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Effect of composition on the structural and thermal properties of TiZrN thin film (TiZrN 박막의 조성이 구조적 특성 및 열적 특성에 미치는 영향)

  • Choi, Byoung Su;Um, Ji Hun;Seok, Min Jun;Lee, Byeong Woo;Kim, Jin Kon;Cho, Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.1
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    • pp.37-42
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    • 2021
  • The effect of chemical composition on the structural and thermal properties of TiZrN thin films was studied. As the Zr fraction in the deposited TixZr1-xN (x = 0.87, 0.82, 0.7, 0.6, and 0.28) increased, microstructural changes consisted of reduction in the grain size and a gradual transition from columnar structure to granular structure were observed. In addition, it was also confirmed that a gradual crystal phase transition from TiN to TiZrN has occurred as the Zr fraction increased up to 0.4. After heat treatment at 900℃, Ti0.82Zr0.18N and Ti0.7Zr0.3N layers were converted to a form in which rutile phase TiO2 and TiZrO4 oxides coexist, while Ti0.6Zr0.4N layer was converted to TiZrO4 oxide. Among the five compositions of TiZrN films, the Ti0.6Zr0.4N showed the best high temperature stability and produced a significant enhancement in the thermal oxidation resistance of Inconel 617 through suppressing the surface diffusion of Cr caused by thermal oxidation of the Inconel 617 substrate.

Reconfiguration of Physical Structure of Vegetation by Voxelization Based on 3D Point Clouds (3차원 포인트 클라우드 기반 복셀화에 의한 식생의 물리적 구조 재구현)

  • Ahn, Myeonghui;Jang, Eun-kyung;Bae, Inhyeok;Ji, Un
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.40 no.6
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    • pp.571-581
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    • 2020
  • Vegetation affects water level change and flow resistance in rivers and impacts waterway ecosystems as a whole. Therefore, it is important to have accurate information about the species, shape, and size of any river vegetation. However, it is not easy to collect full vegetation data on-site, so recent studies have attempted to obtain large amounts of vegetation data using terrestrial laser scanning (TLS). Also, due to the complex shape of vegetation, it is not easy to obtain accurate information about the canopy area, and there are limitations due to a complex range of variables. Therefore, the physical structure of vegetation was analyzed in this study by reconfiguring high-resolution point cloud data collected through 3-dimensional terrestrial laser scanning (3D TLS) in a voxel. Each physical structure was analyzed under three different conditions: a simple vegetation formation without leaves, a complete formation with leaves, and a patch-scale vegetation formation. In the raw data, the outlier and unnecessary data were filtered and removed by Statistical Outlier Removal (SOR), resulting in 17%, 26%, and 25% of data being removed, respectively. Also, vegetation volume by voxel size was reconfigured from post-processed point clouds and compared with vegetation volume; the analysis showed that the margin of error was 8%, 25%, and 63% for each condition, respectively. The larger the size of the target sample, the larger the error. The vegetation surface looked visually similar when resizing the voxel; however, the volume of the entire vegetation was susceptible to error.

A Study on the 「MaengHoEum」 of Mokjae Lee Samhwan (목재(木齋) 이삼환(李森煥)의 「맹호음(猛?吟)」 연구(硏究))

