• 제목/요약/키워드: Chemical flow control

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A Fundamental Study on the Properties of Cement Collected at Different Process Line (시멘트 분쇄공정별 물성에 관한 기초적 연구)

  • Kim, Jong-Back;Cha, Wan-Ho;Kwon, O-Bong;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.11a
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    • pp.111-114
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    • 2006
  • This paper is to investigate the chemical composition and physical properties of cements collected at different crushing process line of ordinary portland cement to verify the possibility for producing special purpose cement based on the particle distribution technique. According to test results, six different cement samples with different blaine were gathered. loss on ignition and chemical composition of cements gathered were satisfied with KS L 5201. Cement collected at line 5 had the lowest blaine value while cement at line 4 had the highest blaine value. The coarser the cement particle is, the larger the fluidity of cement is. The compressive strength of cement was highly affected by the blaine value of cement. It is confirmed that the use of cement produced by the process of particle distribution control may be applied for special purpose cement without modification of chemical composition.

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Fabrication of Iron-Molybdenum Alloyed Nanoparticle and Nanowire using Chemical Vapor Condensation(CVC) (화학적 기상 응축(CVC)법을 이용한 철-몰리브덴합금 나노 입자와 와이어의 제조)

  • Ha, Jong-Keun;Cho, Kwon-Koo;Kim, Ki-Won;Ryu, Kwang-Sun
    • Journal of Powder Materials
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    • v.17 no.3
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    • pp.223-229
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    • 2010
  • Iron(Fe)-Molybdenum(Mo) alloyed nanoparticles and nanowires were produced by the chemical vapor condensation(CVC) process using the pyrolysis of iron pentacarbonyl($Fe(CO)_5$) and Molybdenum hexacarbonyl($Mo(CO)_6$). The influence of CVC parameter on the formation of nanoparticle, nanowire and size control was studied. The size of Fe-Mo alloyed nanoparticles can be controlled by quantity of gas flow. Also, Fe-Mo alloyed nanowires were produced by control of the work chamber pressure. Moreover, we investigated close correlation of size and morphology of Fe-Mo nanoparticles and nanowires with atomic quantity of inflow precursor into the electric furnace as the quantitative analysis. Obtained nanoparticles and nanowires were investigated by field emission scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction.

Statistical process control of dye solution stream using spectrophotometer

  • Lee, Won-Jae;Cho, Gyo-Young
    • Journal of the Korean Data and Information Science Society
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    • v.21 no.6
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    • pp.1289-1303
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    • 2010
  • The need for statistical process control to check the performance of a process is becoming more important in chemical and pharmaceutical industries. This study illustrates the method to determine whether a process is in control and how to produce and interpret control charts. In the experiment, a stream of green dyed water and a stream of pure water were continuously mixed in the process. The concentration of the dye solution was measured before and after the mixer via a spectrophotometer. The in-line mixer provided benefits to the dye and water mixture but not for the stock dye solution. The control charts were analyzed, and the pre-mixer process was in control for both the stock and mixed solutions. The R and X-bar charts showed virtually all of the points within control limits, and there were no patterns in the X-bar charts to suggest nonrandom data. However, the post-mixer process was shown to be out of control. While the R charts showed variability within the control limits, the X-bar charts were out of control and showed a steady increase in values, suggesting that the data was nonrandom. This steady increase in dye concentration was due to discontinuous, non-steady state flow. To improve the experiment in the future, a mixer could be inserted into the stock dye tank. The mixer would ensure that the dye concentration of the stock solution is more uniform prior to entering the pre-mixer ow cell. Overall, this would create a better standard to judge the water and dye mixture data against as well.

Analysis on Flow Control Method for Simultaneous Fuel Filling of the Korea Space Launch Vehicle-II (한국형발사체 연료 동시충전을 위한 유량제어 방식에 대한 고찰)

  • Yeo, Inseok;Lee, Jaejun;An, Jaechel;Kang, Sunil
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.5
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    • pp.132-140
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    • 2018
  • To lunch the Korea Space Launch Vehicle-II(KSLV-II), a second launch complex will be built at the Naro Space Center, and a Kerosene Filling System (KFS) will be installed. KFS of KSLV-II launch complex system is being designed based on Naro Launch Complex. But this must supply fuel to fuel tanks of the vehicle with only a supply pump because KSLV-II is a 3-stage launch vehicle unlike Naro Launch Vehicle or Test Launch Vehicle (TLV). A sudden rise of pump output pressure is recognized during fuel filling scenario selection process. This occurs because return flow can not actively deal with much flow change using the orifice-type flow-control method. To solve this problem, it is verified that fuel can be stably supplied by installing an accumulator, designed for appropriate adjustment of filling-mode change sequence via flow analysis of various cases.

