Browse > Article
http://dx.doi.org/10.7840/kics.2015.40.5.974

Electrochemical Characteristics in Sea Water of Al-3%Mg Arc Spray Coating Layer for Corrosion Protection with Sealing Treatment  

Park, Il-Cho (Division of Marine Engineering, Mokpo National Maritime University)
Kim, Seong-Jong (Division of Marine Engineering, Mokpo National Maritime University)
Abstract
Arc thermal spray coating using Al-3%Mg thermal spray wire was carried out to prevent steel from corrosion damage under the marine environment. Post-sealing was applied to Al-3%Mg spray coating treatment using organic/inorganic composite ceramics in order to improve the corrosion resistance of the as-sprayed coating. The results of various electrochemical experiments with sealing treatment indicated that the improvement in corrosion resistance was observed due to low current density in all applied potential range during anodic and cathodic polarization experiments. Futhermore, the natural potential measurement exhibited severe potential fluctuation due to influence of micro-crack presence on the surface of sealed thermal spray coating layer. In addition, the sealed layer was easily eliminated during anodic polarization. Nevertheless, Al-3%Mg spray coating layer improved corrosion resistance by sealing treatment because the sealed coating efficiency was determined to be 92.11%, indicating the exterior environment barrier effect which is based on the Tafel analysis.
Keywords
Arc Thermal Spray coating; Al-3%Mg; Post-sealing; Corrosion;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 R. H. Unger, "Thermal Spraying of Bridges," National Thermal Spray Conf., pp. 399-406, Florida, USA, 1987.
2 K. J. Altorfer, Atmospheric Corrosion, John Wiley and Sons, (645-650), 1982.
3 D. Grasme, "Deutscher Verlag fuer Schweisstechnik DVS-Verlag GmbH," Thermal Spraying Conf., pp. 188-191, 1993.
4 S. Kawahara and R. Sumida, "R. Nippon yosha kyokai shi," J. TSS, vol. 31, no. 1, pp. 37-42, 1994.
5 S. J. Kim and S. J. Lee, "Effects of F-Si sealer on electrochemical characteristics of 15%Al-85%Zn alloy thermal spray coating," Trans. Nonferrous Metal Soc. Ch., vol. 21, pp. 2798-2804, 2011.   DOI   ScienceOn
6 J. H. Baek, J. H. Lee, M. G. Lee, C. S. Suh, S. T. Kwak, and M. J. Moon, "Characterization of adhesion and preparation of functionalized organic-inorganic hybrid epoxy coatings," J. Kor. Soc. Imag. Sci. Tech., vol. 12, no. 2, pp. 53-60, 2006.
7 M. S. Han, S. J. Lee, S. K. Jang, and S. J. Kim, "Electrochemical and cavitation characteristics of Al thermal spray coating with F-Si sealing," Corros. Sci. Tech., vol. 9, no. 6, pp. 317-324, 2010.
8 S. J. Kim and S. K. Jang, "Mechanical and electrochemical characteristics in welding with robot on 6061-T6 Al alloy for Al ship," J. KOSME, vol. 33, no. 2, pp. 313-321, 2009.
9 S. Liscano, L. Gil, and M. H. Staia, "Effect of sealing treatment on the corrosion resistance of thermal-sprayed ceramic coatings," Surf. Coat. Tech., vol. 188-189, pp. 135-139, 2004.   DOI   ScienceOn
10 Z. Liu, D. Yan, Y. Dong, Y. Yang, Z. Chu, and Z. Zhang, "The effect of modified epoxy sealing on the electrochemical corrosion behaviour of reactive plasma-sprayed TiN coatings," Corros. Sci., vol. 75, pp. 220-227, 2013.   DOI   ScienceOn
11 S. J. Kim, S. J. Lee, I. J. Kim, S. K. Kim, M. S. Han, and S. K. Jang, "Cavitation and electrochemical characteristics of thermal spray coating with sealing material," Trans. Nonferrous Metal Soc. Ch., vol. 23, pp. 1002-1010, 2013.   DOI
12 S. J. Kim and J. I. Kim, "Evaluating the electrochemical properties in the protection potential of material for use in Al vessels in seawater," Mater. Sci. Forum, vol. 510-511, pp. 158-161, 2006.
13 Y. H. Yoo, D. P. Le, and J. G. Kim, "Corrosion behavior of TiN, TiAlN, TiAlSiN thin films deposited on tool steel in the 3.5 wt.% NaCl solution," Thin Solid Films, vol. 516, pp. 3544-3548, 2008.   DOI   ScienceOn
14 S. J. Kim, S. K. Jang, and J. I. Kim, "Characteristics evaluation of thin films formed in Mg-Al alloy in various chemical conversion solution conditions," J. KOSME, vol. 29, no. 1, pp. 98-106, 2005.
15 P. Siitonen, S. L. Chen, K. Niemi, and P. Vuoristo, "Electrochemical method for evaluating the corrosion resistance and porosity of thermal sprayed coatings," Int. Thermal Spray Conf,, pp. 853-858, Orlando, USA, Jun. 1992.
16 Y. J. Yu, J. G. Kim, and S. H. Cho, "Plasma-polymerized toluene films for corrosion inhibition in microelectronic devices," Surf. Coat. Tech., vol. 162, pp. 161-166, 2003.   DOI   ScienceOn