• Title/Summary/Keyword: Binary properties

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Synthesis and Microstructural Characterization of Mechanically Milled $(Ti_{52}Al_{48})_{100-x}$-xB (x=0,0.5,2,5) Alloys (기계적 분쇄화법으로 제조된 $(Ti_{52}Al_{48})_{100-x}$-xB(x=0,0.5,2,5) 합금분말의 제조 및 미세조직 특성)

  • 표성규
    • Journal of Powder Materials
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    • v.5 no.2
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    • pp.98-110
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    • 1998
  • $Ti_{52}Al_{48}$ and $(Ti_{52}Al_{48})_{100-x}B_x(x=0.5, 2, 5)$ alloys have been Produced by mechanical milling in an attritor mill using prealloyed powders. Microstructure of binary $Ti_{52}Al_{48}$ powders consists of grains of hexagonal phase whose structure is very close to $Ti_2Al$. $(Ti_{52}Al_{48})_{95}B_5$ powders contains TiB2 in addition to matrix grains of hexagonal phase. The grain sizes in the as-milled powders of both alloys are nanocrystalline. The mechanically alloyed powders were consolidated by vacuum hot pressing (VHP) at 100$0^{\circ}C$ for 2 hours, resulting in a material which is fully dense. Microstructure of consolidated binary alloy consists of $\gamma$-TiAl phase with dispersions of $Ti_2AlN$ and $A1_2O_3$ phases located along the grain boundaries. Binary alloy shows a significant coarsening in grain and dispersoid sizes. On the other hand, microstructure of B containing alloy consists of $\gamma$-TiAl grains with fine dispersions of $TiB_2$ within the grains and shows the minimal coarsening during annealing. The vacuum hot pressed billets were subjected to various heat treatments, and the mechanical properties were measured by compression testing at room temperature. Mechanically alloyed materials show much better combinations of strength and fracture strain compared with the ingot-cast TiAl, indicating the effectiveness of mechanical alloying in improving the mechanical properties.

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Effect of Additive Powder on Microstructural Evolutions and Mechanical Properties of the Wide-gap Brazed Region in IN738 superalloy (초내열합금 wide-gap 브레이징부의 미세조직 및 기계적 성질 변화에 미치는 첨가금속분말의 영향)

  • Kim Y. H.;Kwun S. I.;Byeon J. W.;Lee W. S.
    • Korean Journal of Materials Research
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    • v.15 no.6
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    • pp.399-407
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    • 2005
  • The effect of IN738 additive powder on microstructure and mechanical properties of the wide-gap region brazed with BNi-3 filler metal powder was investigated. The wide-gap brazing was conducted in a vacuum of $2\times10^{-5}torr\;at\;1200^{\circ}C$ with various powder mixing ratios of additive to filler powders. The microstructures of the wide-gap brazed region were analyzed by SEM and AES. The region brazed with only BNi-3 filler metal powder had a microstructure consisted of proeutectic, binary eutectic and ternary eutectic structure, while that brazed with a mixture of IN738 additive powder and BNi-3 filler metal powder had a microstructure consisted of IN738 additive powder, binary eutectic of $Ni_3B-Ni$ solid solution and (Cr, W)B. The fracture strength of the wide-gap brazed region was about 680 MPa regardless of the additive powder mixing ratios. Cracks were initiated at the (Cr, W)B and binary eutectic of $Ni_3B-Ni$ solid solution, and propagated through them in the wide-gap brazed region, which lowered the fracture strength of the region.

Analysis of Cross-correlation Frequency between Non-linear Binary Sequences Family with 5-Valued Cross-Correlation Functions (5-값 상호상관관계를 갖는 비선형 이진수열군의 상호상관관계 빈도 분석)

  • Choi, Un-Sook;Cho, Sung-Jin
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.17 no.12
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    • pp.2875-2882
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    • 2013
  • The design of PN(Pseudo Noise) sequences with good cross-correlation properties is important for many research areas in communication systems. Also analyses of cross-correlation frequency between designed sequences have been researched. In this paper we analyze of cross-correlation distribution and properties of non-linear binary sequences family $S^r=\{Tr^m_1\{[Tr^n_m(a{\alpha}^t+{\alpha}^{dt}]^r\}{\mid}a{\in}GF(2^m),0{\leq}t < 2^n-1\}$, where $gcd(r,2^m-1)=1$ with 5-valued cross-correlation.

