• Title/Summary/Keyword: 형광변수

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An Experimental Analysis on the Behavior Characteristics of Evaporative Impinging Spray (증발 충돌분무의 거동특성에 관한 실험연구)

  • Yeom, J.K.
    • Journal of Power System Engineering
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    • v.14 no.2
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    • pp.16-21
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    • 2010
  • 분사된 연료의 미립화(atomization), 증발(evaporation), 그리고 혼합기형성과정(mixture formation process)이 디젤엔진의 착화 및 연소특성에 영향을 미치기 때문에, 디젤엔진 내에 분사된 연료의 구조해석으로부터 일련의 과정, 즉 고압분사, 분열(breakup), 미립화, 그리고 주위기체의 난류 도입(entrainment)에 관한 연구$^{1-3)}$는 꾸준히 행해져왔다. 본 연구는 증발디젤분무의 구조해석으로부터 디젤충돌분무의 혼합기형성과정을 조사한다. 주위기체의 밀도는 실험변수로서 선택하였고, $5.0kg/m^3$에서 $12.3kg/m^3$까지 변화시켰다. 그리고 소형고속디젤엔진에 있어서 연료분사초기의 상태의 고온 고압 설정이 가능한 정적용기를 사용했다. 주위 온도와 연료분사압력은 각각 700K 및 72MPa로 일정하게 유지했다. 충동증발분무의 액상과 기상의 이미지는 엑시플렉스형광법으로 동시 계측하였다. 실험결과로서 주위기체의 밀도가 높을수록 충돌분무의 선단도 달거리가 주위기체의 항력으로 인하여 감소하였다.

Growing and Luminous Characterization of ZnGa2O4:Mn Thin Film Deposited by RF Magnetron Sputtering (RF 스퍼터링 방법에 의한 ZnGa2O4:Mn 박막의 성장거동과 발광특성)

  • 정승묵;김영진
    • Journal of the Korean Ceramic Society
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    • v.40 no.7
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    • pp.652-656
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    • 2003
  • The green emitting phosphor, BnGa$_2$O$_4$:Mn thin films with spinel structure were deposited by rf magnetron sputtering at various Ar/O$_2$ ratios. Thin film phosphors were heat-treated in air and $N_2$+vacuum atmosphere, respectively. Effects of Ar/O$_2$ ratios and annealing conditions on the structural and photoluminescence (PL) and cathodeluminescence (CL) properties were investigated. Luminous properties were more improved by inhibiting the films from contacting with oxygen during heat treatment.

Analysis of Two-Dimensional Fluorescence Spectra in Biotechnological Processes by Artificial Neural Networks II - Process Modeling using Backpropagation Neural Network - (인공신경망에 의만 생물공정에서 2차원 영광스펙트럼의 분석 II - 역전파 신경망에 의한 공정의 모델링 -)

  • Lee Kum-Il;Yim Yong-Sik;Sohn Ok-Jae;Chung Sang-Wook;Rhee Jong Il
    • KSBB Journal
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    • v.20 no.4
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    • pp.299-304
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    • 2005
  • A two-dimensional (2D) spectrofluorometer was used to monitor various fermentation processes with recombinant E. coli for the production of 5-aminolevulinic acid (ALA). The whole fluorescence spectral data obtained during a process were analyed using artificial neural networks, i.e. self-organizing map (SOM) and feedforward backpropagation neural network (BPNN).Based on the classified fluorescence spectra a supervised BPNN algorithm was used to predict some of the process parameters. It was also shown that the BPNN models could elucidate some sections of the process performance, e.g. forecasting the process performance.

Analysis of Two-Dimensional Fluorescence Spectra in Biotechnological Processes by Artificial Neural Networks I - Classification of Fluorescence Spectra using Self-Organizing Maps - (인공신경망에 의한 생물공정에서 2차원 형광스펙트럼의 분석 I - 자기조직화망에 의한 형광스펙트럼의 분류 -)

  • Lee Kum-Il;Yim Yong-Sik;Kim Chun-Kwang;Lee Seung-Hyun;Chung Sang-Wook;Rhee Jong Il
    • KSBB Journal
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    • v.20 no.4
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    • pp.291-298
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    • 2005
  • Two-dimensional (2D) spectrofluorometer is often used to monitor various fermentation processes. The change in fluorescence intensities resulting from various combinations of excitation and emission wavelengths is investigated by using a spectra subtraction technique. But it has a limited capacity to classify the entire fluorescence spectra gathered during fermentations and to extract some useful information from the data. This study shows that the self-organizing map (SOM) is a useful and interpretative method for classification of the entire gamut of fluorescence spectral data and selection of some combinations of excitation and emission wavelengths, which have useful fluorometric information. Some results such as normalized weights and variances indicate that the SOM network is capable of interpreting the fermentation processes of S. cerevisiae and recombinant E. coli monitored by a 2D spectrofluorometer.

