• Title/Summary/Keyword: Chemical washing

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On-line Trace Enrichment for the Determination of Insulin in Biological Samples Using Reversed-Phase High Performance Liquid Chromatography with Column Switching

  • Lee, Jung-Sook;Lee, Heeyong;Lee, Hye-Suk;Lee, Kang-Choon
    • Archives of Pharmacal Research
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    • v.17 no.5
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    • pp.360-363
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    • 1994
  • Column--swtiching technique with a reversed-phase high performance liquid chromatographic method has been developed for the routine analysis of radioiodinated insulin and its degadation products in biological fluids. The diluted biological samples were loaded onto a precolumn packed with LiChrosorb RP-8 $(25-40{\;}{\mu}m)$ using 0.1% trifuoroacetic acid (TFA) in water as a washing solvent. After valve switching, the concentrated insulins were eluted in the back-flush mode and separated by a W-Porex $C_{18}$ column with a gradient of 0.1% TFA in water and 0.1% TFA in acetonitrile as the mobile phase. The method showed good precision, accuracy and speed with the detection limit of 20 pg/ml. Total analysis time per sample was about 40 min and the coefficients of variation were less than 8, 2%.

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Development of Cellulosic Woven Fabric for Digital Textile Printing (전처리약제에 따른 셀룰로오스 디지털텍스타일 프린팅소재의 개발에 관한 연구)

  • Son Eun Jong;Lee Young Mok;Jang Se Chan;Yi Sung Chul
    • Textile Coloration and Finishing
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    • v.17 no.6 s.85
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    • pp.20-26
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    • 2005
  • For developing digital printing textiles, special pretreatment processes are necessary. These processes include developing formulation of coating agent and coating processes. The pretreatment were investigated with the variation concentration of anti-migration agent, fixation chemical etc.. The printing qualities according to pretreatment conditions were studied with color yield, printed capital letter sharpness and washing fastness. It was observed that the concentration of anti-migration agent, fixation agent(alkali) was closely related to printing qualities. For developing industrial technology of cellulosic digital printing textiles, optimum viscosity of pretreatment coating formulation is very important factor.

An Experiment on Performance Evaluation of a Vapor Condensation Type Air Washer System for Semiconductor Clean Rooms (반도체 클린룸용 수증기 응축식 에어와셔 시스템의 성능평가)

  • Yeo, Kuk-Hyun;Park, Sang-Tae;Yoo, Kyung-Hoon;Son, Seung-Woo
    • Proceedings of the SAREK Conference
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    • 2006.06a
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    • pp.442-447
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    • 2006
  • In semiconductor manufacturing clean rooms, it becomes important to remove airborne molecular contaminants as well as particulate contaminant in outdoor air introduced into clean rooms. One suitable control technique for these chemical contaminants is air washing by water in an outdoor air handling unit. In order to enhance the removal efficiency of chemical contaminants the effect of adding a heating and humidifying process before an air washer was examined.

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Model Development of Surfactant Reuse by Activated Carbons in Soil Washing Process (토양세척 공정에서 활성탄을 이용한 계면활성제 재사용 모델 개발)

  • Ahn, Chi-Kyu;Kim, Young-Mi;Woo, Seung-Han;Park, Jong-Moon
    • Journal of Soil and Groundwater Environment
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    • v.11 no.2
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    • pp.1-12
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    • 2006
  • A model describing the distributions of surfactants and HOCs (hydrophobic organic chemicals) in surfactant/HOC/activated carbon systems for surfactant reuse in soil washing process was developed. The model simulation was conducted for the evaluation of the effect of concentrations of surfactant, HOC, or activated carbons. Phenanthrene as a target HOC, Triton X-100 as surfactant and three granular activated carbons with different particle sizes (4-12, 12-20, and 20-40 mesh) were used in the model simulation. The distributions of HOC were significantly affected by surfactant dosages, especially at around the CMC(s). The results of selectivities for phenanthrene were much larger than 1 at various concentrations of surfactants, phenanthrene and activated carbons, which mean that the selective adsorption of phenanthrene by activated carbons is a proper separation method from surfactant solution. The model can be applied for the design of the surfactant reuse process using activated carbons without extra experimental efforts.

