• Environmental Engineering Research
• /
• v.16 no.1
• /
• pp.29-34
• /
• 2011

The electric charge on a membrane was investigated by analyzing the experimental rejection of various monovalent and divalent ionic solutes. The characteristics of the separation of ionic solutes using various nanofiltration membranes were obtained from an experimental nanofiltration set-up, with a surface area of $40cm^2$ under the operational pressures between 0.25-0.3 MPa. The state of the membrane electric charge was observed using separation coefficients, i.e., the permeation ratio of monovalent to divalent ions. To confirm the state of the membrane charge observed via the separation coefficient, a calculation using the extended Nernst-Planck equation, coupled with the Donnan equilibrium, assuming different electric charge states of the membrane, was compared with the experimental rejection of ionic solutes. The examination of the characteristics of separation using three types of nanofiltration membranes showed that one of the membranes carried a negative/positive double charge density inside, while other two membranes carried either a positive or negative charge density.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.3
• /
• pp.795-802
• /
• 2012

Geminate electron-hole recombination in organic solids in the presence of a donor-acceptor heterojunction is studied by computer simulations. We analyze how the charge-pair separation probability in such systems is affected by energetic disorder of the media, anisotropy of charge-carrier mobilities, and other factors. We show that in energetically disordered systems the effect of heterojunction on the charge-pair separation probability is stronger than that in idealized systems without disorder. We also show that a mismatch between electron and hole mobilities reduces the separation probability, although in energetically disordered systems this effect is weaker compared to the case of no energetic disorder. We demonstrate that the most important factor that determines the charge-pair separation probability is the ratio of the sum of electron and hole mobilities to the rate constant of recombination reaction. We also consider systems with mobility anisotropy and calculate the electric field dependence of the charge-pair separation probability for all possible orientations of high-mobility axes in the donor and acceptor phases. We theoretically show that it is possible to increase the charge-pair separation probability by controlling the mobility anisotropy in heterojunction systems and in consequence to achieve higher efficiencies of organic photovoltaic devices.

• Journal of the Korean Magnetic Resonance Society
• /
• v.4 no.2
• /
• pp.82-90
• /
• 2000

Photoinduced charge separation of alkylphenothiazines in molecular assemblies such as positively, negatively and neutrally charged micelle interface results in the paramagnetic phenothiazine cation radical. This was studied as a model system for the light energy conversion into chemical energy. The photoproduced phenothaizne cation radical was identified and its amount was quantized with electron spin resonance (ESR). The microenvironment of photoproduced cation radical was studied with pulsed-ESR. Such a charge separation is enhanced by the optimization of various structural factors of the molecular assemblies. The structural factors of molecular assemblies have focused on the interface charge, interface structure with different headgroups and interfacial perturbation by disolving interface active organic additives.

• Journal of the Korean Operations Research and Management Science Society
• /
• v.36 no.2
• /
• pp.43-50
• /
• 2011

We consider the separation problem of the rank-1 Chvatal-Gomory (C-G) inequalities for the 0-1 knapsack problem with the knapsack capacity defined by an additional binary variable, which we call the fixed-charge 0-1 knapsack problem. We analyze the structural properties of the optimal solutions to the separation problem and show that the separation problem can be solved in pseudo-polynomial time. By using the result, we also show that the existence of a pseudo-polynomial time algorithm for the separation problem of the rank-1 C-G inequalities of the ordinary 0-1 knapsack problem.

• Journal of Photoscience
• /
• v.6 no.3
• /
• pp.91-96
• /
• 1999

Zeolites and microporouos materials continue to attract attention as novel hosts for photochemical reactions. Zeolities are attractive because of their ability to selectivity exchange and incorporate species within the void spaces and interconnecting channels, providing a spatial arrangement of molecules. Our research has primarily focused on intrazeolitic electron transfer from excited Ru(bpy)32+ in supercages of zeolite Y to a series of bipyridinium ions. In the Ru(bpy)32+ viologen-zeolite Y samples, the slowing of the back electron transfer from the bipyridinium radical cation to Ru(bpy)32+ allows for charge propagation via self exchange between diquat molecules. This provides an opportunity for permanent charge separation. When the migrating charge on the diquat radical within the zeolite reaches the surface, it can be transferred to a neutral viologen (PVS) in solution, resulting in permanent charge separation. The advantage of long-lived charge separation can be exploited for useful chemistry if suitable catablysts can be assembled on the zeolities. We have studied Ru(bpy)2 as water oxdiation catalysts. We have demonstrated that synthesis of RuO2 fibers on a zeolite via thermal decomposition of Ru3(CO)12 leads to the most active water decomposition catalyst reported to date. Because of the extensive interest of photochemical water reduction to H2, much is known about catalytic systems usin gone electron catalyst, and even more importantly, that no reaction of viologen occurred with H2 over this catalyst. The present challenge is to incorporate all these elements of the system into an architecture and we are examining zeolite membranes for this purpose.

