• Title/Summary/Keyword: CATION

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Electrochemical Characterization of Electric Double Layer Capacitors Assembled with Pyrrolidinium-Based Ionic Liquid Electrolytes

  • Cho, Jinhyun;Shin, Won-Kyung;Kim, Dong-Won;Kim, Young Rae;Lee, Byung Jun;Kim, Sang-Gil
    • Journal of Electrochemical Science and Technology
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    • v.7 no.3
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    • pp.199-205
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    • 2016
  • We present the electrochemical performance of electric double layer capacitors (EDLCs) assembled with pyrrolidinium (Pyr)-based ionic liquid electrolytes at 55 ℃. Cations with various alkyl chain lengths were employed in Pyr-based ionic liquids to investigate the effect of cation structure on the cycling stability of EDLCs. The EDLCs exhibited initial specific capacitances ranging from 122.4 to 131.6 F g−1 based on activated carbon material at 55 ℃. Cycling data and XPS results demonstrate that Pyr-based ionic liquid with longer alkyl chain is more effective for enhancing the cycling stability of EDLC by suppressing the reductive decomposition of pyrrolidinium cations during cycling at high temperatures.

Development of Pore-filled Ion-exchange Membranes for Efficient All Vanadium Redox Flow Batteries

  • Kang, Moon-Sung
    • Journal of the Korean Electrochemical Society
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    • v.16 no.4
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    • pp.204-210
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    • 2013
  • Thin pore-filled cation and anion-exchange membranes (PFCEM and PFAEMs, $t_m=25-30{\mu}m$) were prepared using a porous polymeric substrate for efficient all-vanadium redox flow battery (VRB). The electrochemical and charge-discharge performances of the membranes have been systematically investigated and compared with those of commercially available ion-exchange membranes. The pore-filled membranes were shown to have higher permselectivity as well as lower electrical resistances than those of the commercial membranes. In addition, the VRBs employing the pore-filled membranes exhibited the respectable charge-discharge performances, showing the energy efficiencies (EE) of 82.4% and 84.9% for the PFCEM and PFAEM, respectively (cf. EE = 87.2% for Nafion 1135). The results demonstrated that the pore-filled ion-exchange membranes could be successfully used in VRBs as an efficient separator by replacing expensive Nafion membrane.

Preparation of $(La, Sr)MnO_3$ Powder by Glycine-Nitrate Process Using Oxide as Starting Materials (Glycine-Nitrate Process를 이용한 산화물 출발물질로부터 $(La, Sr)MnO_3$ 분말의 제조)

  • 김재동;문지웅;김구대;김창은
    • Journal of the Korean Ceramic Society
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    • v.34 no.10
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    • pp.1003-1008
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    • 1997
  • The (La, Sr)MnO3 powder used as air-electrode material of Solid Oxide Cell (SOFC) was synthesized by Modified-GNP(Modified-Glycine Nitrate Process). The powders were prepared using oxide and carbonate stable in atmosphere and nitric acid was used as a solvent of starting material as well as an oxidant for combustion. The (La, Sr)MnO3 powders were synthesized with 0.5, 1, 2, 3, 4 of glycine/cation molar ratio. The ICP (Inductively Coupled Plasma Mass Spectrometer) result represented compositional equality between synthesized and desired powders. In case of 2 molar ratio, the as-synthesized powder showed perovskite phase and specific surface area were 19 $m^2$/g. After calcination of 85$0^{\circ}C$, the calcined powder except 0.5, 1 molar ratio of glycine to cation showed perovskite phase.

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Mössbauer Analysis of Cations on Iron Oxyhydroxide Formation

  • Oh, Sei-Jin;Kwon, Soon-Ju
    • Journal of the Korean Magnetics Society
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    • v.15 no.2
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    • pp.85-91
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    • 2005
  • Effect of different cations to the formation of iron oxyhydroxide was studied using $M\ddot{o}ssbauer$ spectroscopy, X-ray diffraction (XRD) and BET. Redox Potential and pH were measured for the determination of the internal reaction rate, as well. The phases of iron oxyhydroxide could not be the same with each other, due to the presence of different cations in solution. Although the oxyhydroxide compound was composed of the same phases, the fraction of each phase was different from each other. The internal reaction rate was varied by the substitution of cation. It could be a cause of the different phase and particle size of oxyhydroxide compound.

Purification of Phytase from Aspergillus ficuum and Production of Anti-phytase Antibody (Aspergillus ficuum의 Phytase의 정제와 Anti-phytase 항체생산)

  • Kim, Keun
    • The Korean Journal of Mycology
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    • v.27 no.4 s.91
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    • pp.299-303
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    • 1999
  • Phytase(myo-inositol-hexakis phosphate 3-phosphohydrolase, E C 3.1.3.8) sequentially hydrolyzes phytate to myo-inositol and inorganic phosphate. Phytase of Aspergillus ficuum was purified to homogeneity using ultrafiltration, cation exchange column and anion exchange column. It's molecular weight is estimated as around 90,000 by SDS-PAGE. Antibody against the phytase was produced by immunizing mice with the purified phytase. The titer of the antibody was determined to be 1/25,000.

