• 제목/요약/키워드: Cathodic Protection

검색결과 240건 처리시간 0.025초

내연기관용 슬라이드 베어링재의 케비테이션 침식거동과 부식영향 및 윤할유의 거동에 관한 연구 (A Study on the behaviour of Cavitation erosion and lubricating Oils and the influence of Corrosion on Slide Bearing Metals for Internal combustion Engine)

  • 이진열;임우조
    • 수산해양기술연구
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    • 제28권2호
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    • pp.171-183
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    • 1992
  • In this paper, the behaviour of cavitation erosion, influence of corrosion and corrosion control on slide bearing metals for internal combustion engine were investigated, and this experiment was done by the vibratory cavitation erosion tester. The main results obtained are as follows: 1. With decreasing the space between horn and specimen, the weight loss and its rate increased step by step. But the weight loss and its rate of 0.2mm space decreased conversely more than that of 0.4mm space at early stage. 2. The weight loss and its rate with change of pH were appeared to the order of pH2>pH12>pH7>pH4. And the weight loss and its rate at pH 4 decreased at best. 3. The weight loss and its rate by cavitation erosion for bearing metals were shown to the order of W.M7>W.M1>K.M4. 4. There appeared mainly small pit hole at pH2, and appeared the pit of netting thread type at pH12 by the results of the damaged surfaces at pH2 and pH12 environments that were sensitive to cavitation erosion. 5. With increasing the viscosity of lubricating oil, the weight loss rate by cavitation erosion became dull at the space below 0.5mm. 6. The protective efficiency of cavitation erosion-corrosion is superior inhibitor of chormate(25 ppm) to cathodic protection.

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Sustainable Development of Palm Oil: Synthesis and Electrochemical Performance of Corrosion Inhibitors

  • Porcayo-Calderon, J.;Rivera-Munoz, E.M.;Peza-Ledesma, C.;Casales-Diaz, M.;de la Escalera, L.M. Martinez;Canto, J.;Martinez-Gomez, L.
    • Journal of Electrochemical Science and Technology
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    • 제8권2호
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    • pp.133-145
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    • 2017
  • Palm oil production is among the highest worldwide, and it has been mainly used in the food industry and other commodities. Currently, a lot of palm oil production has been destined for the synthesis of biodiesel; however, its use in applications other than the food industry has been questioned. Thereby for a sustainable development, in this paper the use of palm oil of low quality for corrosion inhibitors synthesis is proposed. The performance of the synthesized inhibitors was evaluated by using electrochemical techniques such as open circuit potential measurements, linear polarization resistance and electrochemical impedance spectroscopy. The results indicate that the fatty amides from palm oil are excellent corrosion inhibitors with protection efficiencies greater than 98%. Fatty amides molecules act as cathodic inhibitors decreasing the anodic dissolution of iron. When fatty amides are added, a rapid decrease in the corrosion rate occurs due to the rapid formation of a molecular film onto carbon steel surface. During the adsorption process of the inhibitor a self-organization of the hydrocarbon chains takes place forming a tightly packed hydrophobic film. These results demonstrate that the use of palm oil for the production of green inhibitors promises to be an excellent alternative for a sustainable use of the palm oil production.

후처리 적용에 따른 방식용 Al-3%Mg 용사코팅 층의 해수 내 전기화학적 특성 (Electrochemical Characteristics in Sea Water of Al-3%Mg Arc Spray Coating Layer for Corrosion Protection with Sealing Treatment)

  • 박일초;김성종
    • 한국통신학회논문지
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    • 제40권5호
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    • pp.974-980
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    • 2015
  • 해양환경 하에서 강재에 대한 방식 목적으로 Al-3%Mg 용사선재를 이용하여 아크 용사코팅을 실시하였다. 그리고 Al-3%Mg 용사코팅 층의 내식성을 개선하기 위하여 유/무기 복합 세라믹 후처리를 실시하였다. 후처리 적용에 따른 용사코팅 층의 다양한 전기화학적 실험 결과, 양극분극과 음극분극 실험 시 모든 전위구간에서 후처리 적용 시 전류밀도가 작게 나타나 내식성 개선이 확인되었다. 그리고 후처리된 용사코팅 층의 표면에서 관찰된 마이크로 크랙의 영향으로 자연전위 계측 시 심한 전위변동이 나타났으며, 양극분극 실험 시에는 후처리 층의 탈리손상이 용이하게 발생하였다. 그럼에도 불구하고 타펠분석을 기반으로 외부 환경차단 효과를 나타내는 코팅 효율이 92.11%로 산출되어 Al-3%Mg 용사코팅 층의 내식성이 향상되었다.

