• 한국결정성장학회지
• /
• 제33권1호
• /
• pp.15-21
• /
• 2023

산화아연 분말을 제조하기 위해 3종류의 나트륨계 알칼리 침전제인 수산화나트륨, 탄산나트륨, 수산화나트륨/탄산수소나트륨을 이용하여 반응에 따른 열역학적 고찰과 아연 침전생성물로부터 산화아연 분말 제조 공정의 차이점을 비교하였다. 나트륨계 알칼리 침전제와의 반응으로 생성된 아연 침전생성물은 각각 히드록시염화아연(Zn₅(OH)₈Cl₂·H₂O)과 탄산아연수산화물 (Zn₅(OH)₆(CO₃)₂·H₂O)임을 XRD를 통해 확인하였다. 나트륨계 알칼리 침전제에 따라 800℃에서 열처리하여 생성된 산화아연 입자 크기를 비교하였다. 혼합된 수산화나트륨 및 탄산수소나트륨의 알칼리 침전제 반응으로 보다 균일한 산화아연 입자를 제조할 수 있었다.

• 한국재료학회지
• /
• 제21권8호
• /
• pp.444-449
• /
• 2011

Nano-sized $Y_2O_3$ powders were prepared via a sol-gel method starting with $Y(NO_3)_3{\cdot}6H_2O$ (Yttrium(III) nitrate hexahydrate) and water with ethanol as a cosolvent. $Y_2O_3$ is an important rare earth oxide and has been considered for use in nuclear applications, such as ceramic materials, due to its excellent optical and refractory characteristics. It has been used as a chemically stable substrate, a crucible material for melting reactive metals, and a nozzle material for jet casting molten rare earth-iron magnetic alloys. Oxalic acid ($C_2H_2O_4$) has been adopted as a chelating agent in order to control the rate of hydrolysis and polycondensation, and ammonia was added in order to adjust the base condition. The synthesized $Y_2O_3$ powder was characterized using TG/DTA, XRD, FE-SEM, BET and Impedance Analyzer analyses. The powder changed its properties in accordance with the pH conditions of the catalyst. As the pH increases according to the FE-SEM, the grain grew and it showed that the pore size decreased while confirming the effect of the grain size. The nano-material $Y_2O_3$ powders demonstrated that the surface area was improved with the addition of oxalic acid with ammonium hydroxide.

• Bulletin of the Korean Chemical Society
• /
• 제33권8호
• /
• pp.2523-2528
• /
• 2012

Green phosphors $(Zn_{1-a-b}M_aM^{\prime}_b)_xGa_yS_{x+3y/2}:Eu^{2+}$ (M, M' = alkali earth ions) with x = 2 and y = 2-5 were prepared, starting from ZnO, MgO, $SrCO_3$, $Ga_2O_3$, $Eu_2O_3$, and S with a flux $NH_4F$ using a conventional solidstate reaction. A phosphor with the composition of $(Zn_{0.6}Sr_{0.3}Mg_{0.1})_2Ga_2S_5:Eu^{2+}$ produced the strongest luminescence at a 460-nm excitation. The observed XRD patterns indicated that the optimized phosphor consisted of two components: zinc thiogallate and zinc sulfide. The characteristic green luminescence of the $ZnS:Eu^{2+}$ component on excitation at 460 nm was attributed to the donor-acceptor ($D_{ZnGa_2S_4}-A_{ZnS}$) recombination in the hybrid boundary. The optimized green phosphor converted 17.9% of the absorbed blue light into luminescence. For the fabrication of light-emitting diode (LED), the optimized phosphor was coated with MgO using magnesium nitrate to overcome their weakness against moisture. The MgO-coated green phosphor was fabricated with a blue GaN LED, and the chromaticity index of the phosphor-cast LED (pc-LED) was investigated as a function of the wt % of the optimized phosphor. White LEDs were fabricated by pasting the optimized green (G) and the red (R) phosphors, and the commercial yellow (Y) phosphor on the blue chips. The three-band pc-WLED resulted in improved color rendering index (CRI) and corrected color temperature (CCT), compared with those of the two-band pc-WLED.

