• Title/Summary/Keyword: CaN

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Theoretical Study of the Structures and Binding Energies of Ca+-(CO)n and Ca+-(CO2)n (n=1,2) (Ca+-(CO)n과 Ca+-(CO2)n (n=1,2)의 구조와 결합에너지에 대한 이론 연구)

  • Park, Gil-Soon;Sung, Eun-Mo
    • Journal of the Korean Chemical Society
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    • v.53 no.3
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    • pp.272-278
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    • 2009
  • The optimized structures and vibrational frequencies for $Ca^+-(CO)_n$ and $Ca^+-(CO_2)_n$ (n=1,2) complexes were calculated with MP2 and B3LYP methods employing 6-311++G(2d,p) basis sets. Also the binding energies were investigated for all complexes to compare the stabilities. For $Ca^+-(CO)_n$ C-bonded complexes are more stable than O-bonded complexes. Two stable conformations, linear and $C_{2v}$ form, are possible for $Ca^+-(CO)_2$ complexes and the $C_{2v}$ form is more stable than the linear form. $Ca^+-(CO_2)_2$ also has two possible conformations and linear form has slightly lower energy than $C_{2v}$ form.

Synthesis of 90/150 Uniform CA and Computation of Characteristic Polynomial corresponding to uniform CA (90/150 Uniform CA의 합성 및 특성다항식 계산)

  • Choi, Un-Sook;Cho, Sung-Jin;Yim, Ji-Mi
    • The Journal of the Korea institute of electronic communication sciences
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    • v.5 no.1
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    • pp.10-16
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    • 2010
  • 90/150 CA is a CA completely specified by using rule 90 and rule 150. Since 90/150 CA whose minimal and characteristic polynomials are identical has outstanding randomness, this CA is more attractive than LFSR. Sarkar proposed a scheme based on the 90 uniform CA and the 150 uniform CA. That scheme provided authentication by digital signature and other basic security requirements like confidentiality. In this paper we analyze 90 or 150 uniform CA and give a synthesis method of 2n-cell uniform CA and (2n+1)-cell uniform CA using a special n-cell 90/150 CA. And we propose an effective method of computation of characteristic polynomial corresponding to uniform CA.

Electronic Structures and Magnetism at the Interfaces of Rocksalt Structured Half-metallic NaN and CaN (암염구조를 가지는 반쪽금속 CaN과 NaN의 계면 전자구조에 관한 연구)

  • Kim, Dong-Chul;Bialek, Beata;Lee, Jae-Il
    • Journal of the Korean Magnetics Society
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    • v.22 no.5
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    • pp.157-161
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    • 2012
  • Magnetism at the interfaces of rocksalt structured half-metals, NaN and CaN were investigated by use of the first-principles band calculations. The electronic structures for the simple interface and mixed interface systems were calculated by the FLAPW (full-potential linearized augmented plane wave) method. From the calculated number of electrons in muffin-tin spheres of each atom, we found, for the simple interface system, that the magnetic moment of the N atom in the CaN (NaN) side is increased (decreased) compared to those of inner N atoms. For the mixed interface system, the magnetic moments of the interface N atoms are similar to the averaged value for the inner N atoms in CaN and NaN side. Among four interface N atoms, the N atom connected to Na atoms in the upper and down layers has the largest magnetic moment and that connected to Ca atoms has the smallest. The number of p electrons in each N atom and the calculated density of states explain well the above situation.

Development and Luminescent Characteristics of $CaSiN_2$ Based Phosphors ($CaSiN_2$를 모체로 하는 형광체의 개발 및 발광 특성)

  • Lee, Soon-Seok;Lim, Sung-Kyoo
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.36D no.10
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    • pp.31-36
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    • 1999
  • The $CaSiN_2:Eu$ and $CaSiN_2:Tb$ phosphors were synthesized and analyzed to develop new nitride compound phosphors. $Ca_3N_2$, $Si_3N_4$ and $EuF_3$(or $TbF_3$) powders were mixed, cold-pressed, and sintered to synthesize $CaSiN_2:Eu$ and $CaSiN_2:Tb$ phosphors. Photoluminescence(PL) and electroluminescence(EL) characteristics of the synthesized phosphors were measured and found to be similar to general emission spectra of 뗘 and Tb ion, respecticely. Threshold voltage($V_{th)$) and luminance of the $CaSiN_2:Eu$ TFEL device fabricated by sputtering were 90 V and 1.62 $cd/m^2$ at 280 V, respectively. The charge-voltage(Q-V) and transferred charge-phosphor field($Q_t-F_p$) characteristics of the TFEL devices were also measured.

