• Journal of the Microelectronics and Packaging Society
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• v.30 no.4
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• pp.91-97
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• 2023

Electrochemical (EC) CO₂ reduction is a promising method to convert CO₂ into valuable hydrocarbon fuels and chemicals ecofriendly. Here, we report on a facile method to synthesize surface-controlled SnO₂/Cu(OH)₂ nanowires (NWs) and its EC reduction of CO₂ to HCOOH and CO. The SnO₂/Cu(OH)₂ NWs (-16 mA/cm²) showed superior electrochemical performance compared to Cu(OH)2 NWs (-6 mA/cm²) at -1.0 V (vs. RHE). SnO₂/Cu(OH)₂ NWs showed the maximum Faradaic efficiency for conversion to HCOOH (58.01 %) and CO (29.72 %). The optimized catalyst exhibits a high C1 Faradaic efficiency stable electrolysis for 2 h in a KHCO₃ electrolyte. This study facilitates the potential for the EC reduction of CO₂ to chemical fuels.

• Applied Chemistry for Engineering
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• v.32 no.4
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• pp.431-441
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• 2021

In this study, PEBAX/GO-PEI and PEBAX/ZIF-8@GO-PEI composite membranes were prepared by varying the contents of GO and ZIF-8@GO in PEBAX, and also the gas permeation characteristics of N₂ and CO₂ was studied. Overall, the N₂ and CO₂ permeability of the PEBAX/GO-PEI composite membrane decreased as the GO content increased, and the CO₂/N₂ selectivity slightly increased. In the case of PEBAX/ZIF-8@GO-PEI composite membrane, the permeability of N₂ decreased, but CO₂ increased to 1 wt% of ZIF-8@GO and then decreased in the content thereafter. The CO₂/N₂ selectivity at 1 wt% of ZIF-8@GO was 92.3, showing the highest selectivity. This is thought to be due to the greatest effect of GO and ZIF-8 with good affinity for CO₂ alongside the effect of porosity ZIF-8 while improving compatibility with PEBAX and dispersing evenly. In addition, PEBAX/ZIF-8@GO-PEI composite membrane improved both CO₂ permeability and CO₂/N₂ selectivity than those of the PEBAX-PEI and PEBAX/GO-PEI membranes, except for ZIF-8@GO 5 wt%. The result was close to the Robeson upper bound.

• Korean Journal of Environmental Agriculture
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• v.42 no.3
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• pp.231-238
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• 2023

We analyzed the variations in the CO₂ concentration and temperature between a CO₂-enriched and control greenhouse. We cultivated Alstroemeria 'Hanhera' in the two greenhouses and assessed the growth parameters (stem length, stem thickness, and the number of flowers) and yield. The CO₂-enriched greenhouse had a CO₂ generator that produced CO₂ at rate of 0.36 kg/h and its windows were programmed to open when the temperature exceeded 20℃ and close when it dropped below 15℃. The control greenhouse had no additional CO₂ supplementation, and its windows were programmed to open when the temperature exceeded 20℃ and close at approximately 17:00. In the morning, CO₂ concentration remained above 500 ppm in the CO₂-enriched greenhouse, which was higher than that in the control greenhouse (approximately 370 ppm). The ventilation effect only through the side windows to reduce the temperature in both greenhouses did not appear dynamically. CO₂ supplementation promoted plant growth, resulting in a significant increase in plant yield of over 60% compared to that of the control greenhouse. Our findings suggest that elevated CO₂ concentration in the morning can significantly promote the growth and development of Alstroemeria during the winter.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.3
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• pp.226-233
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• 2023