Effect of Retained Pre-construction Primer on the Corrosion Protection Properties of Epoxy Coatings

  • Lee, Chul-Hwan;Shin, Chil-Seok;Lee, Ho-Il;Chung, Mong-Kyu;Baek, Kwang-Ki
    • Corrosion Science and Technology
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    • 제6권5호
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    • pp.219-226
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    • 2007
  • Pre-construction primer (PCP), or shopprimer, have been applied to steel plates to control temporary corrosion during ship fabrication. For surface preparation at ship block stage, in common shipyard practices, welding beads, burnt and rusted areas shall be blasted or power tool cleaned and the contamination such as zinc salt shall be removed with blasting or power tool. Whereas, the sound film of PCP needs not to be removed or roughened as the paint having good compatibility with PCP is used for the first coat. In many cases, however, full blasting or sweep blasting on the sound PCP treated block assemblies was requested. There still has been argument about the legitimacy of this practice, thus, it is critical to evaluate the quality of the coating system applied on the sound PCP retained condition, comparing with the one applied on the full blasted or sweep blasted condition. In this study, two different epoxy systems for water ballast tank were applied on the surfaces with sound PCP condition, full blasted condition, and sweep blasted condition. Coating performances such as durability, anti-corrosion, cathodic disbondment resistance were evaluated. The test results clearly indicated that the sound film of PCP needed not to be removed or roughened as the paint having good compatibility with PCP based on inorganic zinc silicate.

매설 배관 피복 결함 탐상 정확도에 미치는 인접 정류기 및 접지 구리망 간섭의 영향 (Effects of Rectifier and Copper Grid Interference on the Detection Reliability of Coating Flaws on Buried Pipes)

  • 김민기;임부택;김기태;장현영;박흥배;김영식
    • Corrosion Science and Technology
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    • 제19권4호
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    • pp.211-223
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    • 2020
  • The external corrosion of buried piping can be controlled using both coating and cathodic protection. Several factors are involved in the damage and deterioration of the coating on pipes. There are many detection methods for coating defects on pipes and the direct current voltage gradient (DCVG) method is one of the most powerful methods. However, the detection reliability of DCVG can be affected by interferences such as stray current, metal objects connected to rectifiers, and copper grids. Therefore, this study focused on the interference effects of rectifiers and a copper grid on the reliability of coating flaw detection. As the length of the interference pipe connected to the rectifier increased, the reliability decreased. In contrast, as the distance between the pipe and the copper grid increased, the reliability of the coating flaw detection increased. The detection results produced by the DCVG method were discussed using current and potential simulations for a pipe with a rectifier and copper grid interference in the soil.

지중전력케이블에서 고장발생시 인근 가스배관에 유도되는 전압 해석 (Analysis of Induced Voltage on the Gas Pipeline at the Fault in a Underground Power Cables)

  • 배정효;김대경;김기준
    • 한국가스학회지
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    • 제4권3호
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    • pp.26-32
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    • 2000
  • 최근 국내에서는 효율적인 공간활용을 위해 해저터널을 이용하여 전력을 공급하는 것이 시도되고 있으며, 해저터널내에 에너지 공급 기간시설물(전력케이블, 가스배관, 송유관, 지역난방배관 등)들이 같이 포설될 수 있으면 공사비 절감의 효과는 엄청날 것이므로 관심도가 높아지고 있다. 따라서 본 논문에서는 세계최초로 몰타르(Mortar)로 충진되어 있는 해저터널에서 전력케이블과 가스배관이 병행할 경우, 유도에 의한 교류부식에 대하여 검토하였으며, 아직 국내에는 유도전압 제한치가 마련되어 있지 않으므로 인$\cdot$축의 안전적인 측면과 시스템의 보안적인 측면을 세심하게 검토하여 이에 대한 제한치를 정립하였고, 유도전압이 최소가 되도록 전력케이블의 상배치를 최적으로 설계하였다. 이 결과들은 실 사례에 적용되었다.

