• Title/Summary/Keyword: Blue emission

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Efficient white organic light-emitting diodes with a doped hole-blocking layer

  • Ahn, Young-Joo;Kang, Gi-Wook;Lee, Nam-Heon;Lee, Mun-Jae;Kang, Hee-Young;Lee, Chang-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.780-783
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    • 2002
  • We report very efficient white OLEDs consisting of a blue-emitting 4,4'bis[N-(1-napthyl)-N-phenyl-amino]-biphenyl (${\alpha}$-NPD), a hole-blocking layer of 2,9-dimethyl-4, 7-diphenyl-1, 10-phenanthroline (BCP) doped with red fluorescent dye of 4-dicyanomethylene-2-methyl-6-[2-(2,3,6,7-tetrahydro- 1H, 5H-benzo[i,j]quinolizin-8-yl) vinyl]-4H-pyran) (DCM2), and green-emitting tris(8-hydroxyquinoline) aluminum ($Alq_3$). The device with the structure of ITO/${\alpha}$-NPD (50 nm)/BCP:DCM2 (0.8 %, 4 nm)/$Alq_3$ (50 nm)/LiF (0.5 nm)/Al shows a white emission with the CIE coordinates (0.329, 0.333). The maximum luminance of 20,800 cd/$m^2$ is obtained at 15.4 V. The power efficiency is 2.6lm/W and the external quantum efficiency is 2.1 % at a luminance of 100 cd/$m^2$ at the bias voltage of 6 V.

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Photocatalytic Activity of Electrospun PAN/TiO2 Nanofibers in Dye Photodecomposition

  • Ji, Byung Chul;Bae, Sang Su;Rabbani, Mohammad Mahbub;Yeum, Jeong Hyun
    • Textile Coloration and Finishing
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    • v.25 no.2
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    • pp.94-101
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    • 2013
  • Poly(acrylonitrile) (PAN) nanofibers containing different amounts of titanium dioxide ($TiO_2$) have been prepared by electrospinning technique. Photocatalytic activity of these electrospun PAN/$TiO_2$ nanofibers and the effect of $TiO_2$ content on the photocatalytic efficiency of PAN/$TiO_2$ nanofibers have been evaluated by monitoring the photodecomposition of fluorescein dye, rhodamine B and methylene blue under UV irradiation with respect to irradiation time. Moreover, the effect of hydrogen peroxide ($H_2O_2$) on the photocatalytic behavior of PAN/$TiO_2$ nanofibers has also been investigated. The results showed that PAN/$TiO_2$ nanofibers are effective photocatalyst and their photocatalytic efficiency increases with the increase of $TiO_2$ content in the PAN/$TiO_2$ nanofibers. It is also observed that the presence of $H_2O_2$ significantly enhances the photocatalytic ability of PAN/$TiO_2$ nanofibers. The morphology and the photocatalytic behavior of the PAN/$TiO_2$ nanofibers containing different amounts of $TiO_2$ nanoparticles have been investigated by field-emission scanning electron microscopy (FE-SEM) and UV/Visible spectroscopy, respectively.

The Evolution of the Mass-Metallicity Relation at 0.20 < z < 0.35

  • Chung, Jiwon;Rey, Soo-Chang;Sung, Eon-Chang
    • Journal of Astronomy and Space Sciences
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    • v.30 no.1
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    • pp.59-67
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    • 2013
  • We present a spectroscopic study of 343 blue compact galaxies (BCGs) at 0.20 < z < 0.35 from the Sloan Digital Sky Survey (SDSS) DR7 data. We derive gas phase oxygen abundance using the empirical and direct method. Stellar masses of galaxies are derived from the STARLIGHT code. We also derive star formation rates of galaxies based on $H{\alpha}$ emission line from the SDSS as well as far-ultraviolet (FUV) flux from the Galaxy Evolution Explorer GR6 data. Evolution of the luminosity-metallicity and mass-metallicity (M-Z) relations with redshift is observed. At a given luminosity and mass, galaxies at higher redshifts appear to be biased to low metallicities relative to the lower redshift counterparts. Furthermore, low mass galaxies show higher specific star formation rates (SSFRs) than more massive ones and galaxies at higher redshifts are biased to higher SSFRs compared to the lower redshift sample. By visual inspection of the SDSS images, we classify galaxy morphology into disturbed or undisturbed. In the M-Z relation, we find a hint that morphologically disturbed BCGs appear to exhibit low metallicities and high SSFRs compared to undisturbed counterparts. We suggest that our results support downsizing galaxy formation scenario and star formation histories of BCGs are closely related with their morphologies.