In this study, two phases were conducted to investigate the direct injection of gaseous CO₂ into cement mortar. The aim was to advance carbon capture, utilization, and storage (CCUS) technology by harnessing industrial waste CO₂ from the domestic ready-mixed concrete industry. In the first phase, the factors influencing the physical properties of cement mortar when using gaseous CO₂ were identified. This included a review of materials to achieve physical properties comparable to a reference formulation. As a result of this phase, it was confirmed that traditional approaches, such as adjusting the water-to-cement ratio, had limitations in achieving the desired physical properties. Consequently, the second phase focused on the optimization of CO₂-injected mortar. This involved studying the CO₂ application and mixing method for cement mortar. Changes in properties were observed when gaseous CO₂ was injected into the mortar. The optimal injection quantity and time to enhance the compressive strength of mortar were determinded. As a result, this study indicated that an extra mixing time exceeding 120 seconds was necessary, compared to conventional mortar. The optimal CO₂ injection rate was identified as 0.1 to 0.2 % by weight of cement, taking both flowability and compressive strength performance into account. Increasing the CO₂ injection time did not further enhance strength. For this approach to be employed as a CCUS technology, additional studies are required, including a microstructural analysis evaluating the amount of immobilized CO₂.

• Environmental and Resource Economics Review
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• v.30 no.2
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• pp.299-323
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• 2021

This study investigated the impact of information and communication technology (ICT), trade openness, financial development, and economic growth on CO₂ emissions in Korea from 1990 to 2016. The cointegration relationship of the variables was confirmed by an autoregressive distributed lag (ARDL) bounds test. In the long-run, economic growth was statistically significant factor in the increase in CO₂ emissions, while other factors, as well as ICT, did not significant factors in the changes in CO₂ emissions. In the long-run, a link between economic growth and CO₂ emissions has been confirmed, but other factors, including ICT, have not been able to confirm the link between CO₂ emissions in the long-run. Meanwhile, in the short-run, economic growth and ICT increased CO₂ emissions, and financial development led to a decrease in CO₂ emissions. Trade openness did not have a significant effect on CO₂ emissions in the short-run as in the long-run. In particular, ICT did not contribute to the reduction of CO₂ emissions in the short-run as well as the long-run. In order to induce CO₂ mitigation through ICT, the development and deployment of technology that efficiently save energy by using ICT should be further promoted.

• Journal of the Korean Recycled Construction Resources Institute
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• v.12 no.1
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• pp.8-16
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• 2024

Limestone (CaCO₃, calcium carbonate), which is used as a raw material in the portland cement and steel industry, emits CO₂ through decarbonation by high temperatures in the manufacturing process. To reduce CO₂ emissions by the use of raw materials like limestone, it has been proposed to replace limestone with various industrial by-products that contain CaO but less or none of the carbonated minerals, that cause CO₂ emissions. Loss of Ignition (LOI), Thermogravimetric analysis (TG), and Infrared Spectroscopy (IR) are used to quantitative the amount of CO₂ emission by using these industrial by-products, but CO₂ emissions can be either over or underestimated depending on the characteristics of by-product materials. In this study, we estimated CO₂ contents by LOI, TG, IR and DTG(Differential Thermogravimetric analysis) of calcite(CaCO₃) and samples that contain CO₂ in the form of carbonate and whose weight increases by oxidation at high temperatures. The test results showed for CaCO₃ samples, all test methods have a sufficient level of reliability. On the other hand, for the CO₂ content of the sample whose weight increases at high temperature, LOI and TG did not properly estimate the CO₂ content of the sample, and IR tended to overestimate compared to the predicted value, but the estimated result by DTG was close to the predicted valu e. From these resu lts, in the case of samples that contain less than a few percent of CO₂ and whose weight increases during the temperature that carbonate minerals decompose, estimating the CO₂ content using DTG is a more reasonable way than LOI, TG, and IR.

• Korean Journal of Remote Sensing
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• v.39 no.2
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• pp.129-142
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• 2023