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외면부식 직접평가법 개발 및 국내 도입 연구 (The Development and Introduction of External Corrosion Direct Assessment Measures for Urban Gas Pipelines)

  • 류영돈;이진한;윤영기;임호석
    • 한국가스학회지
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    • 제18권5호
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    • pp.12-19
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    • 2014
  • 매설배관의 부식위험성을 최소화하고 음극방식의 효율극대화를 위해 다양한 비굴착 간접검사기법들이 수십년 전부터 이용되고 있으며, 미국에서는 굴착을 통한 매설배관 외면부식 직접평가법을 CFR 코드에서 규정하고 있다. 국내의 경우에는 도시가스사업법 관련 4개의 기준(KGS Code)에서 배관의 손상여부를 측정할 수 있는 장비를 이용하여 배관의 상태를 점검, 측정하고 이상부위에 대하여 누출검사를 한 경우 매설배관의 기밀시험을 한 것으로 보고 있을 뿐 배관외면부식 직접평가에 대한 규정은 없다. 본 논문에서는 미국, 영국 등 국외의 매설배관 건전성 관리 기준 및 방법을 조사하고, 국내의 매설배관 방식관리 실태 및 피복손상탐지 장치 이용실태 등을 조사한 후 국내 실정에 맞는 매설배관 외면부식 직접평가법을 제시하였다. 본 논문에서 제시한 매설배관 외면부식 직접 평가법은 국내에서 중압배관의 정밀안전진단 제도를 도입하는데 기초 자료로 활용되었다.

차량을 이용한 원격전위 측정방법 개발에 관한 연구 (A Study on the Development of Remotely CP Potential Measuring Method by using Vehicle)

  • 류영돈;조영도;김진준;서민성
    • 한국가스학회지
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    • 제20권5호
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    • pp.64-71
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    • 2016
  • 도시가스사업법령에 따라 지하에 매설된 도시가스 배관에는 전기부식 방지조치를 하도록 하고 있으며, 테스트 박스에서 배관의 방식전위를 1년마다 측정하도록 하고 있다. 그런데, 도심에 설치된 테스트 박스(T/B)의 경우 대부분 차량이 통행하는 도로위에 설치되어 있어 전위를 측정할 때 어려움이 있다. 즉, 전위를 측정하기 위해서는 차량을 통제하거나, 교통량이 적은 심야에 실시해야 하는 등 어려움이 있다. 본 연구에서는 이러한 방식전위 측정의 문제점을 해결하기 위하여 차량을 타고 이동하면서 테스트박스의 전위를 측정하는 방법을 연구하였다. 도로위에 설치된 테스트박스 하부에 기준전극과 데이터로거를 설치하고, 차량이 이동하면서 데이터로거로부터 방식 전위를 수신하는 방법으로 시험 연구를 진행하였다. 테스트 박스가 도로위에 설치되어 있어 전파를 송수신하는 데 어려움이 있어 안테나 방식을 변경해 가면서 가장 효과적인 방법을 채택하기로 하였다. 개발한 방법을 도시가스사의 실제 테스트박스에 적용한 결과 이 방법은 기존의 측정방법보다 20배 이상 시간을 절약할 수 있었다.

Seawater ballast tank 환경에서 저합금강의 내식성에 미치는 합금원소의 영향 (Effects of Alloying Elements on Corrosion Resistance of Low Alloyed Steels in a Seawater Ballast Tank Environment)

  • 김동우;김희산
    • 대한금속재료학회지
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    • 제48권6호
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    • pp.523-532
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    • 2010
  • Co-application of organic coating and cathodic protection has not provided enough durability to low-alloyed steels inseawater ballast tank (SBT) environments. An attempt has made to study the effect of alloy elements (Al, Cr, Cu, Mo, Ni, Si, W) on general and localized corrosion resistance of steels as basic research to develop new low-allowed steels resistive to corrosion in SBT environments. For this study, we measured the corrosion rate by the weigh loss method after periodic immersion in synthetic seawater at $60^{\circ}C$, evaluated the localized corrosion resistance by an immersion test in concentrated chloride solution with the critical pH depending on the alloy element (Fe, Cr, Al, Ni), determined the permeability of chloride ion across the rust layer by measuring the membrane potential, and finally, we analyzed the rust layer by EPMA mapping and compared the result with the E-pH diagram calculated in the study. The immersion test of up to 55 days in the synthetic seawater showed that chromium, aluminium, and nickel are beneficial but the other elements are detrimental to corrosion resistance. Among the beneficial elements, chromium and aluminium effectively decreased the corrosion rate of the steels during the initial immersion, while nickel effectively decreased the corrosion rate in a longer than 30-day immersion. The low corrosion rate of Cr- or Al-alloyed steel in the initial period was due to the formation of $Cr_2FeO_4$ or $Al_2FeO_4$, respectively -the predicted oxide in the E-pH diagram- which is known as a more protective oxide than $Fe_3O_4$. The increased corrosion rate of Cr-alloyed steels with alonger than 30-day exposure was due to low localized corrosion resistance, which is explained bythe effect of the alloying element on a critical pH. In the meantime, the low corrosion rate of Ni-alloyed steel with a longer than 30-day exposure wasdue to an Ni enriched layer containing $Fe_2NiO_4$, the predicted oxide in the E-pH diagram. Finally, the measurement of the membrane potential depending on the alloying element showed that a lower permeability of chloride ion does not always result in higher corrosion resistance in seawater.

