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http://dx.doi.org/10.4283/JKMS.2005.15.2.085

Mössbauer Analysis of Cations on Iron Oxyhydroxide Formation  

Oh, Sei-Jin (Department of Acoustics, JuSung College)
Kwon, Soon-Ju (Department of Materials Science and Engineering Pohang University of Science and Technology)
Abstract
Effect of different cations to the formation of iron oxyhydroxide was studied using $M\ddot{o}ssbauer$ spectroscopy, X-ray diffraction (XRD) and BET. Redox Potential and pH were measured for the determination of the internal reaction rate, as well. The phases of iron oxyhydroxide could not be the same with each other, due to the presence of different cations in solution. Although the oxyhydroxide compound was composed of the same phases, the fraction of each phase was different from each other. The internal reaction rate was varied by the substitution of cation. It could be a cause of the different phase and particle size of oxyhydroxide compound.
Keywords
Cation; Iron Oxyhydroxide; Internal Reaction Rate; Redox Potential; Mossbauer Spectroscopy;
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  • Reference
1 C. R. Shastry, J. J. Friel, and H. E. Townsend, ASTM STP 965 (Philadelphia, PA ASTM, 1988) p. 5
2 H. E. Townsend, and Z. C. Zoccola, ASTM 767 (Philadelphia, PA ASTM, 1988) p. 45
3 Sei J. Oh, Ph.D Thesis, Old Dominion University, Department of Physics (1997)
4 C. P. Dillon, Corrosion Control in the Chemical Process Industries (Materials Technology Institute of the Chemical Process Industries, Inc., 1994)
5 M. Yamashita, H. Miyuki, H. Nagano, and T. Misawa, Corro. Eng., 4, 43(1994)
6 T. Misawa, K. Asami, K. Hashimoto, and S. Shimodaira, Corr. Sci., 14, 279(1974)
7 I. Suzuki, and Y. Hisamatsu, J. Electrochem. Soc., 127(10), 2210(1980)   DOI
8 A. Nishikayta, Y. Yamashita, H. Katayama, T. Tsuru, A. Usami, K. Tanabe, and Mabuchi, Corr. Sci., 37, 2059(1995)   DOI   ScienceOn
9 M. Yamashita, and T. Misawa, Proc. 3rd NACE Am. Region Corr. Cong., Cancun Mexico (1998)
10 H. Miyuki, Zairyo-to-Kankyo, 47, 186(1998)   DOI
11 S. J. Oh, S.-J. Kwon, D. C. Cook, and H. E. Townsend, Hyp. Int. C4, 37(1999)
12 R. Balasubramanian, D. C. Cook, T. Perez, and J. Reyes, Hyp. Int. C4, 37(1999)
13 M. Yamashita, H. Nagano, T. Misawa, and H. E. Townsend, ISIJ Int., 38, 285(1998)   DOI
14 E. Jackson, Hydrometallurgical Extraction and Reclamation, (John Willey &Sons., New York, 1986) p. 145
15 M. Stratmann, K. Bohnenkamp, and T. Ramchandran, Corr. Sci., 27(9), 905(1987)   DOI   ScienceOn
16 H. Kihira, S. Ito, and T. Murata, Corr. Sci., 31, 383(1990)   DOI   ScienceOn