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LAMMER Kinase Lkh1 Is an Upstream Regulator of Prk1-Mediated Non-Sexual Flocculation in Fission Yeast

  • Park, Yoon-Dong;Kwon, Soo Jeong;Bae, Kyung Sook;Park, Hee-Moon
    • Mycobiology
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    • v.46 no.3
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    • pp.236-241
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    • 2018
  • The cation-dependent galactose-specific flocculation activity of the Schizosaccharomyces pombe null mutant of $lkh1^+$, the gene encoding LAMMER kinase homolog, has previously been reported by our group. Here, we show that disruption of $prk1^+$, another flocculation associated regulatory kinase encoding gene, also resulted in cation-dependent galactosespecific flocculation. Deletion of prk1 increased the flocculation phenotype of the $lkh1^+$ null mutant and its overexpression reversed the flocculation of cells caused by lkh1 deletion. Transcript levels of $prk1^+$ were also decreased by $lkh1^+$ deletion. Cumulatively, these results indicate that Lkh1 is one of the negative regulators acting upstream of Prk1, regulating non-sexual flocculation in fission yeast.

The Effect of Manganese Substituted M-type Hexagonal Ba-ferrite

  • Lee, In-Kyu;Sur, Jung-Chul;Shim, In-Bo;Kim, Chul-Sung
    • Journal of Magnetics
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    • v.14 no.2
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    • pp.93-96
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    • 2009
  • The Mn-substituted M-type Ba-ferrite ($BaFe_{12-x}Mn_xO_{19}$; x = 0, 2, 4, 6) powders were prepared by the HTTD (High Temperature Thermal Decomposition) method. The effect of $Mn^{3+}$ Jahn-Teller ions on the magnetic properties has been studied by x-ray diffraction, vibrating sample magnetometry, and $M{\ddot{o}}ssbauer$ spectroscopy. With increasing Mn substitution, the lattice parameter $a_0$ increases while $c_0$ decreases. The magnetocrystalline anisotropy constants ($K_1$) were determined as 2.9, 2.2, 1.8, and, $1.3{\times}10^6\;erg/cm^3$ for x = 0, 2, 4, and 6, respectively, by the LAS method. We have studied the change of cation distribution by $M{\ddot{o}}ssbauer$ spectroscopy which is closely related to $K_1$.

The Effect of Ginseng Saponin on Morphine Action of $Qo_2$ and Na, K content in Cerebral Cortex Slices of Rat (인삼(人蔘) Saponin 이 Morphine 에 의(依)한 Rat 대뇌피질절편(大腦皮質切片) 산소소비양(酸素消費量) 및 $Na^+$, $K^+$ 소장(消長)에 미치는 영향(影響))

  • Park, Chan-Woong
    • The Korean Journal of Pharmacology
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    • v.5 no.1
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    • pp.29-33
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    • 1969
  • The effects of Ginseng saponin on respiration and $Na^+$, $K^+$ content of rat cerebral cortex slices were investigated to determine the action of Ginseng saponin on brain cortex at cellular level. There are many reports for the study of Ginseng on central stimulatory action in experimental animals. The electrical stimulation of slices of cortex causes a loss of potassium. And the respiration is needed to maintain a supply of energy for active cation transport. The reduction in $Qo_2$ is a consequence of primary cessation of active cation transport. Ginseng saponin stimulated respiration which was depressed by Morphine. But there was no significant change of electrolyte. It is suggested that the Ginseng saponin act rather on metabolic process than neural excitatory mechanism in vitro.

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Localization of Divalent Cation-Binding Site in the Pore of a Small Conductance $Ca^{2+}$-activated $K^+$ Channel and Its Role in Determining Current-Voltage Relationship

  • Heun Soh;Shin, Na-Rae;Park, Chul-Seung
    • Proceedings of the Korean Biophysical Society Conference
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    • 2002.06b
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    • pp.33-33
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    • 2002
  • In our previous study (Soh and Park, 2001), we proposed that the inwardly rectifying current-voltage (I-V) relationship of small-conductance $Ca^{2+}$-activated $K^{+}$ channels (S $K_{Ca}$ channels) is the result of voltage-dependent blockade of $K^{+}$ currents by intracellular divalent cations. We expressed a cloned S $K_{Ca}$ channel, rSK2, in Xenopus oocytes and further characterized the nature of the divalent cation-binding site by electrophysiological means.(omitted)

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Cation Exchange Behavior of Molybdenum (Ⅵ) and Tungsten (Ⅵ) (양이온 교환 수지에 의한 몰리브덴 (Ⅵ)과 텅그스텐 (Ⅵ) 의 용리에 관하여)

  • Kee Won Cha
    • Journal of the Korean Chemical Society
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    • v.13 no.1
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    • pp.37-40
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    • 1969
  • The separation and species of $MoO_4^{--}$ and $WO_4^{--}$ at the various PH value have been studied by the method of cation exchange chromatography. Elution curves of $MoO_4^{--}$ and $WO_4^{--}$ have been made with a 5 cm column of the resin, $Dowe{\times}50W{\times}12$(100-200 mesh), using solutions of various PH value as eluent. Complete separation of $MoO_4^{--}$ and $WO_4^{--}$ was obtained in each PH of 10% EtOH. According to the evaluation of peak position and number of peaks of elution curves, it is likely to exist cationic species of $MoO_4^{--}$.

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