In order to understand the solidification behavior and microstructural evolution of the Al-Cu-Si ternary eutectic alloy system, changes of the microstructure of the Al-Cu-Si ternary eutectic alloy with different cooling rates were investigated. When the mold preheating temperature is 500℃, primary Si and Al2Cu dendrites are observed, with (α-Al+Al2Cu) binary eutectic and needle-shaped Si subsequently observed. In addition, even when the mold preheating temperature is 300℃, primary Si and Al2Cu dendrites can be observed, and both (α-Al+Al2Cu+Si) areas observed and areas not observed earlier appear. When the mold preheating temperature is 150℃, bimodal structures of the binary eutectic (α-Al+Al2Cu) and ternary eutectic (α-Al+Al2Cu+Si) are observed. When the preheating temperature of the mold is changed to 500℃, 300℃, and 150℃, the greatest change is in the Si phase, and upon reaching the critical cooling rate, the ternary eutectic of (α-Al+Al2Cu+Si) forms. If the growth of the Si phase is suppressed upon the formation of (α-Al+Al2Cu+Si), the growth of both Al and Cu is also suppressed by a cooperative growth mechanism. As a result of analyzing the Al-27wt%Cu-5wt%Si ternary eutectic alloy with a different alloy design simulation programs, it was confirmed that different results arose depending on the program. A computer simulation of the alloy design is a useful tool to reduce the trial and error process in alloy design, but this effort must be accompanied by a task that increases reliability and allows a comparison to microstructural results derived through actual casting.
The development of non-flammable all-solid-state batteries (ASSLBs) has become a hot topic due to the known drawbacks of commercial lithium-ion batteries. As the possibility of applying sulfide solid electrolytes (SSEs) for electric vehicle batteries increases, efforts for the low-cost mass-production are actively underway. Until now, most studies have used high-energy mechanical milling, which is easy to control composition and impurities and can reduce the process time. Through this, various SSEs that exceed the Li+ conductivity of liquid electrolytes have been reported, and expectations for the realization of ASSLBs are growing. However, the high-energy mechanical milling method has disadvantages in obtaining the same physical properties when mass-produced, and in controlling the particle size or shape, so that physical properties deteriorate during the full process. On the other hand, wet chemical synthesis technology, which has advantages in mass production and low price, is still in the initial exploration stage. In this technology, SSEs are mainly manufactured through producing a particle-type, solution-type, or mixed-type precursor, but a clear understanding of the reaction mechanism hasn't been made yet. In this review, wet chemical synthesis technologies for SSEs are summarized regarding the reaction mechanism between the raw materials in the solvent.
The guiding research question of this paper is to discover 'why the UK could not develop a general structure in which transnational corporations were born during the end of the 19th ~ beginning of the 20th century like other countries'. In response to this question, although acknowledging its imperfections, the author would like to explore the causality in the context of 'Social Construction' which is reflected in the attributes of British society. As such, researchers are strongly recommended to take into account the actors' interests and the increased value effect of events which is driven by control power. This paper concludes that: firstly, not only was contempt for industrial capitalism prevalent in British society, the British government was unable to recognize the necessity of promoting policies for the development of transnational corporation. In addition, the increase in the clout of commercial-financial capitalists in the city of London along with the expansion of gentlemanly elites interfered with the transnationality of British companies. Secondly, the foundation of the political and economic structures in the UK experienced continuity and challenge simultaneously. Since the 1850's, the British social structure has been progressively characterized by the strengthening power of the commercial-financial elites in London, which resulted not in the transnationality of manufacturing but that of financial services. Finally, the configuration of the social network driven by the British elites consists of the actors' interests and control power in association with severance and connection. Unlike the complementarity of interests, in the initial stage, intended connection based on voluntary motivation between gentries and commercial-financial elites occurred in terms of control power. However, ultimately, the holding of power was transferred to the commercial-financial elites excluding the industrial capitalists and resulted in the reconfiguration of the social network.
