• Resources Recycling
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• v.21 no.5
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• pp.79-87
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• 2012

With the increasing size and universalization of lithium-ion batteries, the development of cathode materials has emerged as a critical issue. The energy density of 18650 cylindrical batteries had more than doubled from 230 Wh/l in 1991 to 500 Wh/l in 2005. The energy capacity of most products ranges from 450 to 500Wh/l or from 150 to 190 Wh/kg. Product developments are focusing on high capacity, safety, saved production cost, and long life. As Co is expensive among the cathode active materials $LiCoO_2$, to increase energy capacity while decreasing the use of Co, composites such as $LiMn_2O_4$, $LiCo_{1/3}N_{i1/3}Mn_{1/3}O_2$, $LiNi_{0.8}Co_{0.15}Al_{0.05}O_2$, and $LiFePO_4$-C (167 mA/g) are being developed. Furthermore, many studies are being conducted to improve the performance of battery materials to meet the requirement of large capacity output density such as 500Wh/kg for electric bicycles, 1,500Wh/kg for electric tools, and 4,000~5,000Wh/kg for EV and PHEV. As new cathodes active materials with high energy capacity such as graphene-sulfur composite cathode materials with 600 Ah/kg and the molecular cluster for secondary battery with 320 Ah/kg are being developed these days, their commercializations are highly anticipated.

• Journal of the Korean Ceramic Society
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• v.45 no.9
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• pp.512-517
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• 2008

In this study, yttrium-doped $SiO_2$ nanoparticles are synthesized using a reverse micelle technique combined with metal alkoxide hydrolysis and condensation. Spherical Y-doped $SiO_2$ nanoparticles with a uniform size distribution are prepared using selfassembly molecules in conjunction with the hydrolysis and condensation of organometallic precursors. The water/surfactant molar ratio influenced the Y-doped $SiO_2$ particles distribution of the core-shell composite particles and the distribution of Y doped $SiO_2$ particles was broadened as the water to surfactant ratio increased. The particle size of Y increase linearly as the $Y(NO_3)_3$ solution concentration increased. The average size of the cluster was found to depend on the micelle size, the nature of the solvent, and the concentration of the reagent. The effects of synthesis parameters, such as the molar ratio of water to surfactant and the molar ratio of water to TEOS, are discussed.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.24 no.1
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• pp.76-80
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• 2011

The ITO/Cabon Nano Tube (CNT) nano composites were deposited by nano cluster deposition (ITO) and arc discharge deposition (CNT) on glass substrates. The structural, optical and photovoltaic performance of ITO/CNT nano composites as a counter electrode of dye-sensitized solar-cells (DSSCs) such films were investigated. At low temperature below $250^{\circ}C$, the ITO films deposited on CNT. The ITO/CNT nano composit showed a good optical and electrical property for the counter electrode of DSSCs. When the as-prepared ITO/CNT nano composites are used for the counter electrodes, the photovoltaic parameters are $V_{OC}$ = 0.69 V, $J_{SC}$ = 5.69 mA/$cm^2$, FF = 0.32, and $\eta$ = 0.53 %. The ITO/CNT nano composites showed the possibility for the counter electrode applications of DSSCs.

• Journal of the Korean Society of Clothing and Textiles
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• v.28 no.11
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• pp.1458-1469
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• 2004

In this study, color names focusing on the purple series, appearing in the clothing of the Joseon Dynasty, were classified systematically, and the conceptual meaning of each name were investigated through various methods. The results are as follows; First, the color names of purple-series were classified systematically. According to the integration scheme of morphemes, color names could be divided into two categories; single names and composite names. Color names could also be classified into universal and limited names according to the areal distribution of literatures. Secondly, the conceptual meaning of the color names of purple-series were considered. The conceptual meaning could be divided into two categories; one 'etymological and dyeing methodological meaning', the other 'color systematic meaning' By studying the dictionary definition of color names, comparing and analyzing the material composition of colors, the etymological and dyeing methodological meaning could be grasped. Furthermore, the color systematic meaning of each name could be grasped through the cluster analysis of L*, a*, b* values measured from the relics of clothing. Thirdly, the conceptual semantic structure were established on the basis of conceptual meanings of purple-series color names. The conceptual semantic structure of purple-series color names is forming discrete structure with the dyeing method and material of dyes as their semantic components.

