• Title/Summary/Keyword: Boiling Point

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Simultaneous analysis method of BTEX and TPH in soil (토양중 BTEX와 TPH의 동시분석법에 관한 연구)

  • 신호상;박치후
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.05a
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    • pp.3-8
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    • 2000
  • A simple and rapid simultaneous analysis method of BTEX and TPH in soil was developed. 5g of soil sample were mixed with sodium sulfate and then extracted with 10 mL of mixture of acetone and dichloromethane (1:1). Extraction was performed for 10 min in sonicator and analysis was with GC-FID. The detection limits of BTEX and TPH was 0.8 and 10 mg/kg, respectively. The analytical recoveries were >90% for all BTEX and TPH. Low boiling point fuels and high boiling point fuels are consistently reproduced within RSD 7%. The analysis results show very simple and rapid quantitation of BTEX and TPH in soil sample with low RSD.

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Weldability of Low Carbon Steel with Al Coating Condition by Nd:YAG Laser (저탄소강의 알루미늄 도금조건에 따른 Nd:YAG 레이저 용접성)

  • Kim, Jong-Do;Lee, Jung-Han;Kim, Sook-Hwan
    • Journal of Advanced Marine Engineering and Technology
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    • v.31 no.6
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    • pp.736-743
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    • 2007
  • Laser welding has the advantage of high welding speed and Provides low heat distortion Thus laser welding is a very attractive process for joining thin steel sheet and surface treated steel sheet. And the major item in market for surface treated steel sheet is zinc coated steel. However. the laser welding of zinc coated steel is very difficult because of its low boiling point. Compared with zinc, on the other hand, aluminum has a high boiling point. Thus, laser weldability of aluminized steel is better than that of zinc coated steel. Moreover aluminized steel sheet is a material with excellent heat resistance, thermal reflection and corrosion resistance. The results of laser weldability of the aluminized steel for the full penetration welding will be described in this paper We focused on the investigation of the phenomenons caused by coating condition and behavior of aluminum in weld.

A PRACTICAL METHOD FOR THE DISPOSAL OF RADIOACTIVE ORGANIC WASTE

  • Kim, Kil-Jeong;Shon, Jong-Sik;Ryu, Woo-Seog
    • Nuclear Engineering and Technology
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    • v.39 no.6
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    • pp.731-736
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    • 2007
  • Radioactive organic wastes containing acetone, alcohol, and particularly tributyl phosphate (TBP)/dodecane contaminated with uranium are extracted from the PUREX process and the decontamination of related equipment. An evaporation method that utilizes existing DU oxidation apparatuses and ventilation systems and a typical muffle furnace installed with an aspirating system are adopted. A separation method using phosphoric acid especially for the TBP/dodecane waste is also studied and evaluated. The results show that a simple evaporation process is utilizable for wastes containing acetone or alcohol with a lower boiling point. A modified muffle furnace is more appropriate to dispose directly of organic wastes having a higher boiling point, such as TBP/dodecane, without generating a condensed waste solution. It is recommended that, when the uranium concentration of TBP/dodecane waste is much higher than stipulated levels, separation technology should be applied to remove uranium from the mixture. Each type of solvent after separation can then be considered disposable below the regulatory limit in the modified furnace discussed in this study.

The Comparative Study on the Effects of Three kinds of Teaching Model (Deductive, Inductive and Analogical Teaching Models) in Boiling Point Elevation (끓는점 오름의 학습에서 세 가지 수업모형의 효과 비교 - 연역식, 귀납식, 비유를 사용한 수업모형)

  • Kim, Do-Wook
    • Journal of The Korean Association For Science Education
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    • v.12 no.1
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    • pp.35-46
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    • 1992
  • The purpose of this study was to investigate the most effective teaching model in the study of boiling point elevation. The teaching models were classified into three group-deductive, inductive and analogical teaching models. Learning materials, based on three teaching models respectively, were applied to 11th grade students, and the effect of teaching models were investigated and analyzed. The average achievement score(4.24) of the group treated with the analogical teaching model was higher than those(3.06 respectively) of each group treated with inductive or deductive teaching model(p<0.001). Most students answered that the analogical teaching model was helpful and interesting one for the comprehension of scientific concept.

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A Study of Upgrading Wax Oil Obtained from Pyrolysis of Mixed Plastic Waste with Film Type - The Influence of Catalyst Amount and Reaction Temperature (필름형 혼합폐플라스틱의 열분해로부터 얻은 왁스오일의 고급화연구 - 촉매 양과 반응온도의 영향 -)

  • Lee, Kyong-Hwan;Song, Kwang-Sup;Nam, Ki-Yun
    • New & Renewable Energy
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    • v.5 no.4
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    • pp.52-58
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    • 2009
  • Upgrading of pyrolysis wax oil using HZSM-5 catalyst has been conducted in a continuous fixed bed reactor at $450^{\circ}C$, 1hour, LHSV 3.5/h. The catalytic degradation was studied with a function of catalyst amount and reaction temperature. The raw pyrolysis wax oil shows relatively high boiling point distribution ranging from around $300^{\circ}C$ to $550^{\circ}C$, which has considerably higher boiling point distribution than that of commercial diesel. The catalytic degradation using HZSM-5 catalyst shows the high conversion of pyrolysis wax oil to light hydrocarbons. The liquid product obtained shows high gasoline range fraction as around 90% fraction and considerably high aromatic fraction in liquid product. Here, the experimental variable such as catalyst amount and reaction temperature was influenced on the product distribution.

