• Journal of the Korean Ceramic Society
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• v.34 no.2
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• pp.195-201
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• 1997

The present paper describes the effect of dry mixed grinding on kaolinite-aluminum trihydroxide mixture with a planetary ball mill before sintering and its influence on mullite formation during sintering. The size reduction of the mixture is market in the early stage of grinding and the obtained fine particles agglomerate subsequently with an increase of grinding time. The crystal structure of the mixture is collapsed easily into an amorphous one by planetary ball milling, of which amount increases with an increase of grinding time. Only mullite phase except for anatase as an inherent impurity in kaolinite appeared in the sintered body of the mixtures with mixed grinding as relatively lower temperature 1523K, while corundum, cristobalite, and Al-Si spinel phases, besides mullite were formed in the sintered body of the mixture without mixed grinding. Therefore, the mixed grinding treatment is very effective to improve the homogeneous mixing and disp-ersion of the mixture of raw materials on a micro scale and to decrease the thermal decomposition tem-perature by crystal structure change of them so as to obatin direct preparation of mullite with high purity at relatively low temperature.

• International Journal of Highway Engineering
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• v.11 no.4
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• pp.127-132
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• 2009

This study presents the test results on the compaction characteristics of warm mix asphalt mixtures that include the additive in 3 different mixtures(hot mix asphalt, SBS and SMA). The tests were conducted to find out the compaction characteristics on the compactability with varying compaction time, different amount of the warm mix additive and lowering the compaction temperature. The Superpave gyratory compactor was used to find out the variation of the density when the number of the gyration is varied. A dense mixture and 3 different warm mix additives were employed to find the relationship between compactability and compaction time. The comparison of the compactability with lowering the temperature was conducted using dense mixture, SBS polymer modified mixture and stone matrix asphalt mixture(SMA). The difference of the density of warm mix asphalt mixtures was not found due to the lowering of compaction temperature when it was compared with the standard mixture and the warm mix showed the stable condition in density. In the mean time, depending upon the different warm mix additive and mixture, the difference of density and the variation trend of compaction is found to be existed and shows the relationship between these two variables.

• The Journal of Natural Sciences
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• v.3
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• pp.1-10
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• 1990

임계 이중 연계혼합물인 nitroethane 과 cyclohexane 혼합물의 임계온도 근처에서 전기적 감수율 (electric susceptibility)을 전기용량의 온도에 대한 변화를 측정하여 얻었다. 비선형 효과를 관측하기 위하여 자기유도 타원편광축 회전에 의한 제3차 비선형 광학감수율을 측정하여 임계지수를 구하였다. 임계지수는 0.34 였다.

• Journal of Energy Engineering
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• v.25 no.1
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• pp.48-55
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• 2016

The autoignition temperature (AIT) of a material is the lowest temperature at which the material will spontaneously ignite. The AIT is important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AITs of n-hexanol+p-xylene system by using ASTM E659 apparatus. The AITs of n-hexanol and p-xylene system which constituted binary system were $275^{\circ}C$ and $557^{\circ}C$, respectively. The experimental AITs of n-hexanol+p-xylene system system were a good agreement with the calculated AITs by the proposed equations with a few A.A.D.(average absolute deviation).

• The Korean Journal of Rheology
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• v.10 no.2
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• pp.65-73
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• 1998

본연구에서는poystyrene-block-poly (ethlene-co-butylene)-block-polystyrene(SEBS) 삼중블록 공중합체와 저분자량 단일중합체인 Hercotac 1149 (H1149)의 70/30 (w/w) 혼합물 의 미세상분리와 그동력학을 유변물성 측정법과 SAXS 실험을 통하여 연구해 보았다. 먼저 혼합물의 미세상분리 온도를 유변물성 측정법과 SAXS 실험을 통해 각각구한 다음 샘플을 미세상분리 온도보다 높은 온도에서 그이하의 온도로 급냉시킨 후 유변물성과 산란강도의 사간에 따른 변화로부터 미세상분리 동력학에 대한 정보를 구하였다. 이렇게 얻어진 데이터 를 Avrami 형태의 핵생성 성장(NG) 메커니즘으로 해석해 보았는데 최대산란강도 Imax 뿐만 아니라 저장 점탄성계수 G＇과 손실 점탄성계수 G＂의 시간에 따른 변화를 잘 예측할수 있 었다. 한편 서로다른 두 time-resolved 실험으로부터 Avrami 플롯을 그려서 구해진 Avrami 변수들은 같은 급냉 깊이에서는 서로 잘 일치함을 확인하였다. 반감기는 급냉 깊이가 증가 함에 따라 점차 감소하는 경향을 보였는데 이는 급냉 깊이가 클수록 미세상분리가 더 빨리 진행되고 있음을 보여주는 것이다. 또한 Avrami 지수는 급냉 깊이가 증가함에 따라 3에서 4로 급격히 변했는데 이로부터 급냉 깊이가 작을 때에는 70/30 (w/w) SEBS/H1149 혼합물 의 미세상분리가 불균일 핵생성 성장 메커니즘에 따라 진행되고 급냉 깊이가 더 커지면 미 세상분리가 스피노달 상분리 메커니즘으로 변하고 있음을 예측할수 있었다.