In the United States, a number of ocean outfalls discharge primary treated effluent into deep sea water and contribute for more efficient wastewater treatment. The long multiport diffuser connected by long pipe from a treatment plant discharge wastewater into deep water due to the steep slope of the sea bed. However, Plume discharged from the diffuser can have significant impacts on coastal communities and possibly immediate consequence on public health. Therefore, there have been growing interests about the dynamics of plume in the vicinity of the ocean outfalls. It is expected that the ocean outfall should be considered for more efficient and reliable wastewater treatments as soon as possible around coastal area in South Korea. A number of studies of plume ynamics have used various models to predict plume behavior. However, in many cases, the calculated values of plume behavior are in significantly poor agreement with realistic values. Therefore, in this study, it is recommended that improvements should be made in the application of the plume model to more simulate the actual discharge characteristics and ocean conditions. It should be noted that input parameters in plume models reflect realistic ocean conditions like waves as well as currents. In this study, as one of the new parameters, current and long wave-influenced plume rise and initial dilution have been taken into account by using simple linear wave theory under some specific assumptions for more reliable plume behavior description. Among the improved plume models approved by EPA (Environmental Protection Agency), the RSB(Roberts-Snyder-Baurngartner) and UM(Updated Merge) models were chosen for the calculation of plume behavior, and the variation calculated by both models on the basis of long period wave was compared in terms of plume rise and initial dilution.
Journal of the Society of Cosmetic Scientists of Korea
/
v.49
no.2
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pp.127-139
/
2023
In this study, minoxidil, which is well known as a pharmaceutical raw material, and diaminopyrimidine oxide (DAO), which is a cosmetic raw material, were used as active ingredients to evaluate the physical properties of niosomes and compare the skin penetrations of artificial skin. To prepare niosomes of the size of nanoparticles, a high pressure homogenization method was used, and physical properties were evaluated with a zetasizer. The particle size of the noisome including the active ingredient was measured to be 99 to 123 nm according to HLB, and the zeta potential was measured in the range of -60 to -81 mV. Through DSC (differential scanning colorimetry), it was confirmed that minoxidil, a crystalline component, was uniformly dissolved in an amorphous state in niosomes. In order to confirm and compare skin penetration, it was measured by the in vitro Franz diffusion cell method, and the niosome formulation showed 3.4 times higher penetration for minoxidil and 11.1 times higher penetration for DAO than the control gel formulation. In addition, when comparing the skin penetration of minoxidil niosome and DAO niosome, a similar trend was shown, and the penetration amount of DAO was relatively high. The shapes of the niosome formulations with different HLB values were observed using Cryo-TEM, and it was confirmed that vesicles were formed in all of them and that they were intermediate between SUV (small unilamella vesicle) and LUV (large unilamella vesicle). Through this study, minoxidil, an effective drug for hair loss, and DAO, a cosmetic raw material, can be effectively delivered to the skin by encapsulating them in a noisome formulation.
KSCE Journal of Civil and Environmental Engineering Research
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v.28
no.1A
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pp.125-133
/
2008
According to longer and longer span, dynamic instability of stay cable should be prevented. Dynamic instability occurs mainly symmetric 1st mode and antisymmetric 1st mode in stay cable. Especially symmetric 1st mode has a lot of influence on sag. Therefore fundamental frequency of stay cable is different from that of taut sting. Irvine, Triantafyllou, Ahn etc. analyzed dynamic behavior of taut cable with sag through analytical technical and their researches give important results for large bounds of Irvine parameter. But each research shows mutually different values out of characteristic (cross-over or mode-coupled) point and each solution of frequency equations of all researchers can be very difficultly found because of their very high non-linearity. Presented study focuses on fundamental frequency of stay cable. Generalized mechanical energy with symmetric 1st mode vibration shape satisfied boundary conditions is evolved by Rayleigh-Ritz method. It is possible to give linear analytic solution within characteristic point. Error by this approach shows only below 3% at characteristic point against existing researches. And taut cable don't exceed characteristic point. I.e. high accuracy, easy solving techniques, and a little bit limitations. Therefore presented study can be announced that it is good study ergonomically.