This study analyzed the ratio of carbon monoxide (CO) and carbon dioxide (CO₂), CO and nitrogen dioxide (NO₂) for cities and regionsin Korea and China using column-averaged carbon dioxide dry-air mole fraction (XCO₂) of the Orbiting Carbon Observatory-2/3, CO and NO₂ vertical column density (named XCO, XNO₂ in thisstudy) of TROPOspheric monitoring instrument from April 2018 to April 2022, and presented the relationship between socioeconomic indicators (population, number of vehicles, Gross Regional Domestic Product) and ratio, and differences in characteristics between Korea and China. First, CO₂ and CO were analyzed after calculating ΔXCO₂ and ΔXCO removing the background value and trend line due to the difference in atmospheric residence time of three gaseous substances (CO₂, CO, and NO₂). Comparing the three values by regions, ΔXCO and ΔXCO₂ were relatively higher in China and XNO₂ were higher in Korea and the ratio of both values (ΔXCO/ΔXCO₂, ΔXCO/XNO₂) was higher in China than in Korea. ΔXCO/ΔXCO₂, ΔXCO/XNO₂ and socioeconomic indicators have a positive correlation suggesting that the concentration of air pollutants and greenhouse gases is higher as the city is large and the economic activity is active. Regarding the differences in the ratio characteristics of Korea and China, the relationship between ΔXCO and ΔXCO₂ showed a negative correlation in Korea and a positive correlation in China. When the relationship between ΔXCO and XNO₂ was examined for summer and winter, the change of ΔXCO by season was not significant in Korea, whereasthe change of ΔXCO and XNO₂ by season waslarge in China resulting in the relationship between two countries appeared differently. These results suggest that seasonal variability and national emission characteristics should be considered in the process of analyzing the ratio of greenhouse gases to air pollutants.

• Membrane Journal
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• v.32 no.5
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• pp.325-335
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• 2022

In this study, zeolitic imidazolate framework-9 (ZIF-9) was synthesized and Pebax/ZIF-9 mixed membranes were prepared by varying the content in poly(ether-b-amide)-1657 (Pebax-1657), and then a single gas (N₂, CO₂) was permeated to investigate the gas permeation characteristics of the mixed membrane. As the ZIF-9 content incorporated into the pure Pebax membrane increased, the N₂ permeability gradually decreased, and the CO₂ permeability increased up to the Pebax/ZIF-9 3 wt% mixed membrane, and then decreased at the content thereafter. And among the mixed membranes, the Pebax/ZIF-9 3 wt% mixed membrane showed the highest selectivity of 69.3 by selectively accepting CO₂ as the gate-opening phenomenon occurred for the polar gas, CO₂. In addition, both the CO₂ permeability and the CO₂/N₂ selectivity increased, resulting in the closest Robeson upper-bound.

• Journal of the Korean Ceramic Society
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• v.45 no.2
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• pp.112-118
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• 2008

To prepare the high-capacity cathode material with improved electrochemical performances, nanoparticles of $C0_3(PO_4)_2$ were coated on the powder surface of $Li[Co_{0.1}Ni_{0.15}Li_{0.2}Mn_{0.55}]O_2$, which was already synthesized by simple combustion method. The coated powders after the heat treatment at >$700^{\circ}C$ surely showed well-structured crystalline property with nanoscale surface coating layer, which was consisted of $LiCOPO_4$ phase formed from the reaction bwtween $CO_3(PO_4)_2$ and lithium impurities. In addition, cycle performance was particularly improved by the $CO_3(PO_4)_2$-coating for the cathode material for lithium rechargeable batteries.

• Korean Journal of Mineralogy and Petrology
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• v.36 no.4
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• pp.221-232
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• 2023

Carbon neutrality requires carbon dioxide reduction technology and alternative green energy sources. Palygorskite is a clay mineral with a ribbon structure and possess a large surface area due to the nanoscale pore size. The clay mineral has been proposed as a potential material to capture carbon dioxide (CO₂) and possibly to store eco-friendly hydrogen gas (H2). We report our preliminary results of grand canonical Monte Carlo (GCMC) simulations that investigated the adsorption isotherms and mechanisms of CO₂ and H₂ into palygorskite nanopores at room temperature. As the chemical potential of gas increased, the adsorbed amount of CO₂ or H₂ within the palygorskite nanopores increased. Compared to CO₂, injection of H₂ into palygorskite required higher energy. The mean squared displacement within palygorskite nanopores was much higher for H₂ than for CO₂, which is consistent with experiments. Our simulations found that CO₂ molecules were arranged in a row in the nanopores, while H₂ molecules showed highly disordered arrangement. This simulation method is promising for finding Earth materials suitable for CO₂ capture and H₂ storage and also expected to contribute to fundamental understanding of fluid-mineral interactions in the geological underground.