• 제목/요약/키워드: Alkali Oxide

검색결과 135건 처리시간 0.027초

Soda lime glass기판위의 barrier층$(SiO_2,\;Al_2O_3)$이 ITO박막특성에 미치는 영향 (Effect of ITO thin films characterization by barrier layers$(SiO_2\;and\;Al_2O_3)$ on soda lime glass substrate)

  • 이정민;최병현;지미정;안용태;주병권
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.292-292
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    • 2007
  • To apply PDP panel, Soda lime glass(SLG) is cheeper than Non-alkali glass and PD-200 glass but has problems such as low strain temperature and ion diffusion by alkali metal oxide. In this paper suggest the methode that prohibits ion diffusion by deposing barrier layer on SLG. Indium thin oxide(ITO) thin films and barrier layers were prepared on SLG substrate by Rf-magnetron sputtering. These films show a high electrical resistivity and rough uniformity as compared with PD-200 glass due to the alkali ion from the SLG on diffuse to the ITO film by the heat treatment. However these properties can be improved by introducing a barrier layer of $SiO_2\;or\;Al_2O_3$ between ITO film and SLG substrate. The characteristics of films were examined by the 4-point probe, SEM, UV-VIS spectrometer, and X-ray diffraction. GDS analysis confirmed that barrier layer inhibited Na and Ka ion diffusion from SLG. Especially ITO films deposited on the $Al_2O_3$ barrier layer had higher properties than those deposited on the $SiO_2$ barrier layer.

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Synthesis of New pH-Sensitive Poly(ethylene oxide-b-maleic acid) from Modification of Poly(ethylene oxide-b-N-phenylmaleimide)

  • Go, Da-Hyeon;Jeon, Hee-Jeong;Kim, Tae-Hwan;Kim, Geun-Seok;Choi, Jin-Hee;Lee, Jae-Yeol;Kim, Jung-Ahn;Yoo, Hyun-Oh;Bae, You-Han
    • Macromolecular Research
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    • 제16권7호
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    • pp.659-662
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    • 2008
  • A new and useful poly(ethylene oxide)-based pH-sensitive block copolymer is introduced. Poly(ethylene oxide-b-N-phenylmaleimide) was first synthesized by anionic polymerization of N-phenylmaleimide (N-PMI) using mixed alkali metal polymeric alkoxide by sequential monomer addition method in the mixture of benzene/THF/DMSO (10/5/3, v/v/v) at room temperature. Reductive deimidation of the resulting block copolymer was performed using hydrazine monohydrate leading to the formation of the corresponding pH-sensitive poly(ethylene oxide-b-maleic acid).

Hydrogen and Alkali Ion Sensing Properties of Ion Implanted Silicon Nitride Thin Film

  • Park, Gu-Bum
    • Transactions on Electrical and Electronic Materials
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    • 제9권6호
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    • pp.231-236
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    • 2008
  • B, P, and Cs ions were implanted with various parameters into silicon nitride layers prepared by LPCVD. In order to get the maximum impurity concentration at the silicon nitride surface, a high temperature oxide (HTO) buffer layers was deposited prior to the implantation. Alkali ion and pH sensing properties of the layers were investigated with an electrolyte-insulator-silicon (EIS) structure using high frequency capacitance-voltage (HF-CV) measurements. The ion sensing properties of implanted silicon nitrides were compared to those of as-deposited silicon nitride. Band Cs co-implanted silicon nitrides showed a pronounced difference in pH and alkali ion sensing properties compared to those of as-deposited silicon nitride. B or P implanted silicon nitrides in contrast showed similar ion sensitivities like those of as-deposited silicon nitride.

Improved methods for the preparation of $(Y_{1-x}Eu_x)_2O_3$:MX and $(Y_{1-x-y}Gd_xEu_y)_2O_3$:MX as red phosphor materials

  • Lee, You-Hui;Han, Sang-Do;Kim, Jung-Duk;Chang, Mi-Yeon;Singh, Ishwar.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.715-718
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    • 2004
  • Substantially improved methods for the preparation of europium-doped yttrium oxide red phosphor with the inclusion of alkali metal halides having a general formula $(Y_{1-x}Eu_x)_2O_3$:MX where 0.025${\leq}$x${\leq}$0.2 and MX is alkali halide in the mole ratio 0.025 to 0.6, more preferably between 0.05 to 0.2 mole, are reported. Another series of the red phosphor materials with general formula $(Y_{1-x-y}Gd_xEu_y)_2O_3$:MX where 0.05${\leq}$x${\leq}$0.40 and 0.025${\leq}$y${\leq}$0.20 and MX is alkali halide in the mole ratio 0.025 to 0.5, more preferably between 0.1 to 0.2 mole, has also been presented. The inclusion of alkali halide greatly increase the luminance of the materials. The materials are very soft with fine particle size less than 100nm. The phosphorescent materials have good luminance in VUV region.