Effects of hydration structure on the femtosecond white light-induced phase transition to crystalline silicon nanocrystal having ultrabright narrowed luminescence

  • Choi, Kyong-Hoon;Wang, Kang-Kyun;Ha, Jeong-Hyon;Kim, Yong-Rok
    • Rapid Communication in Photoscience
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    • v.4 no.3
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    • pp.54-58
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    • 2015
  • Under the condition of femtosecond impulsive nonlinear optical irradiation, the bright and narrowed blue emission of silicon nanocrystal was observed. This synthetic method produced very small (~ 4 nm) oxide-capped silicon nanocrystal having probably ultra small emitting core (~ 1 nm) inferred from luminescence. By controlling the stirring condition, very high efficiencies of luminescence ( 4 fold higher) were obtained compared with the other conventional femtosecond laser fragmentation methods, which was attributed to the differences in hydration shell structure during the femtosecond laser induced irreversible phase transition reaction. When we properly adjusted the irradiation times of the white light continuum and stirring condition, very homogeneous luminescent silicon nanocrystal bands having relatively sharp lineshape were obtained, which can be attributable to the luminescent core site isolated and free from the surface defects.

Properties of Merging Galaxies in the Nearby Universe

  • Park, Jong-Han;Ann, Hong-Bae;Kang, Hye-Sung
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.2
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    • pp.70.1-70.1
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    • 2011
  • We have investigated properties of merging galaxies in the nearby universe, using Sloan Digital Sky Survey (SDSS) DR7. We first constructed two galaxy samples according to redshift range: Sample 1 for 0 ${\leq}$ z ${\leq}$ 0.025 and Sample 2 for 0.09 ${\leq}$ z ${\leq}$ 0.1. We then identified 118 and 184 merging galaxies among the galaxies in the Sample 1 and 2, respectively, and classified them into different merging types and stages by visual inspection of galaxy images. In the Sample 1, there are more wet mergers than dry mergers, while most merging galaxies in the Sample 2 are dry mergers. The color-magnitude diagram of the merging galaxies in our samples is comparable to that of normal galaxies. Dry mergers tend to locate in the red sequence, while wet and mixed mergers reside mostly in the blue cloud. Unlike some previous studies, we did not find a clear trend that the merger rate increases at higher redshift. However, it is difficult to make a direct comparison of the merger rate found in different studies, because it depends on the number of observed galaxies and criteria for merger classification. From the ratios of emission lines, we infer that the faction of merging galaxies with AGNs is higher in wet mergers than in other types.

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Highly Efficient Three Wavelength WOLEDs by Controlling of Electron-Transfer

  • Park, Ho-Cheol;Park, Jong-Wook;Oh, Seong-Geu
    • Bulletin of the Korean Chemical Society
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    • v.30 no.10
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    • pp.2299-2302
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    • 2009
  • By controlling the number of electrons transferred to the emitting layer, highly efficient three-wavelength WOLEDs were fabricated. Such WOLEDs are different from those made using simple stacking of RGB emitting layers in that the movement distribution of electrons transferred to emitting layer could be adjusted using the difference in LUMO energy level and that lights of all 3 wavelengths could be emitted through appropriate arrangement of RGB emitting layers. WOLED device with the structure of m-MTDTA (40 nm)/NPB (10 nm)/ Coumarin6 doped $Alq_3$ (3%) (8 nm)/ Rubrene doped NPB (5%) (15 nm)/NPB (2 nm)/ DPVBi (20 nm)/$Alq_3$ (20 nm)/LiF (1 nm)/Al (200 nm) showed high luminance efficiency of 8.9 cd/A and color purity of (0.31, 0.40). In addition, WOLED device with the thickness of non-doped NPB layer increased from 2 nm to 3 nm to increase blue light emission showed a luminance efficiency of 7.6 cd/A and color purity of (0.28, 0.36).