• International Journal of Fuzzy Logic and Intelligent Systems
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• v.12 no.4
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• pp.263-269
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• 2012

The ability to characterize feature objects from radar readings is often limited by simply looking at their still frame reflectivity, differential reflectivity and differential phase data. In many cases, time-series study of these objects' reflectivity profile is required to properly characterize features objects of interest. This paper introduces a novel technique to automatically track multiple 3D radar structures in C,S-band in real-time using Doppler radar and profile their characteristic reflectivity distribution in time series. The extraction of reflectivity profile from different radar cluster structures is done in three stages: 1. static frame (zone-linkage) clustering, 2. dynamic frame (evolution-linkage) clustering and 3. characterization of clusters through time series profile of reflectivity distribution. The two clustering schemes proposed here are applied on composite multi-layers CAPPI (Constant Altitude Plan Position Indicator) radar data which covers altitude range of 0.25 to 10 km and an area spanning over hundreds of thousands $km^2$. Discrete numerical simulations show the validity of the proposed technique and that fast and accurate profiling of time series reflectivity distribution for deformable 3D radar structures is achievable.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.38 no.5
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• pp.487-496
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• 2020

This study introduces how GISs (Geographic Information Systems) are used to assess spatial disparities in urban green spaces in the Chicago. Green spaces provide us with a variety of benefits, namely environmental, economic, and physical benefits. This study seeks to explore socioeconomic relationships between green spaces and their surrounding communities and to evaluate spatial disparities from a variety of perspectives, such as health-related, socioeconomic, and physical environment factors. To achieve this goal, this study used spatial statistics, such as optimized hotspot analysis, network analysis, and space-time cluster analysis, which enable conclusions to be drawn from the geographic data. In particular, 12 variables within the three factors are used to assess spatial disparities in the benefits of the use of green spaces. Finally, the variables are standardized to rank the community areas and identify where the most vulnerable community areas or parks are. To evaluate the benefits given to the community areas, this study used the z- and composite scores, which are compared in the three different combinations. After identifying the most vulnerable community area, crime data is used to spatially understand when and where crimes occur near the parks selected. This work contributes to the work of urban planners who need to spatially evaluate community areas in considering the benefits of the uses of green spaces.

• Journal of Electrochemical Science and Technology
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• v.12 no.2
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• pp.285-295
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• 2021

The inverse spinel Cobalt ferrite (CoFe₂O₄, CFO) is considered to be a promising alternative to commercial graphite anodes for lithium ion batteries (LIBs). However, the further development of CFO is limited by its unstable structure during battery cycling and low electrical conductivity. In an effort to address the challenge, we construct three-dimensional hierarchical flower-like CFO nanoclusters (CFO NCs)-decorated carbonized cotton carbon fiber (CFO NCs/CCF) composite. This structure is consisted of microfibers and nanoflower cluster composited of CFO nanoparticle, in which CCF can be used as a long-range conductive matrix, while flower-like CFO NCs can provide abundant active sites, large electrode/electrolyte interface, short lithium ion diffusion path, and alleviated structural stress. As anode materials in LIBs, the flower-like CFO NCs/CCF exhibits excellent electrochemical performance. After 100 cycles at a current density of 0.3 A g^-1, the CFO NCs/CCF delivers a discharge/charge capacity of 1008/990 mAh g^-1. Even at a high current density of 15 A g^-1, it still maintains a charge/discharge capacity of 362/361 mAh g^-1.