  • Yoon, Jaehwan
    • (The)Study of the Eastern Classic
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    • no.70
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    • pp.157-183
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    • 2018
  • Mokjae Lee Samhwan's "MaengHoEum" is the three poems of the Chinese quatrain of 5word 7poetry created according to the previous age. This poem is distinguished from the poem of the general "MaengHoHaeng" series because of it was created in the form of modern-style poetry of series, not a poetry of 5word or 7word or length phrase in a poem. The "MaengHoEum" of MokJae seems to have been built around 1801year when he was 73 years old. Therefore, his "MaengHoEum" can be called an allegory poetry or a society poetry and his poetry can be said that it was created under the criticism of the corrupt political power of the contemporary society, and the 'fierce tiger' which appeared in his poem refers to the factions of Noron Byek line which was the ruling power at that time. However, if you look at the "MaengHoEum" of MokJae, you will see a criticism of the real world, but the feeling is not intense or the description is not concrete. Although his poetry depicts the absurdity of the present reality, but he does not show positive criticism of reality or strong resistance. This characteristic, which can be seen in his poem "MaengHoEum", is the result of the study he pursued for the his life and is thought to be due to the weight of reality. The contradictions of the time of the Mokjae were never silent to him, but on the other hand he could not reveal his own struggle on the surface of the poem. Between his descendants, influenced by his actions, and the stinging gaze watching him, he had no choice but to end his feelings internally.

A Study of Moth-eye Nano Structure Embedded Optical Film with Mitigated Output Power Loss in PERC Photovoltaic Modules (PERC 태양전지 모듈의 출력저하 방지를 위한 모스아이(Moth-eye) 광학필름 연구)

  • Oh, Kyoung-suk;Park, Jiwon;Choi, Jin-Young;Chan, Sung-il
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.4
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    • pp.55-60
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    • 2020
  • The PERC photovoltaic (PV) modules installed in PV power plant are still reports potential-induced degradation (PID) degradation due to high voltage potential differences. This is because Na+ ions in the cover glass of PV modules go through the encapsulant (EVA) and transferred to the surface of solar cells. As positive charges are accumulated at the ARC (SiOx/SiNx) interface where many defects are distributed, shunt-resistance (Rsh) is reduced. As a result, the leakage current is increased, and decrease in solar cell's power output. In this study, to prevent of this phenomenon, a Moth-eye nanostructure was deposited on the rear surface of an optical film using Nano-Imprint Lithography method, and a solar mini-module was constructed by inserting it between the cover glass and the EVA. To analyze the PID phenomenon, a cell-level PID acceleration test based on IEC 62804-1 standard was conducted. Also analyzed power output (Pmax), efficiency, and shunt resistance through Light I-V and Dark I-V. As a result, conventional solar cells were decreased by 6.3% from the initial efficiency of 19.76%, but the improved solar cells with the Moth-eye nanostructured optical film only decreased 0.6%, thereby preventing the PID phenomenon. As of Moth-eye nanostructured optical film, the transmittance was improved by 4%, and the solar module output was improved by 2.5%.

The Determination of Anaerobic Biodegradability and Organic Fractionation of Agricultural Byproducts by Biochemical Methane Potential Assay Using Double First-Order Kinetic Model (반응속도 모델을 적용한 농업부산물의 혐기성 유기물분해율과 메탄생산잠재량 분석)

  • Shin, Kook-Sik;Yoon, Young-Man
    • Journal of the Korea Organic Resources Recycling Association
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    • v.29 no.4
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    • pp.55-65
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    • 2021
  • This study investigated methane productions and a degradation rate of organic matters by German standard method, VDI4630 test. In this study, 11 waste biomasses from agricultural fields were selected for the investigation. The objective of this study was to estimate a distribution of organic matters by using the Double first-order kinetics model in order to calculate the rate of biodegradable organic matters which degrade rapidly in the initial stage and the persistently biodegradable organic matters which degrade slowly later. As a result, all the biomasses applied in this study showed rapid decomposition in the initial stage. Then the decomposition rate began to slow down for a certain period and the rate became 10 times slower than the initial decomposition rate. This trend of decomposition rate changes is typical conditions of biomass decompositions. The easily degradable factors (k1) were raged between 0.097~0.152 day-1 from vegetable crops and persistent degradable factor (k2) were 0.002~0.024 day-1. Among these results, greater organic matter decomposition rates from VDI4630 had greater k1 values (0.152, 0.144day-1) and smaller k1 values (0.002, 0.005day-1) from cucumbers and paprika. In a meanwhile, radishes and tangerine rinds which had low decomposition rates showed 0.097 and 0.094 day-1 of k1 values and decomposition rates seems to affect k1 values.