Direction of Intercalation of a bis-Ru(II) Complex to DNA Probed by a Minor Groove Binding Molecule 4',6-Diamidino-2-phenylindole

  • Jang, Yoon Jung;Kim, Raeyeong;Chitrapriya, Nataraj;Han, Sung Wook;Kim, Seog K.;Bae, Inho
    • Bulletin of the Korean Chemical Society
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    • v.34 no.10
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    • pp.2895-2899
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    • 2013
  • Direction of intercalation to DNA of the planar dipyrido[3,2-a:2',3'-c]phenazine ligands (dppz) of a bis-Ru(II) complex namely, $[Ru(1,10-phenanthroline)_2dipyrido[3,2-a:2^{\prime},3^{\prime}-c]phenazine]^{2+}$ linkered by a 1,3-bis(4-pyridyl)propane, was investigated by probing the behavior of 4',6-diamidino-2-phenylindole (DAPI) that bound deep in the minor groove. Bis-intercalation of DPPZ resulted in a little blue shift and hyperchromism in DAPI absorption band, and a large decrease in DAPI fluorescence intensity which accompined by an increase in the dppz emission intensity. Diminishing the intenisty of the positive induced circular dichroism (CD) and linear dichroism (LD) were also observed. These spectral changes indicated that insertion of dppz ligand caused the change of the binding mode of DAPI, which probably moved to the exterior of DNA from the minor groove and interacted with the phospghate groups of DNA by electrostatic interaction. At the surface of DNA, DAPI binds at the phosphate groups of DNA by electrostatic attraction. Consequently, this observation indicated that the dppz ligand intercalated from the minor groove.

Optoelectronics Properties of In0.27Ga0.73N/GaN Multi-Quantum-Well Structure (In0.27Ga0.73N/GaN 다중 양자우물 구조에 대한 광전기적 특성)

  • Park, Hun-Bo;Bae, In-Ho;Kim, Ki-Hong
    • Korean Journal of Materials Research
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    • v.17 no.9
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    • pp.489-492
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    • 2007
  • Temperature and injection current dependence of elctroluminescence(EL) spectral intensity of the $In_{0.27}Ga_{0.73}N/GaN$ multi-quantum-well(MQW) have been studied over a wide temperature and as a function of injection current level. EL peaks also show significant broadening into higher photon energy region with the increase of injection current. This is explained by the band-filling effect. When temperature is slightly increased to 300 from 15 K, the EL emission peak showed red-blue-red shift. It can be explained by the carrier localization by potential fluctuation of multiple quantum well and band-gap shrinkage as temperature increase. It is found that a temperature-dependent variation pattern of the EL efficiency under very low and high injection currents show a drastic difference. This unique EL efficiency variation pattern with temperature and current is explained field effects due to the driving forward bias in presence of internal(piezo and spontaneous polarization) fields.

Combustion Characteristic and Stability of Flat Premixed Ceramic Burner with Different Porous Baffle Plates (평판 예혼합 세라믹 버너의 분포판 변화에 따른 연소화염특성과 안정성 분석)

  • Lee, Jae-Young;Lee, Pil-Hyong;Park, Chang-Soo;Park, Bong-Il;Hwang, Sang-Soon
    • Journal of the Korean Society of Combustion
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    • v.14 no.4
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    • pp.7-16
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    • 2009
  • Porous metal plates (Metal fiber, muti-hole metal plate) using mainly in surface burner are known to have a corrosion and durability problem under high temperature condition. In this study, premixed flat flame with perforated ceramic tile of more durable cordierite material was examined with respect to combustion stability and emission. The flat premixed ceramic burner consists of perforated ceramic tile and various type of baffle plates to form stable surface flame. The results show that most stable flat flame is generated using baffle plate with open ratio of 0.193. In downward flat flame mode which is widely used in condensing boiler, CO is measured below 50ppm from equivalence ratio 0.755 to 0.765 and $NO_X$ is measured below 12ppm from equivalence ratio 0.75 to 0.79. It is also found that the range of blue flame in flame stability curve becomes wider with increasing heat capacity.

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Preparation of Red Perylene Fluoroionophore Containing Calix[4]azacrown Ether and Their Ionophoric Properties

  • Jeon, Young-Min;Lim, Tae-Ho;Kim, Jong-Gyu;Kim, Jong-Seung;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
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    • v.28 no.5
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    • pp.816-820
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    • 2007
  • Novel new red-light emitting perylene fluoroionophore N,N'-dipropyl-1,7-bis(calix[4]azacrown-5-crown-5)- 3,4,9,10-perylene tetracarboxy diimide (3) was prepared by reacting N,N'-dipropyl-1,7-dibromo-3,4,9,10- perylene tetracarboxy diimide (1) with calix[4]azacrown-5-crown-5. Also the alternating copolymer (4) with similar repeating unit was prepared reacting by calix[4]bisazacrown-5 with 1. Metal ion binding by 3 and 4 leads to a blue-shift of absorption band and emission spectra. When ionophoric characteristics were investigated by binding alkali, alkali earth metal and various metal ions, polymeric ionophores displayed large fluorescence decreasing effects with K+, Ag+ and Ba2+, which was rationalized by photo-induced charge transfer (PCT).