Structure and Thermal Properties of a Ternary Al-Cr-Si Quenching Ribbon Manufactured by Single Roll Method (단일 롤 방법으로 제작한 3원계 Al-Cr-Si 급냉리본의 구조 및 열 특성)

  • Han, Chang-Suk;Kim, Ki-Woong;Kim, Woo-Suk
    • Korean Journal of Materials Research
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    • v.31 no.5
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    • pp.296-300
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    • 2021
  • Al-Cr-Si ternary quench ribbons are fabricated using a single roll method and investigated for their structural and thermal properties. In particular, the sinterability is examined by pulse current sintering to obtain the following results. The Al74Cr20Si6 composition becomes a quasicrystalline single phase; by reducing the amount of Cr, it becomes a two-phase mixed structure of Al phase and quasicrystalline phase. As a result of sintering of Al74Cr20Si6, Al77Cr13Si10 and Al90Cr6Si4 compositions, the sintering density is increased with the large amount of Al phase; the sintering density is the highest in Al90Cr6Si4 composition. In addition, as a result of investigating the effects of sintering temperature and pressurization on the sintered density of Al90Cr6Si4, a sintered compact of 99% or more at 513 K and 500 MPa is produced. In particular, since the Al-Cr-Si ternary crystal is more thermally stable than the Al-Cr binary quaternary crystal, it is possible to increase the sintering temperature by about 100 K. Therefore, using an alloy of Al90Cr6Si4 composition, a sintered compact having a sintered density of 99 % or more at 613 K and 250 MPa can be manufactured. It is possible to increase the sintering temperature by using the alloy system as a ternary system. As a result, it is possible to produce a sintered body with higher density than that possible using the binary system, and at half the pressure compared with the conventional Al-Cr binary system.

Prediction of Forced Convective Boiling Heat Transfer Coefficient of Pure Refrigerants and Binary Refrigerant Mixtures Inside a Horizontal Tube

  • Kim, Min-Soo;Hong, Eul-Cheong;Shin, Jee-Young;Kyungdoug Min;Ro, Sung-Tack
    • Journal of Mechanical Science and Technology
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    • v.17 no.6
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    • pp.935-944
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    • 2003
  • Forced convective boiling heat transfer coefficients were predicted for an annular flow inside a horizontal tube for pure refrigerants and nonazeotropic binary refrigerant mixtures. The heat transfer coefficients were calculated based on the turbulent temperature profile in liquid film and vapor core considering the composition difference in vapor and liquid phases, and the nonlinearity in mixing rules for the calculation of mixture properties. The heat transfer coefficients of pure refrigerants were estimated within a standard deviation of 14% compared with available experimental data. For nonazeotropic binary refrigerant mixtures, prediction of the heat transfer coefficients was made with a standard deviation of 18%. The heat transfer coefficients of refrigerant mixtures were lower than linearly interpolated values calculated from the heat transfer coefficients of pure refrigerants. This degradation was represented by several factors such as the difference between the liquid and the overall compositions, the conductivity ratio and the viscosity ratio of both components in refrigerant mixtures. The temperature change due to the concentration gradient was a major factor for the heat transfer degradation and the mass flux itself at the interface had a minor effect.

Measurement of Flash Point for Binary Mixtures of Toluene, Methylcyclohexane, n-heptane and Ethylbenzene at 101.3 kPa (Toluene, Methylcyclohexane, n-heptane 그리고 Ethylbenzene 이성분 혼합계에 대한 101.3 kPa에서의 인화점 측정)

  • Hwang, In Chan;In, Se Jin
    • Fire Science and Engineering
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    • v.31 no.3
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    • pp.19-24
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    • 2017
  • Flammable substances are used in laboratories and industrial process. The flash point (FP) is one of the most important physical properties used to determine the potential for characterizing the fire and explosion hazard of liquids. The FP data at 101.3 kPa were measured for the binary systems {toluene+ethylbenzene}, {methlycyclohenxane+ethylbenzene} and {n-heptane+ ethylbenzene}. The experiments were performed according to the standard test method (ASTM D 3278) using a SETA closed cup flash point tester. The measured FPs were compared with the values predicted using the following activity coefficient models: Wilson, Non-Random Two Liquid (NRTL), and UNIversal QUAsiChemical (UNIQUAC). The average absolute deviation between the predicted and measured lower FP was less than 1.74 K.