• 한국세라믹학회지
• /
• 제39권6호
• /
• pp.589-593
• /
• 2002

Bi:Y$_3$Fe$_{5}$ $O_{12}$(Bi:YIG)를 (GdCa)$_3$(GaMgZr)$_{5}$ $O_{12}$(SGGG)기판 위에 Liquid Phase Epitaxy(LPE)법으로 단결정 후막을 성장시켰다 기판회전속도, 과냉도, 성장시간을 고정하여 PO/Bi$_2$ $O_3$ 몰 비 변화에 따른 성장된 가네트 결정의 격자상수 변화와 Bi 농도 분포를 조사하였다. PO/Bi$_2$ $O_3$ 몰 비가 감소함에 따라 성장된 가네트 결정의 격자상수하 Bi 농도는 증가하는 경향이 나타났으나, 가네트 결정의 두께가 증가됨에 따라 Bi 농도는 감소하는 경향이 나타났다.

• Transactions on Electrical and Electronic Materials
• /
• 제15권6호
• /
• pp.338-343
• /
• 2014

A $Fe_3O_4$-graphite nanofiber composite for use as an anode material was successfully synthesized by calcining $Fe_3O_4$ and graphite nanofiber (GNF) together in a $N_2$ atmosphere. Using this $Fe_3O_4$-GNF composite in a lithium ion battery resulted in a higher lithium storage capacity than that obtained using $Fe_3O_4$-graphite ($Fe_3O_4$-G). The $Fe_3O_4$-GNF (10 wt%) electrode exhibited a higher lithium ion diffusion coefficient ($2.29{\times}10^{-9}cm^2s^{-1}$) than did the $Fe_3O_4$-G (10%) ($3.17{\times}10^{-10}cm^2s^{-1}$). At a current density of $100mA\;g^{-1}$, the $Fe_3O_4$-GNF (10 wt%) anode showed a higher reversible capacity ($1,031mAh\;g^{-1}$) than did the $Fe_3O_4$-G (10%) anode ($799mAh\;g^{-1}$). Moreover, the $Fe_3O_4GNF$ electrodes showed good cycling performance without the addition of a conductive material.

• 한국환경과학회지
• /
• 제16권6호
• /
• pp.683-688
• /
• 2007

In this study, N doped $TiO_2$ (TiO-N) thin film was prepared by DC magnetron sputtering method to show the photocatalytic activity in a visible range. Various gases (Ar, $O_2\;and\;N_2$) were used and Ti target was impressed by 1.2 kW -5.8 kW power range. The hysteresis of TiO-N thin film as a function of discharge voltage wasn't observed in 1.2 and 2.9kW of applied power. Cross sections and surfaces of thin films by FE-SEM were tiny and dense particle sizes of both films with normal cylindrical structures. XRD pattern of $TiO_2$ and TiO-N thin films was appeared by only anatase peak. Red shift in UV-Vis adsorption spectra was investigated TiO-N thin film. Photoactivity was evaluated by removal rate measurement of suncion yellow among reactive dyes. The photodegradation rate of $TiO_2$ thin film on visible radiation was shown little efficiency but TiO-N was about 18%.