Photoluminescent Properties of YAG:Ce3+ Phosphors for the application of white LED (백색 LED 응용을 위한 YAG:Ce3+ 형광체의 광학특성)

  • Jang, Bum-Sik;Park, Joo-Seok;Yoo, Soon-Jae;Ahn, Young-Soo;Kim, Hong-Soo;Kim, Joon-Soo;Han, Seong-Ok;Cho, Chul-Hee;Yoo, Yoon-Jong;Kim, Si-Kyung;Han, Moon-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.04a
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    • pp.181-184
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    • 2003
  • GaN계 청색 여기용 광원으로 최적인 $Y_{3}AI_{5}O_{12}:Ce$계 phosphor를 고상반응으로 제조하여 white LED용 yellow 형광체로 신뢰성을 검토하였다. 출발시료는 metal hydrous oxide로 합성한 분말에 활성제로서 $Ce^{3+}$ 이온의 농도를 변화시키면서 로내의 온도와 시간을 변수로 하여 형광체를 제조하였다. 그 결과 $1650^{\circ}C$에서 2시간 소성시킨 분말의 경우, 입자 크기가 $3{\mu}m$이하인 순수 YAG 형광체를 얻을 수 있었으며 $Ce^{3+}$이온농도를 변화시킨 결과 0.03~0.05mol% 일 때가 가장 우수하여 해외제품수준을 능가하는 우수한 발광특성을 나타내었다. 이때 CIE1931 색좌표 값은 x=0.385, y=0.433으로서 green yellow 색을 나타내었다.

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Production of Glutathione by yeast and Process Monitoring (효모에 의한 글루타치온의 생산과 공정 모니터링)

  • 김춘광;이종일
    • KSBB Journal
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    • v.19 no.3
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    • pp.192-199
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    • 2004
  • In this work the production of glutathione (GSH) by yeast Saccharomyces cerevisiae and the monitoring of the process were studied. In shaking culture the production of GSH was high at initial pH value of 4 and at temperature of 30$^{\circ}C$. But when L-cysteine was added to the culture medium at the beginning of the cultivation, the productivity of GSH was low. In case 0,5% (v/v) of L-cysteine, glycine and glutamic acid were introduced to the culture medium in the exponential cell growth phase, high concentration of GSH (about 90 mg/L) was produced in the bioreactor. A fed-batch operation with stepwise glucose feeding strategy allowed to produce 102 mg/L of GSH. The cultivation processes were on-line monitored by a 2-dimensional fluorescence sensor. A few off-line data such as cell growth, cystein concentration, phosphate concentration and GSH productivity could be well correlated to the fluorescence intensity of some combinations of excitation and emission wavelengths.

Evaluation through Photochemical Response Analysis on Growth Enhancing Effect of Decomposed Hatchery Waste Egg for Red Pepper (광화학적 반응 분석을 통한 부화장 폐달걀 분해 액비의 고추 생장촉진효과 평가)

  • Yoo, Sung Yung;Kang, Hong Gyu;Yoo, Jae Hong;Lee, Jeon Gyu;Shim, Myoung Yong
    • Korean Journal of Environmental Biology
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    • v.34 no.3
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    • pp.161-168
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    • 2016
  • In this study, growth enhancing effect of hatchery waste egg decomposed liquid fertilizer in pepper plant cultivation through chlorophyll fluorescence (O-J-I-P) analysis. In a whole growth period, egg decomposed fertilizer treated pepper grew well than non treated plant, though it was not statistically significantly different. Amount of chlorophyll fluorescence of non treated plant was higher thant that of fertilizer treated plant. It is determined that eventually lead to increased photosynthesis. In this study, six parameters, Fo, ABS/RC, RC/ABS, TRo/RC, DI0/RC, and DF Total ABS were the important factors represent efficiency of photochemical responses of pepper plant treated with hatchery waste egg decomposed fertilizer.

