Browse > Article
http://dx.doi.org/10.5855/ENERGY.2016.25.4.190

The Calculation and Measurement of Flash Point for Water+1-Propanol and Water+2-Propanol Using Closed Cup Aparatus  

Ha, Dong-Myeong (Department of Occupational Health and Safety Engineering, Semyung University)
Lee, Sungjin (Department of Clinical Laboratory Science, Semyung University)
Publication Information
Abstract
Flash point is the one of the important properties for the safe handling of inflammable liquid solution. In this paper, flash points of binary liquid solutions, water+1-propanol and water+2-propanol, were been measured by using Seta flash closed cup aparatus. Flash point was estimated using regression analysis method. Flash points were also estimated by the method based on Raoul's law and the method optimizing the binary parameters of van Laar equation. Experimental results were compared with the calculated results. The regression analysis method is able to estimate the flash point fairly well for water+1-propanol and water+2-propanol mixture.
Keywords
Flash point; Seta flash closed cup aparatus; binary liquid mixtures; nonflammable; regression analysis;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 Caoire, L.. et al., 2006, Estimation of Closed Cup Flash Points of Combustible Solvent Blends, J. Phy. Chem. Ref. Data, Vol. 35, No. 1, pp. 9-14   DOI
2 Taha, M., 2016, Designing New Mass-Separating Agents Based on Piperazine-Containing Good's Buffers for Separation of Propanols and Water Azeotropic Mixtures Using COSMO-RS method, Fluid Phase Equilibria, Vol. 425, pp. 40-46   DOI
3 Ha, D. M. and Lee, S. J., 2013, The Measurement of the Lower Flash Points for Binary Mixtures (in Korean), J. of the Korean Society of Safety, Vol. 28, No. 1, pp. 35-39   DOI
4 In 2011 Annual Book of ASTM Standards ; ASTM International, 2011, Standard Test Methods for Flash Point of Liquids by Small Scale Closed-Cup Apparatus(ASTM D3278), West Conshohocken, PA
5 Chatelier, H. L., 1891, Estimation of Firedamp by Flammability Limits, Ann. Minmes, Vol. 19, No. 8, pp. 388-395
6 Gmehing, J.. et al., 1980, Vapor-Liquid Equilibrium Data Collection, Vol. 1, Part1-Part7, DECHEMA
7 Kuester, J. L. and Mixe, J .H., 1973, Optimization Techniques with Fortran, McGraw-Hill, New York,
8 Lim, J.. et al., 2013, Solubility of Triclocarban in Pure Alkanols at Different Temperatures, Korean J. Chem. Eng., Vol. 30, No. 1, pp. 181-186   DOI
9 Phoon, L.. et al., 2014, A Review of Flash Point Prediction Models for Flammable Liquid Mixtures, Ind. Eng. Chem. Res., Vol. 53, pp. 12523-12565
10 Kim, S. Y.. et al., 2006, Prediction of Flash Point of Binary Systems by Using Multivariate Statistical Analysis (in Korean), KIGAS, Vol. 10, No. 4, pp. 29-33
11 Lance, R. C.. et al., 1979, Measurement of Flash Points : Apparatus, Methodology, Applications, J. of Hazardous Materials, Vol. 3, pp. 107-119   DOI
12 Affens, W. A. and Mclaren, G. W., 1972, Flammability Properties of Hydrocarbon Solutions in Air, J. of Chem. Ind. Eng. Chem., Vol. 17, No. 4, pp. 482-488
13 White, D.. et al., 1997, Flame Spread on Aviation Fuels, Fire Safety Journal, Vol. 28, pp. 1-31   DOI
14 Hanley, B., 1998, A Model for the Calculation and the Verification of Closed Cup Flash Points for Multicomponent Mixtures, Process Saf. Prog., Vol. 17, No. 2, pp. 86-97   DOI
15 Poling, B. E.. et al., 2001, The Properties of Gases and Liquids, 5th Ed., McGraw-Hill, New York
16 Liaw, H.. et al., 2002, A Mathematical Model for Predicting the Flash Point of Binary Solutions, J. of Loss Prevention in the Process Industries, Vol. 15, pp. 429-438   DOI
17 Ha, D. M. and Lee, S. J., 2006, The Estimation of Lower Flash Point for n-Pentanol+n-Propionic Acid and n-Pentanol+n-Butyric Acid Systems Using Optimization Method (in Korean), KIGAS, Vol. 11, No. 4, pp. 73-78