Consideration of Engineering Strength and Filling Characteristics for Rubble-Ground Modification Method with Grout Injection (그라우트 주입식 사석기초 보강 공법의 개량체 강도 및 충전성에 대한 실험적 검토)

  • Kim, Hyeong-Ki;Han, Jin-Gyu;Kim, Jeong Eun;Ryu, Yong-Sun;Nguyen, Anh Dan;Kang, Gyeong-O;Kim, Young-Sang
    • Journal of the Korean Geotechnical Society
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    • v.38 no.5
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    • pp.47-59
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    • 2022
  • A series of experiments were performed to investigate the design and application of a rubble-ground modification method with grout injection. A small-sized injection machine was designed, and the grouts with various mix proportions were injected into 25 mm aggregate using the designed small-sized injection machine. With the compressive strength of the grout ranging from 20 to 80 MPa, the uniaxial compressive strength of the grout-filling bodies with clean gravels was higher than 1/6th of the strength of grouts themselves. However, this fraction may reduce depending on the interface conditions. The erosion resistance of the hardened grout was evaluated, and it was determined that the grout with a strength greater than 15 MPa did not require erosion consideration. Moreover, a full-scale injection test was performed for 25 cm-sized rubbles in cages with a diameter greater than 1 m and a height of 1.2 m to evaluate the filling characteristics of the grout. Results from this test indicated that the grout flowability sensitively influenced the filling characteristics.

Analysis of Electrochemical Properties of Sulfide All-Solid-State Lithium Ion Battery Anode Material Using Amorphous Carbon-Removed Graphite (비정질 탄소가 제거된 흑연을 이용한 황화물계 전고체 리튬이온전지 음극소재 전기화학적 특성 분석)

  • Choi, Jae Hong;Oh, Pilgun
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.58-63
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    • 2022
  • Graphite has been used as an anode material for lithium-ion batteries for the past 30 years due to its low de-/lithiation voltage, high theoretical capacity of 372 mAh/g, low price, and long life properties. Recently, all-solid-state lithium-ion batteries (ASSLB), which are composed of inorganic solid materials with high stability, have received great attention as electric vehicles and next-generation energy storage devices, but research works on graphite that works well for ASSLB systems are insufficient. Therefore, we induced the performance improvement of ASSLB anode electrode graphite material by removing the amorphous carbon present in the carbon material surface, acting as a resistive layer from the graphite. As a result of X-ray diffraction (XRD) analysis using heat treated graphite in air at 400, 500, and 600 ℃, the full width at half maximum (FWHM) at (002) peak was reduced compared to that of bare graphite, indicating that the crystallinity of graphite was improved after heat treatment. In addition, the discharge capacity, initial coulombic efficiency (ICE) and cycle stability increased as the crystallinity of graphite increased after heat treatment. In the case of graphite annealed in air at 500 ℃, the high capacity retention rate of 331.1 mAh/g and ICE of 86.2% and capacity retention of 92.7% after 10-cycle measurement were shown.

Evaluation of Freeze-Thaw Damage on Concrete Using Nonlinear Ultrasound (초음파의 비선형 특성을 이용한 콘크리트 동결융해 손상 평가)

