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Size Tailored Nanoparticles of ZrN Prepared by Single-Step Exothermic Chemical Route

  • Lee, Sang-Ki;Park, Kyung-Tae;Ryu, Hong-Youl;Nersisyan, Hayk H.;Lee, Kap-Ho;Lee, Jong-Hyeon
    • Korean Journal of Materials Research
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    • v.22 no.5
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    • pp.243-248
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    • 2012
  • ZrN nanoparticles were prepared by an exothermic reduction of $ZrCl_4$ with $NaN_3$ in the presence of NaCl flux in a nitrogen atmosphere. Using a solid-state combustion approach, we have demonstrated that the zirconium nitride nanoparticles synthesis process can be completed in only several minutes compared with a few hours for previous synthesis approaches. The chemistry of the combustion process is not complex and is based on a metathesis reaction between $ZrCl_4$ and $NaN_3$. Because of the low melting and boiling points of the raw materials it was possible to synthesize the ZrN phase at low combustion temperatures. It was shown that the combustion temperature and the size of the particles can be readily controlled by tuning the concentration of the NaCl flux. The results show that an increase in the NaCl concentration (from 2 to 13 M) results in a temperature decrease from 1280 to $750^{\circ}C$. ZrN nanoparticles have a high surface area (50-70 $m^2/g$), narrow pore size distribution, and nano-particle size between 10 and 30 nm. The activation energy, which can be extracted from the experimental combustion temperature data, is: E = 20 kcal/mol. The method reported here is self-sustaining, rapid, and can be scaled up for a large scale production of a transition metal nitride nanoparticle system (TiN, TaN, HfN, etc.) with suitable halide salts and alkali metal azide.

A Study on the Electrochemical Properties Fabrication Process of Mg-Ca Sacrificial Anode for the Corrosion Protection of Steel Structures (철 구조물의 부식방지를 위한 Mg-Ca 희생양극의 전기화학적 특성과 제조에 관한 연구)

  • Park, Kang-Geun;Kim, Hye-Sung
    • Journal of Korean Association for Spatial Structures
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    • v.6 no.4 s.22
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    • pp.73-80
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    • 2006
  • It is an object of the present paper to investigate a electrochemical properties of Mg-based sacrificial anodes and the effect of calcium added from calcium chloride into magnesium on the melt protection during the melting. Electrochemical data will be correlated with processing control variables, and the microstructural change by the addition of CaCl2. Small addition of calcium into magnesium from CaCl2 imparts beneficial effect in electrochemical properties of Mg alloys, primarily, through microstructural modifications. In addition, the protection effect of the melts surface of Ca with low melting point modification is obtained by adding Ca not more than 0.6%.

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Modeling of the Nitrate Adsorption Kinetics onto $ZnCl_2$ Treated Granular Activated Carbon (염화아연으로 표면개질된 입상활성탄의 질산성질소 흡착속도의 모델링 연구)

  • Ji, Min-Kyu;Jung, Woo-Sik;Bhatnagar, Amit;Jeon, Byong-Hun
    • Journal of Soil and Groundwater Environment
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    • v.13 no.3
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    • pp.21-26
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    • 2008
  • Nitrate adsorption from aqueous solutions onto zinc chloride ($ZnCl_2$) treated coconut Granular Activated Carbon (GAC) was studied in a batch mode at two different initial nitrate concentrations (25 and 50 mg/L). The rate of nitrate uptake on prepared media was fast in the beginning, and 50% of adsorption was occurred within 10 min. The adsorption equilibrium was achieved within one hour. The mechanism of adsorption of nitrate on $ZnCl_2$ treated coconut GAC was investigated using four simplified kinetic models : the rate parameters were calculated for each model. The kinetic analysis indicated that pseudo-second-order kinetic with pore-diffusion-controlled was the best correlation of the experimental kinetic data in the present adsorption study.

Inhibition of nicotine-induced Streptococcus mutans biofilm formation by salts solutions intended for mouthrinses

  • Balhaddad, Abdulrahman A.;Melo, Mary Anne S.;Gregory, Richard L.
    • Restorative Dentistry and Endodontics
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    • v.44 no.1
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    • pp.4.1-4.10
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    • 2019
  • Objectives: Biofilm formation is critical to dental caries initiation and development. The aim of this study was to investigate the effects of nicotine exposure on Streptococcus mutans (S. mutans) biofilm formation concomitantly with the inhibitory effects of sodium chloride (NaCl), potassium chloride (KCl) and potassium iodide (KI) salts. This study examined bacterial growth with varying concentrations of NaCl, KCl, and KI salts and nicotine levels consistent with primary levels of nicotine exposure. Materials and Methods: A preliminary screening experiment was performed to investigate the appropriate concentrations of NaCl, KCl, and KI to use with nicotine. With the data, a S. mutans biofilm growth assay was conducted using nicotine (0-32 mg/mL) in Tryptic Soy broth supplemented with 1% sucrose with and without 0.45 M of NaCl, 0.23 M of KCl, and 0.113 M of KI. The biofilm was stained with crystal violet dye and the absorbance measured to determine biofilm formation. Results: The presence of 0.45 M of NaCl, 0.23 M of KCl, and 0.113 M of KI significantly inhibited (p < 0.05) nicotine-induced S. mutans biofilm formation by 52%, 79.7%, and 64.1%, respectively. Conclusions: The results provide additional evidence regarding the biofilm-enhancing effects of nicotine and demonstrate the inhibitory influence of these salts in reducing the nicotine-induced biofilm formation. A short-term exposure to these salts may inhibit S. mutans biofilm formation.

