• Analytical Science and Technology
• /
• v.32 no.3
• /
• pp.88-95
• /
• 2019

This study was conducted to establish the analytical method for the determination of cyanide in blood, urine, lung and skin tissues in rats. In order to detect or quantify the sodium cyanide in above biological matrixes, it was derivatized to Pentafluorobenzyl cyanide (PFB-CN) using pentafluorobenzyl bromide (PFB-Br) and then reaction substance was analyzed using gas chromatography mass spectrometer (GC/MS)-SIM (selected ion monitoring) mode. The analytical method for cyanide determination was validated with respect to parameters such as selectivity, system suitability, linearity, accuracy and precision. No interference peak was observed for the determination of cyanide in blank samples, zero samples and lower limit of quantification (LLOQ) samples. The lowest limit detection (LOD) for cyanide was $10{\mu}M$. The linear dynamic range was from 10 to $200{\mu}M$ for cyanide with correlation coefficients higher than 0.99. For quality control samples at four different concentrations including LLOQ that were analyzed in quintuplicate, on six separate occasions, the accuracy and precision range from -14.1 % to 14.5% and 2.7 % to 18.3 %, respectively. The GC/MS-based method of analysis established in this study could be applied to the toxicokinetic study of cyanide on biological matrix substrates such as blood, urine, lung and skin tissues.

• Analytical Science and Technology
• /
• v.34 no.1
• /
• pp.1-8
• /
• 2021

An analytical method was developed and optimized for the quantification of a plant growth regulator, 2,6-diisopropylnaphthalene (2,6-DIPN), in agricultural products using gas chromatography-tandem mass spectrometry. The samples were extracted, partitioned, and were purified using a Florisil® cartridge. To validate the analytical method, its specificity, linearity, limit of detection (LOD) and limit of quantification (LOQ) of the instrument, LOQ of the analytical method (MLOQ), accuracy, and repeatability were considered. The method displayed excellent results during validation, and is suitable for the determination and quantification of the low residual levels of the analyte in the agricultural samples. All of the results with the optimized method were satisfactory and within the criteria ranges requested in the Codex Alimentarius Commission guidelines and the Ministry of Food and Drug Safety guidelines for pesticide residue analysis. The developed method is simple and accurate and can be used as a basis for safety management of 2,6-DIPN.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1998.04b
• /
• pp.447-454
• /
• 1998

The main object of the study is that axial force-moment relationships for high strength concrete structures using reliability theory(Linear statstical method, Monte Carlo Simulation) including probability conception. And mean stress factors and centroid factors proposed to high strength concrete structures using reliability theory(Linear statstical method, Monte Carlo Simulation). Finally, The established experimental data for axial force-moment relationships are compared to the analytical data(data for Linear statstical method and Monte Carlo Simulation) for axial force-moment relationships in this analytical method.

• 한국전산유체공학회:학술대회논문집
• /
• 2003.10a
• /
• pp.272-275
• /
• 2003

A mixed analytical/numerical method is developed here to solve the low Reynolds number kepsilon turbulence model. In this method the advection-diffusion part is solved numerically, while the source terms are split into two parts: one part is solved analytically and the next is solved numerically.

• Journal of Electrical Engineering and Technology
• /
• v.12 no.5
• /
• pp.1883-1890
• /
• 2017

Transformers are one of the most precious elements of the electric power system. Stability and reliability of the electric power network mainly depend on the working of the transformer. Leakage reactance of the transformer is one of the important factors and accurate calculation of the leakage reactance is necessary for the transformer designers and electric distributors. Leakage reactance of the transformer depends on the geometry of the transformer. There are many different methods for the calculations of the leakage reactance however mostly are usable when the axial heights of the high voltage and low voltage windings are equal. When the axial heights of high voltage and low voltage windings are asymmetric most of the analytical methods are not reliable. In this study, a new analytical method is introduced for the calculation of the leakage reactance. Fourteen different transformers are investigated in this study and four of them are presented in this paper. The results of the new analytical method are compared with the experimental results. Other analytical and numerical methods are also compared with this new method. Results show that this method is more reliable and accurate as compared to the other analytical methods. The maximum relative error between short-circuit test and proposed method for these fourteen transformers was less than 2.8%.