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영지버섯 다당체의 Nitric Oxide 생성능 및 생성기전 연구 (Nitric Oxide Production Ability and its Formation Mechanisms in Macrophage TIB 71 Cell Line by Polysaccharide Extracted from Ganoderma lucidum)

  • 김성환
    • 한국식품영양과학회지
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    • 제27권2호
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    • pp.333-337
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    • 1998
  • This study was carried out to get infomation on the nitric oxide production ability and its formation mechanisms of polysaccharides extracted from Ganoderma lucidum(PSG) by using murine macrophage cell line. The cultured mycelial cells of Ganoderma lucidum were extracted by alkali, and than neutralized by acid. The extract were passed through the column of DEAE cellulose for more purification. The neutral fraction was concentrated and precipitated with 95% ethanol. The precipitate was lyophilized and PSG was obtained. The immunomodulating effects of PSG on macrophage were performed by using murine macrophage cell line ATCC TIB 71 cells with PSG 0.5mg. PSG alone could not induce the production of nitrite, but it had a significant potential effect on nitrite secretion when the cells were primed and triggered with BCG and Interferon(IFN)-${\gamma}$. Also it was prominent by using calcium channel blocker(verapamil) and adenylate cyclase activator(forskolin).

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Mechanochemical Approach for Oxide Reduction of Spent Nuclear Fuels for Pyroprocessing

  • Kim, Sung-Wook;Han, Seung Youb;Jang, Junhyuk;Jeon, Min Ku;Choi, Eun-Young
    • 방사성폐기물학회지
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    • 제19권2호
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    • pp.255-266
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    • 2021
  • Solid-state mechanochemical reduction combined with subsequent melting consolidation was suggested as a technical option for the oxide reduction in pyroprocessing. Ni ingot was produced from NiO as a starting material through this technique while Li metal was used as a reducing agent. To determine the technical feasibility of this approach for pyroprocessing, which handles spent nuclear fuels, thermodynamic calculations of the phase stabilities of various metal oxides of U and other fission elements were made when several alkaline and alkali-earth metals were used as reducing agents. This technique is expected to be beneficial, not only for oxide reduction but also for other unit processes involved in pyroprocessing.

$CaO-TiO_2-P_2O_5$계 다공질 결정화 유리의 물성에 미치는 알카리 금속 산화물의 첨가효과 (Addition Effects of Alkali Metal Oxide on Some Properties of Porous Glass-Ceramics in the $CaO-TiO_2-P_2O_5$ System)

  • 장순규;최세영
    • 한국세라믹학회지
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    • 제31권11호
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    • pp.1337-1345
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    • 1994
  • Glasses in the system of 45CaO-25TiO2-30P2O5 containing 1 mole% of M2O(M=Li, Na, K) were melted and crystallized. And their crystal phases were Ca3(PO4)2, CaTi4(PO4)6, and TiO2. Porous glass-ceramics with skeleton of two crystal phase CaTi4(PO4)6 and TiO2 were prepared by selective leaching of Ca3(PO4)2 with 0.1 N-HCl. Glass transition temperature(Tg) and crystallization temperature(Tc) were decreased by addition of 1 mole% alkali metal oxide. Pore size of porous glass-ceramics was increased with increasing heat treatment temperature and its dependence on heat treatment temperature was decreased with addition of Na2O and K2O. It was found that porous glass-ceramics of parent glass and containing 1mole% M2O(M=Li, Na, K) composition had maximum specific surface area, porosity and maximum of crystallzed phase by heat treatment at 80$0^{\circ}C$, 76$0^{\circ}C$, 78$0^{\circ}C$, 80$0^{\circ}C$ respectively.

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인 흡착용 마그네타이트 합성 시 알칼리 종류 및 농도가 공침 입자크기에 미치는 영향 (Effects of alkali species and concentration on the size distribution of the co-precipitated magnetite particles used for phosphate adsorption)

  • 이민형;;남해욱;김윤중;최영균
    • 상하수도학회지
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    • 제30권4호
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    • pp.409-415
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    • 2016
  • Magnetite particles were synthesized by co-precipitation of water-soluble 밀 스케일-derived precursor by various concentrations of (0.5, 0.67, 1, 2 N) NaOH and (0.6, 0.8, 1.2, 2.4 N) $NH_4OH$. It is theoretically known that as the concentration of the alkaline additive used in iron oxide synthesis increases, the particle size distribution of that iron oxide decreases. This trend was observed in both kind of alkaline additive used, NaOH and $NH_4OH$. In addition, the magnetite synthesized in NaOH showed a relatively smaller particle size distribution than magnetite synthesized in $NH_4OH$. Crystalline phase of the synthesized magnetite were determined by X-ray diffraction spectroscopy(XRD). The particles were then used as an adsorbent for phosphate(P) removal. Phosphorus adsorption was found to be more efficient in NaOH-based synthesized magnetite than the $NH_4OH$-based magnetite.

황산제일철과 암모니아수를 이용한 산화철 합성 (Synthesis of Iron Oxide Using Ferrous Sulfate and Ammonia Water)

  • 김삼중;엄태형;왕웨이;서동수
    • 한국재료학회지
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    • 제18권4호
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    • pp.218-221
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    • 2008
  • A $Fe(OH)_2$ suspension was prepared by mixing iron sulfate and a weak alkali ammonia solution. Following this, iron oxides were synthesized by passing pure oxygen through the suspension (oxidation). The effects of different reaction temperatures ($30^{\circ}C$, $50^{\circ}C$, $70^{\circ}C$) and equivalent ratios ($0.1{\sim}10.0$) on the formation of iron oxides were investigated. An equilibrium phase diagram was established by quantitative phase analysis of the iron oxides using the Rietveld method. The equilibrium phase diagram showed a large difference from the equilibrium phase diagram of Kiyama when the equivalent ratio was above 1, and single $Fe_3O_4$ phase only formed above an equivalent ratio 2 at all reaction temperatures. Kiyama synthesized iron oxide using iron sulfate and a strong alkali NaOH solution.