탄소계 경질 박막의 연구 및 산업 적용 동향 (Trend in Research and Application of Hard Carbon-based Thin Films)

  • 이경황;박종원;양지훈;정재인
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2009년도 춘계학술대회 논문집
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    • pp.111-112
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    • 2009
  • Diamond-like carbon (DLC) is a convenient term to indicate the compositions of the various forms of amorphous carbon (a-C), tetrahedral amorphous carbon (ta-C), hydrogenated amorphous carbon and tetrahedral amorphous carbon (a-C:H and ta-C:H). The a-C film with disordered graphitic ordering, such as soot, chars, glassy carbon, and evaporated a-C, is shown in the lower left hand corner. If the fraction of sp3 bonding reaches a high degree, such an a-C is denoted as tetrahedral amorphous carbon (ta-C), in order to distinguish it from sp2 a-C [2]. Two hydrocarbon polymers, that is, polyethylene (CH2)n and polyacetylene (CH)n, define the limits of the triangle in the right hand corner beyond which interconnecting C-C networks do not form, and only strait-chain molecules are formed. The DLC films, i.e. a-C, ta-C, a-C:H and ta-C:H, have some extreme properties similar to diamond, such as hardness, elastic modulus and chemical inertness. These films are great advantages for many applications. One of the most important applications of the carbon-based films is the coating for magnetic hard disk recording. The second successful application is wear protective and antireflective films for IR windows. The third application is wear protection of bearings and sliding friction parts. The fourth is precision gages for the automotive industry. Recently, exciting ongoing study [1] tries to deposit a carbon-based protective film on engine parts (e.g. engine cylinders and pistons) taking into account not only low friction and wear, but also self lubricating properties. Reduction of the oil consumption is expected. Currently, for an additional application field, the carbon-based films are extensively studied as excellent candidates for biocompatible films on biomedical implants. The carbon-based films consist of carbon, hydrogen and nitrogen, which are biologically harmless as well as the main elements of human body. Some in vitro and limited in vivo studies on the biological effects of carbon-based films have been studied [$2{\sim}5$].The carbon-based films have great potentials in many fields. However, a few technological issues for carbon-based film are still needed to be studied to improve the applicability. Aisenberg and Chabot [3] firstly prepared an amorphous carbon film on substrates remained at room temperature using a beam of carbon ions produced using argon plasma. Spencer et al. [4] had subsequently developed this field. Many deposition techniques for DLC films have been developed to increase the fraction of sp3 bonding in the films. The a-C films have been prepared by a variety of deposition methods such as ion plating, DC or RF sputtering, RF or DC plasma enhanced chemical vapor deposition (PECVD), electron cyclotron resonance chemical vapor deposition (ECR-CVD), ion implantation, ablation, pulsed laser deposition and cathodic arc deposition, from a variety of carbon target or gaseous sources materials [5]. Sputtering is the most common deposition method for a-C film. Deposited films by these plasma methods, such as plasma enhanced chemical vapor deposition (PECVD) [6], are ranged into the interior of the triangle. Application fields of DLC films investigated from papers. Many papers purposed to apply for tribology due to the carbon-based films of low friction and wear resistance. Figure 1 shows the percentage of DLC research interest for application field. The biggest portion is tribology field. It is occupied 57%. Second, biomedical field hold 14%. Nowadays, biomedical field is took notice in many countries and significantly increased the research papers. DLC films actually applied to many industries in 2005 as shown figure 2. The most applied fields are mold and machinery industries. It took over 50%. The automobile industry is more and more increase application parts. In the near future, automobile industry is expected a big market for DLC coating. Figure 1 Research interests of carbon-based filmsFigure 2 Demand ratio of DLC coating for industry in 2005. In this presentation, I will introduce a trend of carbon-based coating research and applications.

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