoxy-BNT composite increased from 5.9 to 7.8 as the volume fraction of BNT increased from 15 to 25. The dielectric constant of the BCB-BNT composite increased from 9.1 to 15.5 as the volume fraction of BNT increased from 30 to 50. The dielectric behavior of BCB-BNT system can be explained by Lichtenecker's equation. The dielectric constant of epoxy resin-BNT composite is smaller than that of BCB resin-BNT composite. These results are considered to be related with the dispersion of BNT filler in polymer matrix from the result of SEM photograph.

Reduction of Thermal Conductivity Through Complex Microstructure by Dispersion of Carbon Nanofiber in p-Type Bi0.5Sb1.5Te3 Alloys

  • P. Sharief;B. Madavali;Y. Sohn;J.H. Han;G. Song;S.H. Song;S.J. Hong
    • Archives of Metallurgy and Materials
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    • 제66권3호
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    • pp.803-808
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    • 2021
  • The influence of nano dispersion on the thermoelectric properties of Bi2Te3 was actively investigating to wide-spread thermoelectric applications. Herein this report, we have systematically controlled the microstructure of Bi0.5Sb1.5Te3 (BST) alloys through the incorporation of carbon nanofiber (CNF), and studied their effect on thermoelectric properties, and mechanical properties. The BST/x-CNF (x-0, 0.05, 0.1, 0.2 wt.%) composites powder was fabricated using high energy ball milling, and subsequently consolidated the powder using spark plasma sintering. The identification of CNF in bulk composites was analyzed in Raman spectroscopy and corresponding CNF peaks were recognized. The BST matrix grain size was greatly reduced with CNF dispersion and consistently decreased along CNF percentage. The electrical conductivity was reduced and Seebeck coefficient varied in small-scale by embedding CNF. The thermal conductivity was progressively diminished, obtained lattice thermal conductivity was lowest compared to bare sample due to induced phonon scattering at interfaces of secondary phases as well as highly dense fine grain boundaries. The peak ZT of 0.95 achieved for 0.1 wt.% dispersed BST/CNF composites. The Vickers hardness value of 101.8 Hv was obtained for the BST/CNF composites.

Formaldehyde Emissions and Moisture Content Change of Wood Composites during Bake-out

  • Lee, Young-Kyu;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • 제40권2호
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    • pp.101-109
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    • 2012
  • Wood composites are a hygroscopic material and have ability to exchange its moisture content with air. This study investigated the formaldehyde emission and moisture content change of four wood composites (particleboard (PB), medium density fiberboard (MDF), high density fiberboard (HDF), laminated HDF (L-HDF)) as a function of bake-out temperature and time. The composites were baked out for 1, 3, 5, 7, 10, 14, 21, and 28 days at temperatures of $20{\pm}2$, $35{\pm}2$, and $50{\pm}2^{\circ}C$ in a dry oven. The moisture content change was used to determine the emission bake-out of the composites. Best bake-out time results were obtained with after 7 days all composites. Formaldehyde emission values of composites decreased with decreasing moisture content for both temperatures. The formaldehyde emission results of bake-out temperature 35 and $50^{\circ}C$ showed a similar tendency.

Research on the Oxidation-Protective Coatings for Carbon/Carbon Composites

  • Li, He-Jun;Fu, Qian-Gang;Huang, Jian-Feng;Zeng, Xie-Rong;Li, Ke-Zhi
    • Carbon letters
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    • 제6권2호
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    • pp.71-78
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    • 2005
  • Anti-oxidation coatings are the key technique for carbon/carbon (C/C) composites used as the thermal structural materials. The microstructure and oxidation behavior of several kinds of high-performance ceramic coatings for C/C composites prepared in Northwestern Polytechnical University were introduced in this paper. It showed that the ceramic coatings such as SiC, Si-$MoSi_2$, SiC-$MoSi_2$, $Al_2O_3$-mullite-SiC and SiC/yttrium silicate/glass coatings possessed excellent oxidation resistance at high temperatures, and some of these coatings were characterized with excellent thermal shock resistance. The SiC-$MoSi_2$ coating system has the best oxidation protective property, which can effectively protect C/C composites from oxidation up to 1973 K. In addition, the protection and failure reasons of some coatings at high temperature were also provided.

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