Adaptive Processing Algorithm Allocation on OpenCL-based FPGA-GPU Hybrid Layer for Energy-Efficient Reconfigurable Acceleration of Abnormal ECG Diagnosis (비정상 ECG 진단의 에너지 효율적인 재구성 가능한 가속을 위한 OpenCL 기반 FPGA-GPU 혼합 계층 적응 처리 알고리즘 할당)

  • Lee, Dongkyu;Lee, Seungmin;Park, Daejin
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.25 no.10
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    • pp.1279-1286
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    • 2021
  • The electrocardiogram (ECG) signal is a good indicator for early diagnosis of heart abnormalities. The ECG signal has a different reference normal signal for each person. And it requires lots of data to diagnosis. In this paper, we propose an adaptive OpenCL-based FPGA-GPU hybrid-layer platform to efficiently accelerate ECG signal diagnosis. As a result of diagnosing 19870 number of ECG signals of MIT-BIH arrhythmia database on the platform, the FPGA accelerator takes 1.15s, that the execution time was reduced by 89.94% and the power consumption was reduced by 84.0% compared to the software execution. The GPU accelerator takes 1.87s, that the execution time was reduced by 83.56% and the power consumption was reduced by 62.3% compared to the software execution. Although the proposed FPGA-GPU hybrid platform has a slower diagnostic speed than the FPGA accelerator, it can operate a flexible algorithm according to the situation by using the GPU.

A Study from a Highly Populated Country : Risk Factors Associated with Lower Back Pain in Middle-Aged Adults

  • Feda Anisah Makkiyah;Tasya Anggraini Sinaga; Namira Khairunnisa
    • Journal of Korean Neurosurgical Society
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    • v.66 no.2
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    • pp.190-198
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    • 2023
  • Objective : Low back pain (LBP) is a global health problem that affects the productivity of the patients. Several factors such as individual, occupational, and psychosocial factors increase the risk of LBP. However, only a few studies investigated those factors, especially in middle adulthood in Indonesia. Indonesia is a country with a young population that has been rapidly developing in recent years. This study was conducted to find out the factors associated with LBP in middle adulthood. Methods : This study is a cross-sectional observational analytic study using a convenience sampling method with a total sample of 3005 respondents. Data were collected using a questionnaire which was then analyzed using the chi-square test, Kolmogorov-smirnov, Spearman's Rank, and logistic regression test. Results : From the result of this study, it was found that the 12-month prevalence of LBP in middle-aged adults was 44,29%. Female (odds ratio [OR], 1.3; 95% confidence interval [Cl], 1.098-1.545; p=0.002), lack of physical exercises (OR, 0.87; 95% Cl, 0.794-0.959; p=0.005), high body mass index (OR, 1.09; 95% Cl, 1.009-1.187; p=0.002), stress level (OR, 1.26; 95% Cl, 1.088-1.458; p=0.002), and years of work experience (OR, 1.1; 95% Cl, 1.001-1.225; p=0.047) were determined as risk factors that significantly associated with LBP. Conclusion : LBP is quite common among middle-aged adults in Indonesia. Female gender, higher body mass index, lack of physical activity, stress level, and years of work experience were all potential risk factors for LBP in middle-aged adults. Middle-aged adults in Indonesia should be aware of LBP and avoid disabilities by identifying risk factors that may worsen LBP in the future.

Analysis on the Relationship of Geotechnical Strength Parameters in the Marine Clay (해성점토의 지반 강도정수 상관성 분석)

  • Heo, Yol;Kwon, Seonwuk;Lee, Cheokeun;Bae, Wooseok
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.7
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    • pp.33-43
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    • 2010
  • The physical characteristics of the marine clay in the Korean Peninsula, specifically Pusan areas of the south coast of Korea, were previously studied and reliable data from harbor construction projects were used for the relationship analysis of geotechnical strength parameters. The sample of marine clay classified to ML, MH, CL, CH and ML-CL from USCS were included for the analysis while the samples classified to SC were excluded in order to raise the degree of data analysis. Geotechnical strength properties, such as undrained shear strength, sensitivity ratio, and effective friction angle were analyzed and evaluated using the data obtained from unconfined compression test, triaxial compression test and field vane test. Abnormal values were extracted through statistical analysis. Moreover, the reliability of the results was improved by performing the evaluation of disturbance. Linear regression analysis was used for the relationship analysis, between undrained shear strength and depth. The relationship equation between undrained shear strength and depth was derived from the analysis of unconfined and triaxial compression test data of samples obtained at same location. Consequently, The relationship between depth and undrained shear strength is $S_u=0.015148D+0.04624$ and the undrained shear strength derived from the triaxial compression test was estimated to be about 1.26 of derived from the unconfined compression test.

