• 제목/요약/키워드: Activation Process

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Electrochemical Capacitance of Activated Carbons Regenerated using Thermal and Chemical Activation

  • Park, Jung Eun;Lee, Gi Bbum;Hwang, Sang Youp
    • Journal of Electrochemical Science and Technology
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    • 제12권3호
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    • pp.339-345
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    • 2021
  • Spent activated carbons (SACs) collected from a water treatment plant were regenerated and then adopted as electrochemical material in capacitors. The SACs used in this study were regenerated via two steps, namely thermal and chemical activation. However, during the activation process, the adsorbates were converted into ashes, which caused pore blockage and decreased specific surface area. The regenerated SACs were washed with acid solutions with different levels of acidity (strong: HCl, mild: H3PO4, and weak: H2O2) to remove the ashes. The regenerated SACs washed with HCl exhibited the highest specific surface area, although their capacitance was not the highest. Conversely, the specific surface area of regenerated SACs washed using H3PO4 was slightly lower than that of HCl, but exhibited higher capacitance and electrochemical stability. Although the strong acid removed the generated ashes in the pores efficiently, it could adversely affect their structural stability, which would lead to lower capacitance.

오존에 의한 전처리가 활성탄소섬유 화학적 표면개질에 미치는 영향 (Effect of Pre-Treatment by Ozone on Chemical Surface Modification of Activated Carbon Fiber)

  • 장정희;한기보;김호
    • 대한환경공학회지
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    • 제35권6호
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    • pp.415-421
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    • 2013
  • 활성탄소섬유(Activated carbon fiber, ACF)의 비표면적을 향상시키는 대표적인 방법은 알칼리금속을 이용한 화학적 활성화(Chemical activation, CA)와 산화제를 이용한 표면처리(Surface treatment, ST)방법이 있다. 알칼리금속을 이용한 CA 공정은 열처리 과정에서 알칼리금속의 화학반응에 의하여 미세기공이 발달되며, ST 공정은 산화제의 산화력에 의하여 표면의 미세기공을 발달시킨다. 본 연구에서는 대표적인 표면개질 방법인 CA 공정의 효과를 증대하기 위하여 전처리로 ST 공정을 수행하였으며, ST 공정 유무에 따라 CA된 ACF의 특성변화를 관찰하였다. ST 및 CA 유무에 따른 ACF 특성을 조사하기 위하여 무게변화, FT-IR, TGA, 원소분석을 수행하였으며, 대표적인 VOC물질인 톨루엔을 이용하여 흡착특성을 평가하였다. 실험결과 초기 raw ACF의 비표면적과 톨루엔 흡착량은 각각 1,483 $m^2/g$, 0.22 $g_{-Tol.}/g_{-ACF}$였으며, CA 처리시 1,998 $m^2/g$, 0.27 $g_{-Tol.}/g_{-ACF}$로 증가하였고, ST된 ACF를 CA 처리한 경우 2,743 $m^2/g$, 0.37 $g_{-Tol.}/g_{-ACF}$로 증가하였다. 본 연구를 통하여 ST 및 CA 결합공정을 통한 ACF의 표면특성을 증가를 확인하였다.

사무간접부문에서의 6시그마 경영 활성화 방안 (Activation Scheme of Six Sigma in the Non-manufacturing Process of Industry)

  • 안병진;김상익;서한손
    • 품질경영학회지
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    • 제31권2호
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    • pp.220-229
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    • 2003
  • The methodology of Six Sigma originated at Motorola in the early 1980s is nowadays proved to be an effective way in Improving the quality. Many companies find adding Six Sigma to their current business system gives them all or almost all the elements of total quality management(TQM). However most companies where Six Sigma is implemented confront many difficulties in non-manufacturing parts such as transactional and administrative processes. In this paper we discuss distinct aspects of such non-manufacturing process, and investigate activating scheme of Six Sigma in those parts of industry.

급속 열처리 시스템의 개발 및 응용 (Development and Application of Rapid Thermal Process System)

  • 김윤태;정기로;김호영;김현태;유형준
    • 대한전자공학회논문지
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    • 제25권9호
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    • pp.1051-1059
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    • 1988
  • In this study, we developed a proto-type RTP equipment by using tungsten halogen lamps. The system has been designed utilizing the result of the numerical analysis of the reactor. In order to analyze the system performance, experiments for activation of implanted atoms and oxidation process were performed. As a result, we obtained 2-3% uniformity in sheet resistance and 2-4% uniformity in oxide thickness, although after a long time process at high temperatures slip lines and warpage of the wafer have been observed.