The Journal of the Convergence on Culture Technology
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v.9
no.5
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pp.133-140
/
2023
The origin of texts we refer to as literary or artistic may be imagination, but many are based on experiences. In fact, experiences can be the source of artistic imagination since imagination often builds upon experiences. Therefore, the act of verbalizing human experiences using them as raw material can become a great form of art. Transforming past experiences into stories and infusing them with vitality inevitably requires a creative process of reconstruction, which is essentially a literary process. As such, 'Personal Narrative' holds significance as a literary process that weaves facts into stories and shapes them into forms. Individual experiences are stored as personal memories, and these 'personal memories' continuously generate stories. Collections of individual stories are stored as multiple memories, which gradually form 'collective memories' with distinct social and cultural inclinations through the passage of time and invisible yet potent societal and cultural censorship. The problem lies in the fact that individuals may tend to align their own memories with the inclinations of collective memory rather than simply recalling what they personally experienced. In the context of actual history, personal memories and collective memories communicate with each other, producing non-fictional content close to reality and sometimes manifesting as fiction content enriched with imagination. 'Personal Narrative' holds a significant genre as one genre of non-fiction content within our culture.
Journal of the Korean Crystal Growth and Crystal Technology
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v.33
no.5
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pp.167-173
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2023
Li3V2(PO4)3 and Li3V2(PO4)3/C composite with single phase monoclinic structure for the cathode materials are successfully synthesized by direct co-precipitation method using N2H4·H2O as the reducing agent and alginic acid as the carbon source, and their electrochemical properties were compared. The particles with approximately 1~2 ㎛ size and the uniform spherical-like morphology of the narrow particle size distribution were obtained. In addition, the residual carbon can also improve the electrical conductivity. The Li3V2(PO4)3/C composite has improved initial specific discharge capacity and excellent cycle characteristics to maintain capacity stably than Li3V2(PO4)3. The results indicate that the reducing agent and carbon composite can affect the good crystallinity and electrochemical performance of the cathode materials.
Journal of the Korea institute for structural maintenance and inspection
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v.28
no.3
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pp.47-58
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2024
This study were conduced experimentally to analyze the heat-generating performance, flexural strength, and microstructure of conductive mortar mixed with micro steel fiber and multi-wall carbon nanotube (MWCNT). In the conductive mortar heat-generating performance and flexural strength tests, the mixing concentration of MWCNT was selected as 0.0wt%, 0.5wt%, and 1.0wt% relative to the weight of cement, and micro steel fibers were mixed at 2.0vol% relative to the volume. The performance experiments were conducted with various applied voltages (DC 10V, 30V, 60V) and different electrode spacings (40 mm, 120 mm) as parameters, and the flexural strength was measured at the curing age of 28 days and compared and analyzed with the normal mortar. Furthermore, the surface shape and microstructure of conductive mortar were analyzed using a field emission scanning electron microscope (FE-SEM). The results showed that the heat-generating performance improved as the mixing concentration of MWCNT and the applied voltage increased, and it further improved as the electrode spacing became narrower. However, even if the mixing concentration of MWCNT was added up to 1.0 wt%, the heat-generating performance was not significantly improved. As a result of the flexural strength test, the average flexural strength of all specimens except the PM specimen and the MWCNT mixed specimens was 4.5 MPa or more, showing high flexural strength due to the incorporation of micro steel fibers. Through FE-SEM image analysis, Through FE-SEM image analysis, it was confirmed that a conductive network was formed between micro steel fibers and MWCNT particles in the cement matrix.
Donghyeon Lee;Joung-Man Park;Hyung Mi Lim;Dong-Jun Kwon
Composites Research
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v.37
no.3
/
pp.204-208
/
2024
De-icing/anti-icing fluid is essential for removing ice formation on aircraft. It chemically removes ice using organic solvents, which can cause damage to the topcoat surface in the process. In this study, glycol-based deicing/anti-icing fluid was used to remove ice, and the resulting damage to the topcoat was examined. USB microscope was used to observe the formation and growth of ice, while a confocal microscope was employed to observe the surface morphology after treatment with de-icing/anti-icing fluid. Additionally, coating thickness measurements and Fourier transform infrared (FT-IR) analysis were conducted to investigate the physical and chemical changes on the surface. The repeated application of de-icing/anti-icing fluid showed a reduction in the ice formation rate and an increase in the growth rate. Damage during the pressurization process and surface damage to the polyurethane topcoat caused by ethylene glycol were observed during the de-icing process. Although no chemical changes were detected, the analysis revealed that surface uniformity decreased, with physical damage such as cracks and undulations forming on the surface. It was confirmed that while de-icing/anti-icing fluid is effective in removing ice, it also causes surface damage.
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