A Study on the Information Exchange in Container Cargo Logistics (우리나라 컨테이너 물류 정보 교환에 관한 연구)

  • 박남규
    • Journal of the Korean Institute of Navigation
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    • v.18 no.3
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    • pp.81-103
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    • 1994
  • Increasing costs and competition in the global trade and transportation arena have led to a search for effient, cost-effective, particularly through the application of computer and information technologies. Most recently the introduction of Electronic Data Interchange(EDI) technologies in both trading and trade facili-tation activitiess have bagun to change the complextion of the international transport space. Korea as well as the other developing countries has become aware of the need to embrace EDI strate-gies in order to maintain a competitive market position with their more technologically advanced neighbou-ring and international trading partners. A way of EDI implementation, KMPA has invested large budgets in the research of the EDI since 1990. As the result of study in EDI of transport, KL-Net(Korea Logistics Network) was organized for the EDI business in cargo logistics. In spite of these KMPA's activities, the development plan of container logistics data interchange is not good and useful. So a new model of EDI in transportation is required by using the concepts of cargo data sharing. The purpose of this paper is to suggest a new way of container logistics data interchange model. This paper therefore analyze the information flow in the current container logistics and find the problem in the area to derive a new model. The followings are the results of this paper : (1) There are many problems and user's requirements in container logistics data interchange in Korea. (2) Many messages of UN/EDIFACT are able to be used in container logistics data interchange. (3) The container cargo data are stored in Container Logistics Network(CL-Net) database. And when necessary by requesting message transmission, the container logistics data interchange is possible. (4) Customs cargo clearance system and PORT-MIS can be linked to CL-Net. If the systems, however, are to introduce EDI in data interchange, the quality of user's software has to be assured.

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NMR Structure of Syndecan-4L reveals structural requirement for PKC signalling

  • Koo, Bon-Kyoung;Joon Shin;Oh, Eok-Soo;Lee, Weontae
    • Proceedings of the Korean Magnetic Resonance Society Conference
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    • 2002.08a
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    • pp.90-90
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    • 2002
  • Syndecans, transmembrane heparan sulfate proteoglycans, are coreceptors with integrin in cell adhesion process. It forms a ternary signaling complex with protein kinase C and phosphatidylinositol 4,5 bisphosphate (PIP2) for integrin signaling. NMR data indicates that cytoplasmic domain of syndecan-4 (4L) undergoes a conformational transition in the presence of PIP2, forming oligomeric conformation. The structure based on NMR data demonstrated that syndecan-4L itself forms a compact intertwined symmetric dimer with an unusual clamp shape for residues Leu$^{186}$ -Ala$^{195}$ . The molecular surface of the syndecan-4L dimer is highly positively charged. In addition, no inter-subunit NOEs in membrane proximal amino acid resides (Cl region) has been observed, demonstrating that the Cl region is mostly unstructured in syndecan-4L dimmer. However, the complex structure in the presence of PIP2 induced a high order multimeric conformation in solution. In addition, phosphorylation of cytoplasmic domain induces conformational change of syndecan-4, resulting inhibition of PKC signaling. The NMR structural data strongly suggest that PIP2 promotes oligomerization of syndecan-4 cytoplasmic domain for PKC activation and further induces structural reorganization of syndecan for mediating signaling network in cell adhesion procedure.

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Assessment of Groundwater Quality on a Watershed Scale by Using Groundwater Quality Monitoring Data (지하수수질측정망 자료를 이용한 유역단위 지하수 수질등급 평가)

  • Kim, Jeong Jik;Hyun, Yunjung
    • Journal of Soil and Groundwater Environment
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    • v.26 no.6
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    • pp.186-195
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    • 2021
  • In Korea, groundwater quality is monitored through National Groundwater Quality Monitoring Network (NGQMN) administered by Ministry of Environment. For a given contaminant, compliance to groundwater quality standards is assessed on a annual basis by monitoring the number of incidents that concentration exceeds the regulatory limit. However, this approach provides only a fractional information about groundwater quality degradation, and more crucial information such as location and severity of the contamination cannot be obtained. For better groundwater quality management on a watershed, a more spatially informative and intuitive method is required. This study presents two statistical methods to convert point-wise monitoring data into information on groundwater quality status of a watershed by using a proposed grading scale. The proposed grading system is based on readily available reference standards that classify the water quality into 4 grades. The methods were evaluated with NO3-, Cl-, and total coliform data in Geum River basin. The analyses revealed that groundwater in most watersheds of Geum River basin is good for domestic or/and drinking with no treatment. But, there was notable quality degradation in Bunam seawall and So-oak downstream standard watersheds contaminated by NO3- and Cl-, respectively.