Analysis of Behavior Characteristics of Water Pollutants in Yeongsan River Using 3D Hydraulic Model (3차원 수리 모델을 이용한 영산강 수질오염물질의 수체 내 거동 특성 분석)

  • Hye Yeon Oh;Eun Jung Kim;Jung Hyun Choi
    • Journal of Korean Society on Water Environment
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    • v.39 no.6
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    • pp.439-450
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    • 2023
  • The Yeongsan River, a major water resource for Jeollanam-do, that is adjacent to industrial complexes and agricultural areas, is exposed to water pollution. Therefore, it is necessary to investigate the impact of water pollution incidences and prepare response systems for river environment safety for other water resources in the future. Environmental Fluid Dynamics Code (EFDC) was applied to the mainstream of the Yeongsan River where residential, commercial, and agricultural areas are located to analyze the behavior of pollutants conducting the scenario analysis. Considering the pollutants that affected the study area, two pollutants, oil and benzene, with different physical and chemical characteristics were selected for the analysis. As a result of comparing the actual and simulated values of the water elevation, temperature, and flow rate, it was confirmed that the model adequately reproduced the hydraulic characteristics of the Yeongsan River. The oil flow dynamics showed that an increase in flow rate led to reduction in the maximum height of the slick. Notably, the behavior of the oil was predominantly influenced by the wind conditions. In the case of benzene, lower flow scenarios exhibited decreased arrival times and residence times accompanied by an elevation in the maximum concentration levels. From the results of pollutant behavior in the study area, it is feasible to utilize the section of tributary confluence for collection and the weir area for dilution. This study enhances the understanding of the pollutant's behavior with different characteristics and develops effective control systems tailored to the physicochemical attributes of pollutants.

The Development and Implementation of Model-based Control Algorithm of Urea-SCR Dosing System for Improving De-NOx Performance and Reducing NH3-slip (Urea-SCR 분사시스템의 DeNOx 저감 성능 향상과 NH3 슬립저감을 위한 모델 기반 제어알고리즘 개발 및 구현)

  • Jeong, Soo-Jin;Kim, Woo-Seung;Park, Jung-Kwon;Lee, Ho-Kil;Oh, Se-Doo
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.1
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    • pp.95-105
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    • 2012
  • The selective catalytic reduction (SCR) system is a highly-effective aftertreatment device for NOx reduction of diesel engines. Generally, the ammonia ($NH_3$) was generated from reaction mechanism of SCR in the SCR system using the liquid urea as the reluctant. Therefore, the precise urea dosing control is a very important key for NOx and $NH_3$ slip reduction in the SCR system. This paper investigated NOx and $NH_3$ emission characteristics of urea-SCR dosing system based on model-based control algorithm in order to reduce NOx. In the map-based control algorithm, target amount of urea solution was determined by mass flow rate of exhaust gas obtained from engine rpm, torque and $O_2$ for feed-back control NOx concentration should be measured by NOx sensor. Moreover, this algorithm can not estimate $NH_3$ absorbed on the catalyst. Hence, the urea injection can be too rich or too lean. In this study, the model-based control algorithm was developed and evaluated on the numerical model describing physical and chemical phenomena in SCR system. One channel thermo-fluid model coupled with finely tuned chemical reaction model was applied to this control algorithm. The vehicle test was carried out by using map-based and model-based control algorithms in the NEDC mode in order to evaluate the performance of the model based control algorithm.

A review: controlled synthesis of vertically aligned carbon nanotubes

  • Hahm, Myung-Gwan;Hashim, Daniel P.;Vajtai, Robert;Ajayan, Pulickel M.
    • Carbon letters
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    • v.12 no.4
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    • pp.185-193
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    • 2011
  • Carbon nanotubes (CNTs) have developed into one of the most competitively researched nano-materials of this decade because of their structural uniqueness and excellent physical properties such as nanoscale one dimensionality, high aspect ratio, high mechanical strength, thermal conductivity and excellent electrical conductivity. Mass production and structure control of CNTs are key factors for a feasible CNT industry. Water and ethanol vapor enhance the catalytic activity for massive growth of vertically aligned CNTs. A shower system for gas flow improves the growth of vertically aligned single walled CNTs (SWCNTs) by controlling the gas flow direction. Delivery of gases from the top of the nanotubes enables direct and precise supply of carbon source and water vapor to the catalysts. High quality vertically aligned SWCNTs synthesized using plasma enhance the chemical vapor deposition technique on substrate with suitable metal catalyst particles. This review provides an introduction to the concept of the growth of vertically aligned SWCNTs and covers advanced topics on the controlled synthesis of vertically aligned SWCNTs.