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Studies on Secretion of Catecholamines Evoked By DMPP and McN-A-343 in the Rat Adrenal Gland (흰쥐 적출 부신에서 DMPP 및 McN-A-343의 Catecholamine 분비작용에 관한 연구)

  • Lim, Dong-Yoon;Hwang, Doo-Hwan
    • The Korean Journal of Pharmacology
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    • v.27 no.1
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    • pp.53-67
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    • 1991
  • The characteristics and differences between DMPP and McN-A-343 on the secretory effect of catecholamines(CA) were studied in the isolated perfused rat adrenal glands. DMPP(100 uM) and McN-A-343(100 uM) perfused into an adrenal vein of the gland casued significant increases in CA secretion. On molar basis the secretory effect of McN-A-343 was about one fifth as potent as that of DMPP. Tachyphylaxis to releasing effects of CA evoked by DMPP and McN-A-343 was not observed by repeated perfusion of these agents. The DMPP-evoked CA secretion was significantly inhibited by pretreatment with chlorisondamine, desipramine and profusion of $Ca^{2+}-free$ Krebs solution containing EGTA, while it was not affected by pirenzepine, ouabain and physostigmine. However, pretreatment with atropine rather enhanced CA release by DMPP. The releasing effect of CA induced by McN-A-343 was markedly depressed by pretreatment with atropine, pirenzepine, chlorisondamine, physostigmine, and perfusion of $Ca^{2+}-free$ medium plus EGTA but was not influenced by desipramine, except for the case of ouabain which clearly potentiated CA release by McN-A-343. These experimental results suggest that both DMPP and McN-A-343 cause greatly secretion of CA from the isolated perfused rat adrenal glands by a calcium-dependent exocytotic mechanism. The secretory effect of DMPP is due to the stimulation of cholinergic nicotinic receptors and the secretion by McN-A-343 via activation of selecive $M_{1}-muscarinic$ receptors in the adrenal gland. It is also thought that the DMPP-evoked secretory effect is much greater than McN-A-343-induced effect.

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Characteristic Polynomials of 90/150 CA <10 ⋯ 0> (90/150 CA <10 ⋯ 0>의 특성다항식)

  • Kim, Jin-Gyoung;Cho, Sung-Jin;Choi, Un-Sook;Kim, Han-Doo;Kang, Sung-Won
    • The Journal of the Korea institute of electronic communication sciences
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    • v.13 no.6
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    • pp.1301-1308
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    • 2018
  • 90/150 CA which are used as key generators of the cipher system have more randomness than LFSRs, but synthesis methods of 90/150 CA are difficult. Therefore, 90/150 CA synthesis methods have been studied by many researchers. In order to synthesize a suitable CA, the analysis of the characteristic polynomial of 90/150 CA should be preceded. In general, the characteristic of polynomial ${\Delta}_n$ of n cell 90/150 CA is obtained by using ${\Delta}_{n-1}$ and ${\Delta}_{n-2}$. Choi et al. analyzed $H_{2^n}(x)$ and $H_{2^n-1}(x)$, where $H_k(x)$ is the characteristic polynomial of k cell 90/150 CA with state transition rule <$10{\cdots}0$>. In this paper, we propose an efficient method to obtain $H_n(x)$ from $H_{n-1}(x)$ and an efficient algorithm to obtain $H_{2^n+i}(x)$ and $H_{2^n-i}(x)$ ($1{\leq}i{\leq}2^{n-1}$) from $H_{2^n}(x)$ by using this method.

Characteristic Polynomial of 90 UCA and Synthesis of CA using Transition Rule Blocks (90 UCA의 특성다항식과 전이규칙 블록을 이용한 CA 합성법)

  • Choi, Un-Sook;Cho, Sung-Jin
    • The Journal of the Korea institute of electronic communication sciences
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    • v.13 no.3
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    • pp.593-600
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    • 2018
  • Cellular automata (CA) have been applied to effective cryptographic system design. CA is superior in randomness to LFSR due to the fact that its state is updated simultaneously by local interaction. To apply these CAs to the cryptosystem, a study has been performed how to synthesize CA corresponding to given polynomials. In this paper, we analyze the recurrence relations of the characteristic polynomial of the 90 UCA and the characteristic polynomial of the 90/150 CA whose transition rule is <$00{\cdots}001$>. And we synthesize the 90/150 CA corresponding to the trinomials $x^{2^n}+x+1(n{\geq}2)$ satisfying f(x)=f(x+1) using the 90 UCA transition rule blocks and the special transition rule block. We also analyze the properties of the irreducible factors of trinomials $x^{2^n}+x+1$ and propose a 90/150 CA synthesis algorithm corresponding to $x^{2^n}+x^{2^m}+1(n{\geq}2,n-m{\geq}2)$.

