• Title/Summary/Keyword: 활성화제

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Influence of Blended Activators on the Physical Properties of Alkali-activated Slag Mortar (알칼리 활성화 슬래그 모르타르의 특성에 미치는 혼합 활성화제의 영향)

  • Kim, Tae Wan;Park, Hyun Jae;Seo, Ki Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.6
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    • pp.26-33
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    • 2012
  • This paper reported on the effect of blended activator on the physical properties of alkali-activated slag mortar. Five different activators(caustic alkalis) were used: sodium hydroxide(NaOH, A Case), calsium hydroxide($Ca(OH)_2$, B Case), magnesium hydroxide($Mg(OH)_2$, C Case), aluminum hydroxide($Al(OH)_3$, D Case), and potassium hydroxide(KOH, E Case). We blended five caustic alkalis with sodium carbonate($Na_2CO_3$). The dosage of five caustic alkalis was 3M and sodium carbonate was 1M, 2M and 3M. The result of flow and setting time was decrease as the dosage of sodium carbonate increase. But the compressive strength was increase as the dosage of sodium carbonate increase. It was shown that there is a good effect of blended caustic alkalis with sodium carbonate in alkali-activated slag mortar.

A Study on Cementation of Sand Using Blast Furnace Slag and Extreme Microorganism (고로슬래그와 극한미생물을 이용한 모래의 고결화 연구)

  • Park, Sung-Sik;Choi, Sun-Gyu;Nam, In-Hyun
    • Journal of the Korean Geotechnical Society
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    • v.30 no.1
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    • pp.93-101
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    • 2014
  • In this study, a blast furnace slag having latent hydraulic property with an alkaline activator for resource recycling was used to solidify sand without using cement. Existing chemical alkaline activators such as $Ca(OH)_2$ and NaOH were used for cementing soils. An alkaliphilic microorganism, which is active at higher than pH 10, is tested for a new alkaline activator. The alkaliphilic microorganism was added into sand with a blast furnace slag and a chemical alkaline activator. This is called the microorganism alkaline activator. Four different ratios of blast furnace slag (4, 8, 12, 16%) and two different chemical alkaline activators ($Ca(OH)_2$ and NaOH) were used for preparing cemented specimens with or without the alkaliphilic microorganism. The specimens were air-cured for 7 days and then tested for the experiment of unconfined compressive strength (UCS). Experimental results showed that as a blast furnace slag increased, the water content and dry density increased. The UCS of a specimen increased from 178 kPa to 2,435 kPa. The UCS of a specimen mixed with $Ca(OH)_2$ was 5-54% greater than that with NaOH. When the microorganism was added into the specimen, the UCS of a specimen with $Ca(OH)_2$ decreased by 11-60% but one with NaOH increased by 19-121%. The C-S-H hydrates were found in the cemented specimens, and their amounts increased as the amount of blast furnace slag increased through SEM analysis.

Proposal of A Method to Enhance Pumping Efficiency of Cementitious Materials by Injecting Activation Agent to Slip-Layer and its Lab-Scale Experimental Verification (시멘트계 재료의 펌프압송성능 향상을 위한 윤활층 활성화제 주입 방법 제안 및 소규모 실험검증)

  • Lee, Jung-Soo;Yoo, Yong-Sun;Han, Jin-Gyu;Park, Chan-Kyu;Kwon, Seung-Hee
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.4
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    • pp.442-449
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    • 2017
  • In this study, a method to inject small amount of activation agent from the outside of the pipeline to the inside wall of the pipe was newly proposed to enhance pumping efficiency of cementitious materials. The activation agent is injected into the slip-layer, which is generally formed in the vicinity of the inside wall of the pipe during pumping cementitous materials. Through the injections, it is expected to decrease viscosity of slip-layer, namely, the friction between the mateirals and the pipe. The proposed method was verified by lab-scale pumping tests with mortars having water to cement ratio of 47%. The tests were performed with two different type of activation agents(superplasticizer and anionic surfactant) and three different amount of the agents(0.14, 0.28, 0.42% of the mortar volume). The compressive strength were measured with and without injecting the activation agent, and the internal pressures of pipeline were measured. When the anionic surfactant was used, there was no change in the compressive strength. As the amount of anionic surfactant increased, the pumping pressure decreased up to 71.4% at the maximum.

Compressive Strength and Optimal Mixing Ratio of Alkali Activated Cement Concrete Containing Fly Ash (플라이 애쉬를 활용한 알칼리 활성시멘트 콘크리트의 압축강도와 최적혼합비)

  • Han, Sang-Ho;Park, Sang-Sook;Kang, Hwa-Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.11 no.4
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    • pp.152-158
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    • 2007
  • This is a fundamental research to utilize alkali activated cement(AAC) in concrete. The compressive strength of AAC concrete were measured for the various mixing ratios of activator/fly ash, and the mixing ratios of water glass, NaOH, and water among the activators. The mixing ratio of fine and coarse aggregates was maintained constantly. The relationships between the compressive strength and mixing ratios were analyzed to find the optimal mixing ratio of AAC concrete. As the results, the optimal mixing ratio of activator/fly ash in AAC concrete was 0.7, and that of water glass, NaOH, water among the activator was 4.0:1.0:2.5 for the maximum compressive strength.