Change in the Physicochemical Properties of Dolsan Leaf Mustard under Salting Conditions (절임조건에 따른 돌산갓의 이화학적 특성 변화)

  • Bae, Sang-Ok;Wi, Sung-Dol;Lim, Hyun-Soo;Choi, Myeong-Rak
    • Food Science and Preservation
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    • v.18 no.4
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    • pp.502-507
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    • 2011
  • To investigate the optimal salting conditions, the physicochemical properties of Dolsan leaf mustard were compared under various salting times and using various washing methods and storage temperatures at 10% saline. On the other hand, the cell number of lactic-acid bacteria in Dolsan leaf mustard salted under the optimal conditions was also examined during the 50-day storage. The results of the sensory evaluation of the crispness value of the Dolsan leaf mustard treated with stepwise washing after 8h salting showed the optimal conditions for long-term preservation. The pH of the salted Dolsan leaf mustard decreased with the increase in the lactic-acid bacteria during the storage at $4^{\circ}C$. The cutting energy slowly increased during the storage, but the cutting energy of the salted Dolsan leaf mustard treated with stepwise washing remained at the initial values. The color of the salted Dolsan leaf mustard did not change during 40-day storage, but the mustard turned brown after 50-day storage, for which reason it could not be made into Dolsan leaf mustard kimchi. These results could be recommended as the optimal salting conditions and storage time of salted Dolsan leaf mustard for making kimchi.

Three Component Solvent-free Synthesis of Chroman-2,4-dione-based Heterocyclic Ketene Aminal (HKA) Derivatives by "GAP" Chemistry

  • Yu, Fu-Chao;Hao, Xiao-Pan;Jiang, Xiu-Yang;Yan, Sheng-Jiao;Lin, Jun
    • Bulletin of the Korean Chemical Society
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    • v.35 no.6
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    • pp.1625-1632
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    • 2014
  • A concise and efficient one-pot synthesis of chroman-2,4-dione-based HKA derivatives by three component reaction of HKAs, triethoxymethane and 4-hydroxycoumarin derivatives under solvent-free and catalyst-free conditions is described. This protocol has many advantages, in that the GAP (Group-Assistant-Purification) chemistry process is involved in this method. As a result, the experimenter can avoid cumbersome process steps such as traditional chromatography and recrystallization purifications. The desired products can be easily obtained by washing the crude products with 95% EtOH.

Characterization of a Blend-Biosurfactant of Glycolipid and Lipopeptide Produced by Bacillus subtilis TU2 Isolated from Underground Oil-Extraction Wastewater

  • Cheng, Fangyu;Tang, Cheng;Yang, Huan;Yu, Huimin;Chen, Yu;Shen, Zhongyao
    • Journal of Microbiology and Biotechnology
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    • v.23 no.3
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    • pp.390-396
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    • 2013
  • Biosurfactants have versatile properties and potential industrial applications. A new producer, B. subtilis TU2, was isolated from the underground oil-extraction wastewater of Shengli Oilfield, China. Preliminary flask culture showed that the titer of biosurfactant obtained from the broth of TU2 was ~1.5 g/l at 48 h (718 mg/l after purification), with a reduced surface tension of 32.5 mN/m. The critical micelle concentration was measured as 50 mg/l and the surface tension maintained stability in solution with 50 g/l NaCl and 16 g/l $CaCl_2$ after 5 days of incubation at $70^{\circ}C$. FT-IR spectra exhibited the structure information of both glycolipid and lipopeptide. MALDI-TOF-MS analyses confirmed that the biosurfactant produced by B. subtilis TU2 was a blend of glycolipid and lipopeptide, including rhamnolipid, surfactin, and fengycin. The blended biosurfactant showed 86% of oil-washing efficiency and fine emulsification activity on crude oil, suggesting its potential application in enhanced oil recovery.

Synthetic Detergent and our Daily Lives as Consumers against Environmental Pollution. (환경오염과 합성세제에 대한 소비생활)

  • Lee, Eun-Kyung
    • Korean Journal of Human Ecology
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    • v.4 no.1
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    • pp.123-133
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    • 1995
  • Lately our environments have been destroyed by such new things as synthetic detergent. How to use detergent at home can be a decisive factor for decreasing water pollution because living sewage by using detergent at home is the main cause of water pollution. We consumers, therefore, should understand the relation between the chemical ingredients of detergent and water pollution and should choose detergent always taking the kinds of detergent, its washing pewer into consideration. We should also contribute to the protection of out environment by keeping the standard of using amount attached to the products.

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Improved Dyeability of Cotton Fabrics by FC Water Repellent Finish (FC 발수가공에 의한 면직물의 염색성 향상)

  • 권영아
    • Journal of the Korean Society of Clothing and Textiles
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    • v.21 no.1
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    • pp.3-9
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    • 1997
  • From the standpoint of end-use and practical performances, attention was focused preparing cotton fabrics which posses good dyeability as well as water repellency. The results are summarized as follows, as far as findings obtained from this study is concerned. The fluoro chemical (FC) water repellent finished cotton fabrics exhibited good dyeing properties and colorfastness to washing. Furthermore, the DMDHEU durable-press and FC water repellent finishes in a single pad bath resulted in excellent durable press performance and good water repellency.

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