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Chemistry of Ruthenium Hydridonitrosyl Complexes Containing Chelating Triphosphines III-Structure and Fluxional Mechanism of fac-RuH(NO)(ttp)

  • Ik Mo Lee;Yeoug Joong Kim;Ook Jae Cho;Devon W. Meek
    • Bulletin of the Korean Chemical Society
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    • 제13권5호
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    • pp.504-507
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    • 1992
  • fac-RuH(NO)(ttp) is fluxional in the range between 180 K and 303 K. The structures involved in this fluxional process are found to be a mixture of two square pyramids and a trigonal bipyramid from the low temperature NMR spectra and the line shape analysis using DNMR 3 program and the activation parameters of this process were determined by using the simulated data. The mechanism of this fluxional process is proposed to be a pathway known as Turnstile Rotation.

토목공사의 BIM 현황 및 활성화에 관한 연구 (The Current Status and Facilitation Strategy of BIM for Civil Infrastructure Projects)

  • 박태순;박희성
    • 대한토목학회논문집
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    • 제38권1호
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    • pp.133-140
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    • 2018
  • 본 논문은 건설업에서 전 생애주기 동안 생성되는 정보와 업무 등을 통합 및 관리할 수 있는 BIM (Building Information Modeling)에 관해 국내 토목분야에서 BIM기술의 현황과 활성화를 위한 방안의 기초자료 제공을 목적으로 수행하였다. 이를 위해 토목분야와 건축분야의 실무자를 대상으로 국내 건설업의 BIM 적용 현황, 실무자 인식조사, 활성화 방안을 위한 계층 분석을 실시하였다. 설문조사 결과 BIM 활성화 저해요인, 단계별 업무에 따른 BIM의 필요성, BIM 적용 시 효과 등과 향후 BIM의 발전 가능성에 대한 질문들은 비슷한 경향을 나타냈다. 토목분야는 건축분야에 비해 BIM의 활용 현황, 기술 교육 정도 등이 낮은 것으로 나타났다. BIM의 활성화 방안을 위한 AHP (Analytic Hierarchy Process) 분석 시에는 재무적, 운영적, 투자적, 기술적, 제도적인 부문별로 중요도에 따른 순위 결과 기술적인 부문이 중요하게 나타났다. 본 연구결과는 BIM의 현황 및 활성화를 위한 분석 결과를 기반으로 효율적인 방안을 제시함으로써 향후 토목분야에 BIM 적용 시 기본방향을 위한 연구에 활용될 수 있다.

치과 임플란트 고정체의 여러 가지 제조공정과정에 따른 표면특성 (Surface Characteristics of Dental Implant Fixture with Various Manufacturing Process)

  • 정용훈;문영필;이충환;유진우;최한철
    • 한국표면공학회지
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    • 제43권1호
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    • pp.17-24
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    • 2010
  • In this study, surface characteristics of dental implant fixture with various manufacturing process have been researched using electrochemical methods. The dental implant fixture was selected with 5 steps by cleaning, surface treatment and sterilization with same size and screw structure; the 1st step-machined surface, 2nd step-cleaned by thinner and prosol solution, 3th step-surface treated by RBM (resorbable blasting media) method, 4th step-cleaned and dried, 5th step-sterilized by gamma-ray. The electrochemical behavior of dental implant fixture has been evaluated by using potentiostat (EG&G Co, 2273A) in 0.9% NaCl solution at $36.5{\pm}1^{\circ}C$. The corrosion surface was observed using field-emission scanning electron microscopy (FE-SEM) and energy dispersive x-ray spectroscopy (EDS). The step 5 sample showed the cleaner and rougher surface than step 3 sample. The step 5 sample of implant fixture treated by RBM and gamma sterilization showed the low corrosion current density compared to others. Especially, the step 3 sample of implant fixture treated by RBM was presented the lowest value of corrosion resistance and the highest value of corrosion current density. The step 3 sample showed the low value of polarization resistance compared to other samples. In conclusion, the implant fixture treated with RBM and gamma sterilization has the higher corrosion resistance, and corrosion resistance depends on the step of manufacturing process.