• Journal of Mechanical Science and Technology
• /
• v.17 no.10
• /
• pp.1485-1495
• /
• 2003

We investigate the triboelectrostatic separation of polyvinylchloride (PVC) from mixed plastics in the laboratory scale triboelectrostatic separation system. The flow and electric fields in the precipitator are obtained from the numerical solution of finite volume method. Using these flow and electric fields, we solved the particle motion equation considering the inertia, drag, gravity and electrostatic forces acted on the particles. The particle trajectories are obtained using a Lagrangian method as a function of different important variables such as Reynolds number, Stokes number, electrostatic force, electric charge and electric field distribution, inclined angle of plane electrodes, particle rebounding, particle charge decay rate after impact on the electrode surface, etc., in order to determine the optimal design conditions. The present predicted results for the cumulative yield represent well the experimental ones.

• Explosives and Blasting
• /
• v.32 no.1
• /
• pp.1-9
• /
• 2014

TNT was blasted on the surface of steel plates and concrete block to study the effect of separation distance between object and charge. The equation of US Army Corps of Engineers turned out to be rather conservative. Effect of separation distance is larger for steel plate than concrete block. Steel plate cannot be cut by standard or more charge in the case of 2 cm separation while the concrete block can be crushed with the same distance.

• Resources Recycling
• /
• v.11 no.3
• /
• pp.37-45
• /
• 2002

Triboelectrostatic Separation procese is a technology that different particles charged after contact and rubbing different materials are separated in an electric field. At this time, charged polarity of different materials depends on their own work function. Therefore this study discovers work functions of various plastics and determines charging characteristics for the specific optimum operation condition. The experiment is conducted with two sample sets composed of various different plastics. Each sample is charged by contact and rubbing different materials. Surface charge of charged particles is measured by Faraday Cage. The specific work function of an each plastic is driven by measured charging amount and charged particles are separated in a certain electric field ($\pm$20 kV). At last, the relationship between charging amount and separation efficiency is induced by the separation experiment.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.2
• /
• pp.587-596
• /
• 2014

A new ${\pi}$-stacked donor-acceptor (D-A) system, [Ru(1-([2,2'-bipyridine]-6-yl-methyl)-3-(2-cyclohexa-2',5'-diene-1,4-dionyl)-1H-imidazole)(2,2':6',2"-terpyridine)]$[PF_6]_2$ (ImQ_T), has been synthesized and characterized. Similar to its precedent, [Ru(6-(2-cyclohexa-2',5'-diene-1,4-dione)-2,2':6',2"-terpyridine)(2,2':6',2"-terpyridine)]$[PF_6]_2$ (TQ_T), this system has a cofacial alignment of terpyridine (tpy) ligand and quinonyl (Q) group, which facilitates an electron transfer through ${\pi}$-stacked manifold. Despite the presence of lowest-energy charge transfer transition from the Ru-based-HOMO-to-Q-based-LUMO (MQCT) predicted by theoretical calculations by using time-dependent density functional theory (TD-DFT), the experimental steady-state absorption spectrum does not exhibit such a band. The selective excitation to the Ru-based occupied orbitals-to-tpy-based virtual orbital MLCT state was thus possible, from which charge separation (CS) reaction occurred. The photo-induced CS and thermal charge recombination (CR) reactions were probed by using ultrafast visible-pump/mid-IR-probe (TrIR) spectroscopic method. Analysis of decay kinetics of Q and $Q^-$ state CO stretching modes as well as aromatic C=C stretching mode of tpy ligand gave time constants of <1 ps for CS, 1-3 ps for CR, and 10-20 ps for vibrational cooling processes. The electron transfer pathway was revealed to be Ru-tpy-Q rather than Ru-bpy-imidazol-Q.

• Journal of the Korea Institute of Military Science and Technology
• /
• v.25 no.3
• /
• pp.275-284
• /
• 2022

Linear Shaped Charge(LSC) is widely used as a separation system in the field of weapon system. However, there are some disadvantages that are charging lots of explosives due to lack of uniformity and having difficulties of the design of liner and explosives because of manufacturing process. In order to solve these problems, Precision Linear Shaped Charge(PLSC) that can design a liner independently and charge explosives uniformly has been developed. In this study, PLSC was designed to have a proper liner shape and amount of explosives, and the penetration test of PLSC with different stand-off distance from liner to target was conducted. On the basis of the penetration test results of PLSC, the numerical analysis method using AUTODYN was established and verified. The penetrative mechanism and characteristics of PLSC with targets of different materials was analyzed from experimental and numerical results.