Cascaded Propagation and Reduction Techniques for Fault Binary Decision Diagram in Single-event Transient Analysis

  • Park, Jong Kang;Kim, Myoungha;Kim, Jong Tae
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.17 no.1
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    • pp.65-78
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    • 2017
  • Single Event Transient has a critical impact on highly integrated logic circuits which are currently common in various commercial and consumer electronic devices. Reliability against the soft and intermittent faults will become a key metric to evaluate such complex system on chip designs. Our previous work analyzing soft errors was focused on parallelizing and optimizing error propagation procedures for individual transient faults on logic and sequential cells. In this paper, we present a new propagation technique where a fault binary decision diagram (BDD) continues to merge every new fault generated from the subsequent logic gate traversal. BDD-based transient fault analysis has been known to provide the most accurate results that consider both electrical and logical properties for the given design. However, it suffers from a limitation in storing and handling BDDs that can be increased in size and operations by the exponential order. On the other hand, the proposed method requires only a visit to each logic gate traversal and unnecessary BDDs can be removed or reduced. This results in an approximately 20-200 fold speed increase while the existing parallelized procedure is only 3-4 times faster than the baseline algorithm.

A Molecular Dynamics Study of Thermophysical Properties and Stability of Nanoscale Liquid Thread (분자동역학 해석을 이용한 액체 극미세사의 열역학적 물성과 안정성 연구)

  • Kim, Byeong-Geun;Choi, Young-Ki;Kwon, Oh-Myoung;Park, Seung-Ho;Lee, Joon-Sik
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.1366-1371
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    • 2003
  • Molecular dynamics (MD) simulations are conducted to investigate the thermophysical characteristics and the stability of liquid threads for various conditions. A cylindrical thread in the simulation domain is made of Lennard-Jones molecules. The surface tension of liquid threads can be determined from local densities, local normal and transverse components of the pressure force. In order to understand the effects of thread radii on surface tensions, the Tolman equation is modified on the basis of the cylindrical coordinates for prediction of surface tensions. Surface tensions calculated from the MD simulation agree with the prediction from the modified Tolman equation. In addition, surface tensions decrease linearly with increasing system temperature. For a binary system, the surface tension decreased linearly compared to that for a pure system with increasing binary ratio of solute molecules which have relatively large value of the affinity coefficient. For a fixed binary ratio, the surface tension increased slightly with the affinity coefficient and the maximum value appear around where the affinity coefficient is 1.5 and decreased rapidly for upper value of 1.5. In addition, the critical wavelengths of perturbations are proven to be directly proportional to the equimolar dividing radii of the liquid threads.

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The Calculation and Measurement of Flash Point for Water+1-Propanol and Water+2-Propanol Using Closed Cup Aparatus (밀폐식 장치를 사용한 Water+1-Propanol 과 Water+2-Propanol의 인화점 측정과 계산)

  • Ha, Dong-Myeong;Lee, Sungjin
    • Journal of Energy Engineering
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    • v.25 no.4
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    • pp.190-197
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    • 2016
  • Flash point is the one of the important properties for the safe handling of inflammable liquid solution. In this paper, flash points of binary liquid solutions, water+1-propanol and water+2-propanol, were been measured by using Seta flash closed cup aparatus. Flash point was estimated using regression analysis method. Flash points were also estimated by the method based on Raoul's law and the method optimizing the binary parameters of van Laar equation. Experimental results were compared with the calculated results. The regression analysis method is able to estimate the flash point fairly well for water+1-propanol and water+2-propanol mixture.

Binary Metal Oxide ($IrO_2-RuO_2$) pH Sensor Prepared by Sol-gel Method (Sol-gel 법을 이용한 이성분 금속산화물 ($IrO_2-RuO_2$) pH 센서)

  • Lee, Jeong-Ran;Oh, Se-Lim;Han, Won-Sik;Hong, Tae-Kee
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.2
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    • pp.190-196
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    • 2014
  • The sol-gel method was used to prepare binary metal oxide ($IrO_2-RuO_2$) pH sensor. The electrodes that mole percent compositions (mol%) of $IrO_2$ and RuO2 were 70:30 and 30:70 were selected. The characterizations of Nernstian response over pH range, response rate, interference on alkaline metals and reproducibility were investigated. Also the electroanalytical properties of these electrodes were evaluated in comparison with a commercial glass pH electrode. The composition of $IrO_2:RuO_2$ 70:30 mol% was chosen as better electrode formulation. The electrode was not susceptible to the action of interfering ions such as $Li^+$, $Na^+$ and $K^+$.