Life cycle Health Promotion Programs using Traditional Korean Medicine (HaPPs-TKM) and Activation Plan

  • Jo, Jae Kyung;Park, Sunju
    • 대한예방한의학회지
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    • 제24권3호
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    • pp.57-67
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    • 2020
  • Background : The Life cycle Health Promotion Programs using Traditional Korean Medicine (the Life cycle HaPPs-TKM) are the on-going 3rd stage projects that have centered on the development and dissemination of the standard life cycle HaPPs-TKM in the local community. The purpose of the study was to introduce the development background of the standard life cycle HaPPs-TKM and to suggest its activation plan. Methods : Academic and government research reports on the life cycle HaPPs-TKM were analyzed to introduce the development process, development backgrounds and the details of KM-HPP for each life cycle, such as infants and toddlers, adolescents, pregnant women, adults and the elderly. Results : We reviewed the development process of the standard life cycle HaPP-TKM consisted of a series of diagnosis on community members' health problems, establishment of project purpose, research on the involvement of KM intervention in a project, and final development of the project model. And we rediscovered that in the development backgrounds of KM-HPP, there were beneficial goals to manage and promote public health conditions for each life cycle. Conclusion : To activate life cycle HaPPs-TKM, we would recommend that activation plan should include six factors through systematic analysis of research reports. These factors consist of diversified goals for each life-cycle, competency reinforcement of local project manager, diversified Korean Medicinal modalities to enhance Sasang Constitution and Qigong, development of standard Outcome Index, periodical holding of performance contest, and improved guidance of government and associated entities through whole process of HaPP-TKM.

Experimental research on the effect of water-rock interaction in filling media of fault structure

  • Faxu, Dong;Zhang, Peng;Sun, Wenbin;Zhou, Shaoliang;Kong, Lingjun
    • Geomechanics and Engineering
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    • 제24권5호
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    • pp.471-478
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    • 2021
  • Water damage is one of the five disasters that affect the safety of coal mine production. The erosion of rocks by water is a very important link in the process of water inrush induced by fault activation. Through the observation and experiment of fault filling samples, according to the existing rock classification standards, fault sediments are divided into breccia, dynamic metamorphic schist and mudstone. Similar materials are developed with the characteristics of particle size distribution, cementation strength and water rationality, and then relevant tests and analyses are carried out. The experimental results show that the water-rock interaction mainly reduces the compressive strength, mechanical strength, cohesion and friction Angle of similar materials, and cracks or deformations are easy to occur under uniaxial load, which may be an important process of water inrush induced by fault activation. Mechanical experiment of similar material specimen can not only save time and cost of large scale experiment, but also master the direction and method of the experiment. The research provides a new idea for the failure process of rock structure in fault activation water inrush.

High-energy-density activated carbon electrode for organic electric-double-layer-capacitor using carbonized petroleum pitch

  • Choi, Poo Reum;Kim, Sang-Gil;Jung, Ji Chul;Kim, Myung-Soo
    • Carbon letters
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    • 제22권
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    • pp.70-80
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    • 2017
  • Activated carbons (ACs) have been used as electrode materials of electric double-layer capacitors (EDLC) due to their high specific surface areas (SSA), stability, and ecological advantages. In order to make high-energy-density ACs for EDLC, petroleum pitch (PP) pre-carbonized at $500-1000^{\circ}C$ in $N_2$ gas for 1 h was used as the electrode material of the EDLC after KOH activation. As the pre-carbonization temperature increased, the SSA, pore volume and gravimetric capacitance tended to decrease, but the crystallinity and electrode density tended to increase, showing a maximum volumetric capacitance at a medium carbonization temperature. Therefore, it was possible to control the crystalline structure, SSA, and pore structure of AC by changing the pre-carbonization temperature. Because the electrode density increased with increasing of the pre-carbonization temperature, the highest volumetric capacitance of 28.4 F/cc was obtained from the PP pre-carbonized at $700^{\circ}C$, exhibiting a value over 150% of that of a commercial AC (MSP-20) for EDLC. Electrochemical activation was observed from the electrodes of PP as they were pre-carbonized at high temperatures above $700^{\circ}C$ and then activated by KOH. This process was found to have a significant effect on the specific capacitance and it was demonstrated that the higher charging voltage of EDLC was, the greater the electrochemical activation effect was.