• Fire Science and Engineering
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• v.26 no.3
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• pp.85-90
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• 2012

The autoignition temperature (AIT) of a material is the lowest temperature at which the material will spontaneously ignite. The AIT is important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AITs of n-Decane+sec-Butanol system by using ASTM E659 apparatus. The AITs of n-Decane and sec-Butanol which constituted binary system were $212^{\circ}C$ and $447^{\circ}C$, respectively. The experimental AITs of n-Decane+sec-Butanol system were a good agreement with the calculated AITs by the proposed equations with a few A.A.D. (average absolute deviation).

• International Journal of Highway Engineering
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• v.13 no.4
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• pp.133-142
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• 2011

The objective of this study is to validate the number of gyrations of Superpave gyratory compactor(SGC) for compaction of hot-mix asphalt (HMA) and warm-mix asphalt(WMA) mixtures. Marshall compaction was also used for comparison purpose. The 13mm and 19mm aggregates of 1st class quality shape were used. A PG64-22 and a PG76-22 for HMA and a PG70-22 for WMA. Four compaction temperatures based on the suggested value were used for each binder using 100 gyrations for SGC and 75 blows per side for Marshall compactor. It was found that SGC compaction was somewhat better than Marshall compaction. The analysis of variance showed that two compactors were significantly different in air voids of 19mm mixtures at ${\alpha}=0.05$ level. The 13mm mixture did not show a significant statistical difference. When compacted at the temperature below a certain level, however, the compaction of two compactors were fond to be proor. Therefore, observing compaction temperature above the minimum level is important to secure proper compaction work. If the minimum temperatures were maintained, 100 gyrations, which was given for HMA of arterial road pavement by the Korean Guide, was found to be appropriate compaction, showing similar or better compaction work than 75 blows per side of Marshall compaction.

• Fire Science and Engineering
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• v.28 no.4
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• pp.44-49
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• 2014

The autoignition temperaturs (AIT) of solvent mixture is important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AIT and ignition delay time for Propionic acid and 3-Hexanone system by using ASTM E659 apparatus. The AITs of Propionic acid and 3-Hexanone which constituted binary system were $511^{\circ}C$ and $425^{\circ}C$, respectively. The experimental AIT of Propionic acid and 3-Hexanone system were a good agreement with the calculated AIT by the proposed equations with a few average absolute deviation (A.A.D.). And Propionic acid and 3-Hexanone system was shown the minimum autoignition temperature behavior (MAITB).

• The Korean Journal of Rheology
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• v.3 no.2
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• pp.124-134
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• 1991

세라믹 재료들을 성공적으로 사출성형하기 위한 적절한 사출조건을 얻기 위하여 그 동안 많은 실험을 하여 왔으나 게이트 크기가 미치는 영향에 대한 연구는 미진하였다. 본 연구에선 압출기를 사용하여 미세한 질화규소분말과 결합제시스템을 혼합하였으며 이러한 세라믹혼합물을 이용하여 사출압력, 보압시간, 보압, 배럴온도, 게이트의 형태와 크기 등을 변화시키면서 사출성형 실험을 수행하였다. 55%의 세라믹혼합물을 사출실험한 결과 적절한 게이트의 크기와 형태를 선택하고 105 MPa의 사출압력과 10초의 보압시간, 24$0^{\circ}C$의 배럴온 도와 같은 사출조건하에서 성형한다면 불완전 충전 체적수축과 젯팅현상을 최소화시킬수 있 어 성공적으로 인장시편과 굽힘시편을 성형할 수 있음을 알수있었다. 상용프로그램인 C-MOLD를 이용하여 사출조건과 게이트의 크기를 변화시키면서 혼합물의 유동특성을 해석 하였다. 유동해석 결과. 세라믹혼합물은 순수고분자보다 열전도도가 크고 비열이 작아서 고 화가 빨리 되므로 게이트의 크기는 사출압력, 배럴온도와 같은 사출조건과 더불어 중요한 사풀변수임을 예측할 수 있었다.

• Resources Recycling
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• v.10 no.1
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• pp.32-41
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• 2001

Bond shear strengths of recycled asphalt concrete were evaluated under different tack coat applications. Regardless of the new and old mixtures, the bond shear strengths at $30^{\circ}C$ were increased by 10-20% than those at 1$0^{\circ}C$. The bond shear strengths of recycled asphalt concrete without tack coat showed very low ones. These are the main reasons for the frequent longitudinal interface crack in the field. The effect of tack coat curing time on bond shear strengths was inferior to the tack coat construction temperature.