Recent Trends on Telomerase Activators, Sirtuin Activators, and Senolytics as a Potential Anti-aging Agent (잠재적인 항노화제로 텔로머레이즈 활성화제, 서르튜언 활성화제, 세노릭틱스에 대한 최신 동향)

  • Kim, Moon-Moo
    • Journal of Life Science
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    • v.30 no.9
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    • pp.819-825
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    • 2020
  • All living organisms exhibit the characteristics of aging, such as skin wrinkle formation, muscle degeneration, cataracts, and hair graying as the number of aged cells increases over time. Senescence, which is known as a key cause of aging, is directly related to the aging of living organisms because cells are aged by external and internal factors and eventually cell proliferation is stopped. Senescence is caused by the gradual shortening of the telomere with cell division, and lifespan is determined by the length of the telomere. Recently, it has been found that the histone deacetylase, which can influence gene expression, is not only involved in yeast but also deeply involved in anti-aging mechanisms in both C. elegans and humans. It was also discovered that old cells play a decisive role in the aging phenomenon, and it has been reported that it is possible to promote the proliferation of young cells and delay aging by removing these senescent cells from the inside. Therefore, in order to develop potential anti-aging agents in the future, research should begin with an in-depth study of telomerase activators, sirtuin activators, and senolytics.

Compressive and Tensile Properties of Fiber-Reinforced Cementless Composites According to the Combination of Sodium-Type Alkali-Activators (나트륨계 알칼리 활성화제 조합에 따른 섬유보강 무시멘트 복합재료의 압축 및 인장특성)

  • Choi, Jeong-Il;Park, Se-Eon;Lee, Bang-Yeon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.1
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    • pp.29-36
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    • 2017
  • The purpose of this study is to investigate experimentally the effect of types of alkali-activators and curing conditions on the compressive and tensile behavior of fiber-reinforced cementless composites. Two types of alkali-activators and two curing conditions were determined and density test, compressive strength test, and uniaxial tension test were performed. Test results showed that the cementless composite with sodium silicate showed higher performance in terms of strength, tensile strain capacity, and toughness than that with calcium hydroxide and sodium carbonate. The effect of curing conditions depends on the types of alkali-activators.

Development activator for physical properties of slag Cement (슬래그 시멘트의 물성제어를 위한 활성화제 개발)

  • Park, Nam-Kyu;Lee, Jong-Kyu;Chu, Yong-Sik;Song, Hun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.545-548
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    • 2008
  • In this study aluminium sulfate, Ca(OH)$_2$, K-R Slag and $Na_2SO_4$ were used as active admixtures and their concentration 1, 3, 5, 7 weight percent in cement. The physical properties of active admixtures cement mortar were investigated by flow test and compressive strength. It was found that the resulting active admixtures exhibited the higher compressive strength than OPC mortar up. From the test results, cement mortars added active admixture have a good fundamental property.

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The Effect on the Kind of Alkali-Activator of Cement ZERO Mortar (알칼리 활성화제 종류가 시멘트 ZERO 모르타르에 미치는 영향)

  • Ryu, Gum-Sung;Kang, Hyun-Jin;Ko, Kyung-Taek;Kang, Su-Tae;Kim, Sung-Wook;Lee, Jang-Hwa
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.397-398
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    • 2009
  • Recently, the research about alkaline activity concrete is being progressed actively. In this paper, the effect of many kinds of alkaline activation to fly ash based cement zero mortar is examined.

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Influence of Superplasticizers on Fluidity and Compressive Strength of Alkali Activated Slag Mortar (유동화제가 알칼리 활성 슬래그 모르타르의 유동 특성 및 압축 강도에 미치는 영향)

  • Kim, Dae-Wang;Oh, Sang-Hyuk;Lee, Kwang-Myong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.1
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    • pp.33-40
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    • 2013
  • The cement industry brought very severe environment problems with massive carbon dioxide during its production. To solve this problem, attempts on Alkali-Activated Slag (AAS) concrete that perfectly substitutes industrial by-products such as ground granulated blast furnace slag (GGBFS) for cement are being actively made. AAS concrete is possible to have high strength development at room temperature, however, it is difficult to ensure the working time due to the fast setting time and the loss of workabillity because of the alkali reaction. In this study, the early age properties of alkali activated slag mortar are investigated to obtain the fundamental data for AAS concrete application to structural members. The water-binder ratio (W/B) was fixed at 0.35 and sodium hydroxide and waterglass as alkali activator was used. The compressive strength, the flow and the ultrasonic pulse velocity were measured according to the type of superplasticisers, which were naphthalene(N), lignin(L), melamine(M) and PC(P), up to a maximum of 2 percent by the mass of GGBFS. The results showed that adding melamine type of superplasticizer improved the fluidity of AAS mortar without decreasing the compressive strength, while naphthalene and polycarbonate type of superplasticizer had little effect on the fluidity of AAS mortar.

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Freeze-Thaw Resistance of Alkali Activated Ternary Blended Cement Incorporated with Ferronickel Slag (알칼리 활성화제를 첨가한 페로니켈슬래그 혼입 삼성분계 콘크리트의 동결융해 저항성)

  • Cho, Won-Jung;Park, Kwang-Pil;Ann, Ki-Yong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.2
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    • pp.159-167
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    • 2022
  • The present study assessed the micro structure and durability characteristics of ternary blended cement with different types of alkali activators. Ground granulated blast furnace slag(GGBS) and ferronickel slag(FNS) was replaced until 50 % of the weight of cement. In addition, potassuim hydroxide and sodium hydroxide were used for comparing the properties of different type of alkali activator. Ternary blended cement with alkali activators showed higher peak portlandite peak than that of OPC(Ordinary Portlande Cement) and non activated ternary blended cement. Also, there was no new hydration products in ternary blended cement or/and alkali activators. Based on the mercury intrustion porosimetry(MIP) test result, ternary blended cement increased macro pore while alkali activated ternary blended cement modified pore structure and increased microp pore as compared to OPC as control. Combination with alkali activators is desirable to enhance the compressive strength and freeze thaw resistance.