• Steel and Composite Structures
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• v.47 no.4
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• pp.523-537
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• 2023

This paper proposed a new self-centering brace (SCB), which consists of four post-tensioned (PT) high strength steel strands and energy absorbing steel plate (EASP) clusters. First, analytical equations were derived to describe the working principle of the SCB. Then, to investigate the hysteretic performance of the SCB, four full-size specimens were manufactured and subjected to the same cyclic loading protocol. One additional specimen using only EASP clusters was also tested to highlight the contribution of PT strands. The test parameters varied in the testing process included the thickness of the EASP and the number of EASP in each cluster. Testing results shown that the SCB exhibited nearly flag-shape hysteresis up to expectation, including excellent recentering capability and satisfactory energy dissipating capacity. For all the specimens, the ratio of the recovered deformation is in the range of 89.6% to 92.1%, and the ratio of the height of the hysteresis loop to the yielding force is in the range of 0.47 to 0.77. Finally, in order to further understand the mechanism of the SCB and provide additional information to the testing results, the high-fidelity finite element (FE) models were established and the numerical results were compared against the experimental data. Good agreement between the experimental, numerical, and analytical results was observed, and the maximum difference is less than 12%. Parametric analysis was also carried out based on the validated FE model to evaluate the effect of some key parameters on the cyclic behavior of the SCB.

• Journal of the Korean earth science society
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• v.22 no.3
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• pp.186-194
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• 2001

The operational meso-scale short range NWP system was developed for Cheju Regional Meteorological Office located at Cheju island, Korea. The Central Meteorological Service Center, KMA has reported the information on numerical weather prediction every 12 hours. But this information is not enough to determine the detail forecast for the regional meteorological office because the terrain of the Korean peninsula is very complex and the resolution of the numerical model provided by KMA headquarter is too coarse to resolve the local severe weather system such as heavy rainfall. LAPS and MM5 models were chosen for three-dimentional data assimilation and numerical weather prediction tools respectively. LAPS was designed to provide the initial data to all regional numerical prediction models including MM5. Synoptic observational data from GTS, satellite brightness temperature data from GMS-5 and the composite reflectivity data from 5 radar sites were used in the LAPS data assimilation for producing the initial data. MM5 was performed on PC-cluster based on 16 pentium CPUs which was one of the cheapest distributed parallel computer in these days. We named this system as Halla Short Range Prediction System (HSRPS). HSRPS was verified by heavy rainfall case in July 9, 1999, it showed that HSRPS well resolved local severe weather which was not simulated by 30 km MM5/KMA. Especially, the structure of rainfall amount was very close to the corresponding observation. HSRPS will be operating every 6 hours in the Cheju Regional Meteorological Office from April 2000.

• Korean Journal of Materials Research
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• v.8 no.8
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• pp.757-765
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• 1998

This study was performed to investigate the influence of fuel/oxygen ratio (F/O= 3.2, 3.0, 2.8) on the oxidation behavior of two kinds of (20wt%NiCr claded $\textrm{Cr}_{3}\textrm{C}_{2}$, and 7wt%NiCr mixed $\textrm{Cr}_{3}\textrm{C}_{2}$) composite powder with different manufacturing method. The results show that the oxidation behavior between the 20wt% NiCr claded $\textrm{Cr}_{3}\textrm{C}_{2}$ and 7wt% NiCr mixed $\textrm{Cr}_{3}\textrm{C}_{2}$ coating was widely different. The surface morphology of the coating composed of 7wt% NiCr mixed $\textrm{Cr}_{3}\textrm{C}_{2}$ was changed to porous with F/O ratio by the aggressive evolution of gas phases($\textrm{CO}_2$, CO and $\textrm{CrO}_3$) and the oxide cluster composed of Ni and Cr were grown after oxidation at $1000^{\circ}C$ for 50 hours. But the surface morphology of the coating composed of 20wt% NiCr claded $\textrm{Cr}_{3}\textrm{C}_{2}$ was not changed to porous after oxidation at $1000^{\circ}C$ for 50 hours. Therefore, the reason for high oxidation rate is due to activation of $\textrm{Cr}_{3}\textrm{C}_{2}$ to oxidation by entrapped oxygen gases within coating layer, and to closely relate with the decomposition of $\textrm{Cr}_{3}\textrm{C}_{2}$ to $\textrm{Cr}_{7}\textrm{C}_{3}$ phase. Accordingly, On the evidence of these results, the study about the oxidation behavoir of the HVOF sprayed $\textrm{Cr}_{3}\textrm{C}_{2}$ coating depending on hydrogen flow rate must be done.