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http://dx.doi.org/10.14579/MEMBRANE_JOURNAL.2022.32.5.325

Gas Permeation Characteristics by Pebax/ZIF-9 Mixed Matrix Membrane  

Yoon, Soong Seok (Department of Chemical Engineering and Materials Science, Sangmyung University)
Hong, Se Ryeong (Kyedang College of General Educations, Sangmyung University)
Publication Information
Membrane Journal / v.32, no.5, 2022 , pp. 325-335 More about this Journal
Abstract
In this study, zeolitic imidazolate framework-9 (ZIF-9) was synthesized and Pebax/ZIF-9 mixed membranes were prepared by varying the content in poly(ether-b-amide)-1657 (Pebax-1657), and then a single gas (N2, CO2) was permeated to investigate the gas permeation characteristics of the mixed membrane. As the ZIF-9 content incorporated into the pure Pebax membrane increased, the N2 permeability gradually decreased, and the CO2 permeability increased up to the Pebax/ZIF-9 3 wt% mixed membrane, and then decreased at the content thereafter. And among the mixed membranes, the Pebax/ZIF-9 3 wt% mixed membrane showed the highest selectivity of 69.3 by selectively accepting CO2 as the gate-opening phenomenon occurred for the polar gas, CO2. In addition, both the CO2 permeability and the CO2/N2 selectivity increased, resulting in the closest Robeson upper-bound.
Keywords
Pebax-1657; ZIF-9; permeability; selectivity;
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