On the Construction of the 90/150 State Transition Matrix Corresponding to the Trinomial x2n-1 + x + 1 (3항 다항식 x2n-1 + x + 1에 대응하는 90/150 상태전이행렬의 구성)

  • Kim, Han-Doo;Cho, Sung-Jin;Choi, Un-Sook
    • The Journal of the Korea institute of electronic communication sciences
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    • v.13 no.2
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    • pp.383-390
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    • 2018
  • Since cellular automata(CA) is superior to LFSR in randomness, it is applied as an alternative of LFSR in various fields. However, constructing CA corresponding to a given polynomial is more difficult than LFSR. Cattell et al. and Cho et al. showed that irreducible polynomials are CA-polynomials. And Cho et al. and Sabater et al. gave a synthesis method of 90/150 CA corresponding to the power of an irreducible polynomial, which is applicable as a shrinking generator. Swan characterizes the parity of the number of irreducible factors of a trinomial over the finite field GF(2). These polynomials are of practical importance when implementing finite field extensions. In this paper, we show that the trinomial $x^{2^n-1}+X+1$ ($n{\geq}2$) are CA-polynomials. Also the trinomial $x^{2^a(2^n-1)}+x^{2^a}+1$ ($n{\geq}2$, $a{\geq}0$) are CA-polynomials.

Generation of Maximum Length Cellular Automata (최대길이를 갖는 셀룰라 오토마타의 생성)

  • Choi Un-Sook;Cho Sung-Jin
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.14 no.6
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    • pp.25-30
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    • 2004
  • Linear cellular automata(CA) which generate maximum-length cycles, have wide applications in generation of pseudo-random patterns, signature analysis, cryptography and error correcting codes etc. Linear CA whose characteristic polynomial is primitive has been studied. In this paper Ive propose a effective method for generation of a variety of maximum-length CA(MLCA). And we show that the complemented CA's derived from a linear MLCA are all MLCA. Also we analyze the Properties of complemented MLCA. And we prove that the number of n-cell MLCA is ${\phi}(2^{n}-1)2^{n+1}$/n.

Human Cytomegalovirus Replication and $Ca^{2+}$ Response in Human Cell Lines of Neuronal Origin (신경세포에서의 Human Cytomegalovirus 증식과 이에 따른 세포내 유리칼슘 농도 변화)

  • Kang, Kyung-Hee;Lee, Chan-Hee
    • The Journal of Korean Society of Virology
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    • v.26 no.1
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    • pp.1-8
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    • 1996
  • Human cytomegalovirus (HCMV) replication and $Ca^{2+}$ response in human cell lines of neuronal origin were investigated. SK-N-SH (neuroblastoma cells) and A172 cells (glioblastoma cells) were used. SK-N-SH cells were permissive for HCMV multiplication with a delay of one day compared to virus multiplication in human embryo lung (HEL) cells. The delay of HCMV multiplication in SK-N-SH cells appeared to be correlated with a delay in the $Ca^{2+}$ response. The cytoplasmic free $Ca^{2+}$ concentration ($[Ca^{2+}]_i$) began to increase at 12 h p.i. in HCMV-infected SK-N-SH cells, while $[Ca^{2+}]_i$ increase in HCMV-infected HEL cells was observed as early as 3 h p.i. On the whole, the level of the increase in $[Ca^{2+}]_i$ in SK-N-SH cells was about 30% of that in HEL cells. On the other hand, in A172 cells infected with HCMV, neither production of infectious virus nor detectable increase in $[Ca^{2+}]_i$ was observed. Treatment with TPA of HCMV-infected SK-N-SH cells resulted in $[Ca^{2+}]_i$ increase at 6 h p.i. The stimulatory effect of TPA on HCMV- induced $[Ca^{2+}]_i$ increase continued until 12 h p.i., but TPA failed to stimulate the $Ca^{2+}$ response in SK-N-SH cells at 24 h p.i., suggesting that the effect of TPA had disappeared in SK-N-SH cells at that time point. In conclusion, SK-N-SH cells are permissive for HCMV replication and the delay in $Ca^{2+}$ response may be a consequence of the lower responsiveness of SK-N-SH cells than HEL cells to HCMV infection.

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