  • Choi, Ha-Jin;Kim, Ryul-Ri;Lee, Jong-Suk;Min, Ji-Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.4
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    • pp.56-64
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    • 2021
  • Leakage due to deterioration and damage is one of the major causes of volume change by freezing and thawing, and it leads micro-cracking and surface scaling in concrete structures. The deterioration of damaged concrete accelerates with the chloride attack. Thus, in the detailed guidelines for facility performance evaluation (2020), the quality of cover concrete and the freeze-thaw (FT) repetition cycle were newly suggested for concrete durability assessment. The quality of cover concrete should be evaluated by the rebound hammer test and the FT repetition cycle should be also considered in the deterioration environmental assessment. This study suggested the application of fast dynamic based nonlinear ultrasound method to monitor initial micro-scale damage under freezing and thawing environment. Concrete specimens were fabricated with different water-cement ratios (40%, 60%) and air contents (1.5% and 3.0%). The compressive strength, rebound number, relative dynamic modulus, and nonlinear ultrasound were measured with different FT cycles. The scanning electron microscopy was also performed to investigate the micro-scale FT damage. As a result, both the rebound number and the relative dynamic modulus had difficulty to detect early damage but the proposed method showed a potential to detect initial micro-scale damage and predict the FT resistance performance of concrete.

Electrical and Optical Properties of ITO Thin Films with Various Thicknesses of SiO2 Buffer Layer for Capacitive Touch Screen Panel (정전용량식 터치스크린 패널을 위한 SiO2 버퍼층 두께에 따른 ITO 박막의 전기적 및 광학적 특성)

  • Yeun-Gun, Chung;Yang-Hee, Joung;Seong-Jun, Kang
    • The Journal of the Korea institute of electronic communication sciences
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    • v.17 no.6
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    • pp.1069-1074
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    • 2022
  • In this study, we prepared ITO thin films on the Nb2O5/SiO2 double buffer layer and investigated electrical and optical properties according to the change of SiO2 buffer layer thickness (40~50nm). The ITO thin film fabricated on the Nb2O5/SiO2 double buffer layer exhibited a broad surface roughness with a small value ranging of 0.815 to 1.181nm, and the sheet resistance was 99.3 to 134.0Ω/sq. It seems that there is no problem in applying the ITO thin film to a capacitive touch screen panel. In particular, the average transmittance in the short-wavelength (400~500nm) region and the chromaticity (b*) of the ITO thin film deposited on the Nb2O5(10nm)/SiO2(40nm) double buffer layer showed significantly improved results as 83.58% and 0.05, respectively, compared to 74.46% and 4.28 of ITO thin film without double buffer layer. As a result, it was confirmed that optical properties such as transmittance in the short-wavelength region and chromaticity were remarkably improved due to the index matching effect in the ITO thin film with the Nb2O5/SiO2 double buffer layer.

Heating Characteristics of Planar Heater Fabricated with Different Mixing Ratios of MXene-CNT-WPU Composites (MXene-CNT-WPU 복합소재 기반 면상발열체의 배합 비율에 따른 발열 특성)

  • Hyo-Jun, Oh;Quy-Dat, Nguyen;Yoonsik, Yi;Choon-Gi, Choi
    • Clean Technology
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    • v.28 no.4
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    • pp.278-284
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    • 2022
  • This study presents an excellent planar heater based on low-dimensional composites. By optimizing the ratio of 1D carbon nanotubes (CNT) and 2D MXene (Ti3C2TX), it is possible to create a planar heater that has superior electrical conductivity and high heat generation characteristics. Low-dimensional composites were prepared by mixing CNT paste and MXene solution with eco-friendly waterborne polyurethane (WPU). In order to find the optimal mixing ratio for the MXene-CNT-WPU composites, samples with MXene to CNT weight ratios of 3:1, 1:1, 1:3, 1:7, and 1:14 were investigated. In addition to these different weight ratios, 5 wt% WPU was equally applied to each sample. It was confirmed that the higher the weight ratio of CNT, the lower the sheet resistance and the higher the heating temperature. In particular, when the MXene-CNT-WPU planar heater was fabricated by mixing MXene and CNT at a weight ratio of 1:7 and 1:14, the heating temperature was higher than the heating temperature of a CNT-WPU planar heater. These characteristics are due to the optimized mixture of the 1D materials (CNT) and the 2D materials (MXene) causing the formation of a flat surface and a dense network structure. The low-dimensional composites manufactured with the optimized mixing ratios found in this study are expected to be applied in flexible electronic devices.