Single-stranded DNA Enhances the Rate of Product Release During Nucleotide Hydrolysis Reaction by T7 DNA Helicase

  • Kim, Dong-Eun;Jeong, Yong-Joo
    • Bulletin of the Korean Chemical Society
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    • v.27 no.10
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    • pp.1618-1622
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    • 2006
  • Bacteriophage T7 gp4A' is a ring-shaped hexameric DNA helicase that catalyzes duplex DNA unwinding using dTTP hydrolysis as an energy source. To investigate the effect of single-stranded DNA (ssDNA) on the kinetic pathway of dTTP hydrolysis by the T7 DNA helicase complexed with ssDNA, we have first determined optimal concentration of long circular M13 single-stranded DNA and pre-incubation time in the absence of $Mg^{2+}$ which is necessary for the helicase-ssDNA complex formation. Steady state dTTP hydrolysis in the absence of $Mg^{2+}$ by the helicase-ssDNA complex provided $k_{cat}$ of $8.5\;{\times}\;10^{-3}\;sec^{-1}$. Pre-steady state kinetics of the dTTP hydrolysis by the pre-assembled hexameric helicase was monitored by using the rapid chemical quench-flow technique both in the presence and absence of M13 ssDNA. Pre-steady state dTTP hydrolysis showed distinct burst kinetics in both cases, indicating that product release step is slower than dTTP hydrolysis step. Pre-steady state burst rates were similar both in the presence and absence of ssDNA, while steady state dTTP hydrolysis rate in the presence of ssDNA was much faster than in the absence of ssDNA. These results suggest that single-stranded DNA stimulates dTTP hydrolysis reaction by T7 helicase by enhancing the rate of product release step.

Enhancement of Mass Transfer Using Piezoelectric Material in Fluid Flow System

  • Kim, Gi-Beum;Chong, Woo-Suk;Kwon, Tae-Kyu;Hong, Chul-Un;Kim, Nam-Gyun;Jheong, Gyeong-Rak
    • 제어로봇시스템학회:학술대회논문집
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    • 2004.08a
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    • pp.165-170
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    • 2004
  • The purpose of this work was to assess and quantify the beneficial effects of long-term gas exchange, at varying frequencies, for the development of a vibrating intravascular lung assistance device (VIVLAD), for patients suffering from acute respiratory distress syndrome (ARDS). The experimental design and procedure have been applied to the construction of a new device for assessing the effectiveness of membrane vibrations. An analytical solution has been developed for the hydrodynamics of flow through a bundle of sinusoidally vibrated hollow fibers, with the intention of gaining insight into how wall vibrations might enhance the performance of the VIVLAD. As a result, the maximum oxygen transfer rate was reached at the maximum amplitude and through the transfer of vibrations to the hollow fiber membranes. The device was excited by a frequency band of 7Hz at various water flow rates, as this frequency was the 2nd mode resonance frequency of the flexible beam. 675 hollow fiber membranes were also bundled, within the blood flow, into the device.

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A Study on the Characteristics change of WSix Thin Films by S/H Life Time (S/H Life Time에 따른 WSix의 특성 변화에 관한 연구)

  • 정양희;강성준
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.6 no.5
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    • pp.689-695
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    • 2002
  • Film compositions are needed in semiconductor manufacturing for such diverse application as production tool qualifications and process development. Surface and interface information is generally provided with Auger electron spectroscopy(AES). In this paper, WSix films were analyzed for structural, electrical, and compositional properties of tungsten silicide thin films produced by low pressure chemical vapor deposition as a function of temperature, DCS post flow, shower head life time, and the silicon to tungsten ratios have been investigated. We find that Si/W composition ratio is increased in the surface and interface of WSix thin films by the DCS post flow process and increasing deposition temperature, respectively. The results obtained in this study are also applicable to process control of WSix deposition for memory device fabrication.