Residue Analysis of Quinclorac in Soil by Supercritical Fluid Extraction and Fluorogenic Derivatization Coupled with High Performance Liquid Chromatography (초임계추출과 형광유도체를 이용한 HPLC 에서의 Quinclorac 의 토양중 잔류분석)

  • Kim, Yong-Whan
    • Applied Biological Chemistry
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    • v.40 no.5
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    • pp.442-446
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    • 1997
  • A new analytical method was developed by HPLC after supercritical fluid extraction and fluorogenic derivatization for the determination of quinclorac (3,7-dichloro-8-quinoline carboxylic acid) in soil. The graminicide quinclorac was extracted from soil by supercritical fluid extraction. Supercritical carbon dioxide at 7000 psi $(80^{\circ}C)$ modified with 30% of methanol extracted quinclorac from soil samples at the level of $0.1ng\;g^{-1}$ with 96% recovery. Extracted quinclorac was determined by HPLC as a fluorescent derivative. Derivatization was made with 4-bromomethyl-7-methoxycoumarin (4-Br-Mmc) using 18-crown-6-ether as a catalyst. The conversion was completed within 30 min and the limit of detection was 0.5 ppb to prove that the procedure could be used in the residue analysis of the pesticides containing carboxylic acid group.

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Multi-Case Analysis on Long-Tail Success Laws (롱테일 성공 법칙에 관한 사례 연구)

  • Choi, Hyung-Kwang;Kim, Byoung-Ki;Oh, Jae-Suhp
    • 한국IT서비스학회:학술대회논문집
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    • 2008.11a
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    • pp.383-386
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    • 2008
  • 본 논문에서는 성공적인 롱테일을 위한 가설을 생성하고 시사점을 제시하고자 한다. 이를 위해서 롱테일 9가지 법칙을 중심으로 성공과 실패 사례들을 분석하여 롱테일의 성공에 영향을 미치는 변수를 도출하고 이를 귀납 학습을 통해 가설을 생성한 후에 그 의미를 해석하여 롱테일 전략을 구사하고자 하는 기업과 실무 담당자 및 관련분야의 연구자에게 시사점을 주고자 한다.

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Optimization of Anti-glycation Effect of ʟ-Carnitine, Pyridoxine Hydrochloride and ᴅʟ-α-Tocopheryl Acetate in an Infant Formula Model System Using Response Surface Methodology (ʟ-Carnitine, pyridoxine hydrochloride, ᴅʟ-α-tocopheryl acetate를 이용한 분유모델시스템의 마이얄반응생성물 저감화 조건 최적화)

  • Jung, Hye-Lim;Nam, Mi-Hyun;Hong, Chung-Oui;Pyo, Min-Cheol;Oh, Jun-Gu;Kim, Young Ki;Choi, You Young;Kwon, Jung Il;Lee, Kwang-Won
    • Korean Journal of Food Science and Technology
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    • v.47 no.1
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    • pp.95-102
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    • 2015
  • The Maillard reaction is a non-enzymatic reaction between amino and carbonyl groups. During milk processing, lactose reacts with milk protein through this reaction. Infant formulas (IFs) are milk-based products processed with heat-treatments, including spray-drying and sterilization. Because IFs contain higher Maillard reaction products (MRPs) than breast milk, formula-fed infants are subject to higher MRP exposure than breast milk-fed ones. In this study, we investigated the optimization of conditions for minimal MRP formation with the addition of $\small{L}$-carnitine ($\small{L}$-car), pyridoxine hydrochloride (PH), and $\small{DL}$-${\alpha}$-tocopheryl acetate (${\alpha}$-T) in an IF model system. MRP formation was monitored by response surface methodology using fluorescence intensity (FI) and 5-hydroxymethylfurfural (HMF) content. The optimal condition for minimizing the formation of MRPs was with $2.3{\mu}M$ $\small{L}$-car, $15.8{\mu}M$ PH, and $20.6{\mu}M$ ${\alpha}$-T. Under this condition, the predicted values were 77.4% FI and 248.7 ppb HMF.