• The Transactions of The Korean Institute of Electrical Engineers
• /
• v.59 no.2
• /
• pp.318-327
• /
• 2010

This paper deals with analysis on dynamic characteristic and circuit parameter of linear switched reluctance motor by electromagnetic analytical method. Above all, using space harmonic method, which is electromagnetic method, the air-gap flux density is analyzed in the both align and unaign positions, and the inductance profile, force characteristic and resistance per phase are calculated by means of the process. The validity of the analyzed results are demonstrated by the finite element method(FEM) and manufacture of the prototype machine. Second, the dynamic simulation is analyzed by the use of circuit parameters derived from analytical method, and the operating system of the prototype machine is manufactured to demonstrated the validity of simulation analysis. As a result, it is considered that the characteristic equation suggested in this paper will contribute to the design, analysis and application of LSRM.

• Journal of the Korean Geotechnical Society
• /
• v.16 no.4
• /
• pp.5-16
• /
• 2000

THe purpose of this paper is to suggest the analytical method which can predict lateral nonlinear behavior in non-homogeneous soil using the coefficient of soil resistance and ultimate soil resistance. Those parameters are obtained through back analysis on the base of the results of a series of model tests.Analytical method of Chang is more or less difficult to predict nonlinear behavior in non-homogeneous sol. So, in this study, for the prediction of nonlinear behavior the compositive analytical method which apply the p - y curve to Chang model is suggested. Also, the program is developed to predict nonlinear behavior using the compositive analytical method and it can be used to calculated the deflection, bending moment and soil reaction with DFM in non-homogeneous soil. To establish applicability of the suggested analytical method, the results of model tests and field tests and Pentagon2D finite element program are compared with those of the compositive analytical method. In the analysis values of the coefficient of soil reaction and ultimate soil resistance are also applied to the case of non-homogeneous soil. Lateral defection calculated using the compositive analytical method has been found to be in good agreement with values measured in field and model load tests.

• Journal of the Korean Society for Industrial and Applied Mathematics
• /
• v.2 no.2
• /
• pp.97-109
• /
• 1998

A comparison of the two dimensional heat loss, computed using the analytical method and the finite difference method in two models(i.e. one is a parabolic fin whose parabolic curves meet at the fin center line and the other is a transformed parabolic fin whose tip cuts vertically), is made assuming the analytical method is correct. For these methods, the root temperature and surrounding convection coefficients of these fins are assumed as constants. The results show that the relative errors of the heat loss between the two methods for the parabolic fin whose tip cuts vertically are smaller than those for the one whose tip does not cut. In case of Bi=0.01, the values of the heat loss obtained using a finite difference method are close to those values obtained using the analytical method for both models. The values of the heat loss from both models calculated by using the analytical method are almost the same for given range of non-dimensional fin length in case of Bi = 0.01 and 0.1.

• The Transactions of The Korean Institute of Electrical Engineers
• /
• v.64 no.11
• /
• pp.1551-1557
• /
• 2015

Magnetic coupling is used where required high reliability. because magnetic coupling's durability is stronger than mechanical coupling's durability. This paper shows the characteristics of radially magnetized tubular type magnetic coupling by using Analytical method such as space harmonic method. Analytical method was used, to find force characteristics. First, on the basis of the magnetic vector potential and two-dimensional(2-D) polar-coordinate system, the magnetic field solutions of the radially magnetized permanent magnet are obtained. And we obtain the analytical solutions for the flux density produced by permanent magnet. Finally, we can calculate the force by using the Maxwell stress tensor. And then, Finite element method(FEM) is used to validate force characteristics.

• Proceedings of the KSR Conference
• /
• 2005.11a
• /
• pp.1215-1222
• /
• 2005

The object of this thesis is an study on detailing for concrete reinforcement and analytical study for seismic behavior of underground reinforced concrete box structures using the established seismic analytical method. Using the established seismic analytical method that has been presented in various documents seismic behavior of buried reinforce concrete box structures is compared. From the comparsion, it is shown that feasibility and detailing detailng for concrete reinforcement and seismic method for seismic analysis of buried reinforced concrete box structures.