• 한국결정성장학회지
• /
• 제28권6호
• /
• pp.235-242
• /
• 2018

$Y_2O_3$를 소결조제로 사용한 질화알루미나(AlN)에 다양한 소결조건과 MgO의 도핑이 고온전기전도도의 특성에 대해 미치는 영향에 대해 연구하였다. MgO를 도핑 하였을 때, 2차상으로 스피넬과 페로브스카이트 상이 생성되었고, 이는 전기적 특성에 영향을 끼쳤다. 고온 임피던스를 분석한 결과 MgO의 도핑은 AlN 입내의 활성화 에너지와 전기전도도의 감소를 보이는 반면에, 입계의 경우에는 활성화 에너지와 전기전도도의 증가를 보였다. 이는 저항이 높은 비정질의 액상이 입계에 형성되거나, Mg의 석출에 의하여 쇼트키 장벽이 높아졌기 때문으로 예상된다. MgO가 도핑된 AlN을 어닐링 한 경우에는 어닐링 하지 않은 경우에 비하여, 활성화 에너지와 전기전도도가 더욱 증가하는 것을 볼 수 있었다. 이러한 결과는 $1500^{\circ}C$에서 어닐링을 통하여 미세구조분석에서 보이는 바와 같이 Mg 이온이 입계에서 입내로 확산된 때문으로 예상된다.

• 한국가스학회지
• /
• 제23권6호
• /
• pp.8-16
• /
• 2019

저공해 연소를 위한 방법 중 하나인 배기가스 재순환(flue gas recirculation, 이하 FGR)은 질소산화물 저감에 효과적인 연소 기법이다. 이를 메탄/공기 대향류 예혼합화염에 적용하여 화염의 특성변화와 NOx 생성 기구를 파악하기 위한 수치해석을 진행하였다. 신장률에 따라 배출되는 생성물들의 몰분율이 달라진다는 점을 고려하여 재순환율은 생성물을 기준으로 정의되었으며, 실제 연소 시스템을 반영하기 위해 주요 생성물인 CO₂, H₂O, O₂ 그리고 N₂를 희석제로써 재순환하였다. FGR 기법이 적용됨에 따라 특정한 신장률 조건에서 최대화염 온도의 전환점이 발견되었다. 또한, 재순환율이 증가함에 따라 온도와 NO의 경향이 달리 나타났으며, 이를 파악하고자 NO 반응을 열적 NO와 Fenimore NO로 구분하여 분석하였다.

• 한국표면공학회지
• /
• 제48권5호
• /
• pp.211-217
• /
• 2015

To fabricate white LED having a high color rendering index value, red color phosphor mixed with the green color phosphor together in the blue chip, namely the blue chips with RG phosphors packaging is most favorable for high power white LEDs. In our previous papers, we reported on successful syntheses of $Sr_{2-}$ $Si_5N_8:Eu^{2+}$ and $CaAlSiN_3$ phosphors for red phosphor. In this work, for high power green phosphor, greenemitting ternary nitride $Ba_3Si_6O_{12}N_2:Eu^{2+}$ phosphor was synthesized in a high frequency induction furnace under $N_2$ gas atmosphere at temperatures up to $1400^{\circ}C$ using $EuF_3$ as a raw material for $Eu^{2+}$ dopant. The effects of molar ratio of component and experimental conditions on luminescence property of prepared phosphors have been investigated. The structure and luminescence properties of prepared $Ba_3Si_6O_{12}N_2:Eu^{2+}$ phosphors were investigated by XRD and photoluminescence spectroscopy. The excitation spectra of $Ba_3Si_6O_{12}N_2:Eu^{2+}$ phosphors indicated broad excitation wavelength range of 250 - 500 nm, namely from UV to blue region with distinct enhanced emission spectrum peaking at ${\approx}530nm$.

• Current Photovoltaic Research
• /
• 제8권2호
• /
• pp.60-65
• /
• 2020

In perovskite solar cells with planar heterojunction configuration, selection of proper charge-transporting layers is very important to achieve stable and efficient device. Here, we developed solution processible Cu doped NiO_x (Cu:NiO_x) thin film as a hole-transporting layer (HTL) in p-i-n structured methylammonium lead trihalide (MAPbI₃) perovskite solar cell. The transmittance and thickness of NiO_x HTL is optimized by control the spin-coating rate and Cu is additionally doped to improve the surface morphology of undoped NiO_x thin film and hole-extraction properties. Consequently, a perovskite solar cell containing Cu:NiO_x HTL with optimal doping ratio of Cu exhibits a power conversion efficiency of 14.6%.