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Effects of Bottom Inflow Area on Pool Boiling Heat Transfer in a Vertical Annulus (하부 유로단면적이 수직 환상공간 내부 풀비등열전달에 미치는 영향)

  • Kang, Myeong-Gie;Yoo, Joo-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.7 s.262
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    • pp.604-610
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    • 2007
  • To investigate effects of the inflow area on pool boiling heat transfer in a vertical annulus, the inflow area at its bottom has been changed from 0 to $1060.3mm^2$. For the test, a heated tube of 34 mm diameter and water at atmospheric pressure have been used. To elucidate effects of the inflow area on heat transfer results of the annulus are compared to the data of a single unrestricted tube. The change in the inflow area at the bottom of the annulus results in much variation in heat transfer coefficients. When the inflow area is $113.1mm^2$ the deterioration point of heat transfer coefficients gets moved up to the higher heat fluxes because of the convective flow at the bottom regions.

Study on Correlation of Droplet Flow Rate and Film Boiling Heat Transfer in Spray Cooling (액적 유량과 분무냉각 막비등 열전달의 상관관계에 관한 연구)

  • Yun, Seung-Min;Kim, Yeung-Chan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.4
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    • pp.335-340
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    • 2007
  • A new correlation between the Nusselt number based on modified heat transfer coefficient and Reynold number based on droplet-flow-rate was developed for the experimental data. The modified heat transfer coefficient was defined as ratio of wall heat flux to droplet subcooling. In the previous reports, the local heat flux of spray cooling in the film boiling region was experimentally investigated for the water spray region of $D_{max} = 0.0007{\sim}0.03m^3/(m^2s)$ . In the region near the stagnation point of spray flow, a new heat transfer correlation is recommended which shows good predictions for the water spray region of $D_x{\le}0.01m^3/(m^2s)$.

A Study on the Real Quality and Void Fraction of Subcooled Refrigerant Flow (과냉 비등류의 실제건도와 보이드율에 관한 연구)

  • Kim, J.H.;Kim, C.S.;Kim, K.K.;Oh, C.
    • Journal of Advanced Marine Engineering and Technology
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    • v.17 no.2
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    • pp.36-43
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    • 1993
  • Real quality and axial void fraction distribution of subcooled refrigerant flow is very important to predict the heat transfer rate and pressure drop in the design of refrigerating system. In the subcooled boiling region, the liquid bulk temperature is still below the corresponding saturation temperature. But beyond the net vapor generation point, bubble detachment is occured actively from the vapor layer formed on the wall. A reliable method to predict the vapor fraction from the liquid bulk temperature is suggested in this paper. And also the actual quality of the subcooled R-113 flow is calculated in the range of 261-1239kg/$m^2$s mass velocity and 10-30K subcooling.

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Using Largest Lyapunov Exponent to Confirm the Intrinsic Stability of Boiling Water Reactors

  • Gavilan-Moreno, Carlos J.;Espinosa-Paredes, Gilberto
    • Nuclear Engineering and Technology
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    • v.48 no.2
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    • pp.434-447
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    • 2016
  • The aim of this paper is the study of instability state of boiling water reactors with a method based in largest Lyapunov exponents (LLEs). Detecting the presence of chaos in a dynamical system is an important problem that is solved by measuring the LLE. Lyapunov exponents quantify the exponential divergence of initially close state-space trajectories and estimate the amount of chaos in a system. This method was applied to a set of signals from several nuclear power plant (NPP) reactors under commercial operating conditions that experienced instabilities events, apparently each of a different nature. Laguna Verde and Forsmark NPPs with in-phase instabilities, and Cofrentes NPP with out-of-phases instability. This study presents the results of intrinsic instability in the boiling water reactors of three NPPs. In the analyzed cases the limit cycle was not reached, which implies that the point of equilibrium exerts influence and attraction on system evolution.

Comparison of spray characteristics for ammonia, ethanol, n-decane by using numerical simulation (시뮬레이션을 이용한 암모니아, 에탄올, 노말데케인 분무 특성 비교)

  • Lee, Jaejin;Yeom, Eunseop
    • Journal of the Korean Society of Visualization
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    • v.20 no.2
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    • pp.38-44
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    • 2022
  • Due to increasingly strict emission regulations for carbon-based fuels in the shipping industry, there is a significant motivation to investigate the alternative fuel. Ammonia is one of the attractive alternative fuels as a carbon-free fuel. Since ammonia has different properties such as high vapor pressure and low boiling point compared to conventional fuels, further research into ammonia spray behavior is important. In this work, the spray characteristics of ammonia and other fluids (ethanol, n-decane) were compared by using numerical simulation. The results show that the spray characteristics of ammonia differs from those of the others due to the occurrence of flash boiling. The narrow-dispersed spray with accelerated velocity at the center have been observed for ammonia. It is also found that droplets of ammonia achieve smaller diameter with more uniform distribution, leading to better atomization behavior compared to the others.