• Journal of Energy Engineering
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• v.27 no.4
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• pp.27-35
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• 2018

The passive containment cooling system (PCCS) has been designed to remove the released decay heat during the accident by means of the condensation heat transfer phenomenon to guarantee the safety of the nuclear power plant. The heat removal performance of the PCCS is mainly governed by the condensation heat transfer of the steam-air mixture. In this study, the heat removal performance of the PCCS was evaluated by using the MARS-KS code with a new empirical correlation for steam condensation in the presence of a noncondensable gas. A new empirical correlation implemented into the MARS-KS code was developed as a function of parameters that affect the condensation heat transfer coefficient, such as the pressure, the wall subcooling, the noncondensable gas mass fraction and the aspect ratio of the condenser tube. The empirical correlation was applied to the MARS-KS code to replace the default Colburn-Hougen model. The various thermal-hydraulic parameters during the operation of the PCCS follonwing a large-break loss-of-coolant-accident were analyzed. The transient pressure behavior inside the containment from the MARS-KS with the empirical correlation was compared with calculated with the Colburn-Hougen model.

• Journal of the Korean Applied Science and Technology
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• v.36 no.2
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• pp.676-684
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• 2019

The Pictet-Spengler reactions have widely known for the organic synthesis or biosynthesis of biologically active compounds, tetrahydro-${\beta}$-carbolines. We have developed the simple and efficient synthetic method for the synthesis of ${\beta}$-carbolines in water. Their chemical structures were characterized by nmr and UPLC/MS/QTOF. Calculated masses of compound 1 ($C_{17}H_{17}N_2$ 249.1392), 2 ($C_{17}H_{23}N_2$ 255.1861), 3 ($C_{19}H_{21}N_2O_3$ 325.1552) and 4 ($C_{19}H_{19}N_2O$ 279.1497) were almost identical with the detected masses of compound 1 (249.1315), 2 (255.1789), 3 (325.1460) and 4 (279.1364) respectively. Those synthesized four compounds showed strong antibiotic activity against the common E. coli.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.4
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• pp.86-95
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• 2019

Recently, the applications of carbon fiber have been broader than ever when it comes to such industrials as automobiles, ships, aerospace, civil engineering and architecture because of their lightweight-ness and high mechanical properties. This study analyzed mechanical properties and flexural behavior of carbon fiber reinforced cement composites(CFRC) with different fiber contents and fiber lengths, and also impact resistance by natural drop test on mortar specimens was compared and examined. In addition, contents of carbon fiber(CF) were varied by 0.5%, 1.0%, 2.0% and 3.0%. Fiber lengths was used for 6 mm and 12 mm, respectively. As a result of the test, the flow value was very disadvantageous in terms of fluidity due to the carbon fiber ball phenomenon, and the unit weight was slightly reduced. In particular, the compressive strength was decreased with increasing carbon fiber contents. On the other hand, the flexural strength was the highest with 12 mm fiber length and 2% fiber content. As the results of the impact resistance test, the specimens of plain mortar takes about 2~3 times to final fracture, while the specimens of CFRC is somewhat different depending on the increase of the fiber contents. However, when the fiber length is 12 mm and the fiber content is 2%, the impact resistance was the highest.

• The Korean Journal of Food And Nutrition
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• v.33 no.6
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• pp.655-665
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• 2020

In this study, chemical information on a total of 20 individual compounds was constructed to identify isoflavones from the previous reports related with used parts(seeds, leaves, stems, pods) and products of soybean(Glycine max L.). Through constructed library and UPLC-DAD-QToF/MS analysis, a total of 19 individual isoflavones including aglycones, glucosides, acetylglucosides and malonylglucosides as major compounds was identified and quantified from 14 selected soybean seeds. Among them, genistein 7-O-(2"-O-apiosyl)glucoside and genistein 7-O-(6"-O-apiosyl)glucoside(ambocin) were identified tentatively as novel compounds in soybean seeds. Besides, among malonylglucosides, glycitein 4'-O-(6"-O-malonyl)glucoside was estimated for the first time. Total isoflavone contents were distributed from 240.21 to 445.21(mg/100 g, dry matter) and 7-O-6"-O-malonylglucosides were composed of 77.8% on total isoflavone as well as genistein derivatives were confirmed as major class. It was considered importantly that the development of isoflavone-rich varieties was necessary to strengthen their effects such as anti-inflammation, anti-cancer and menopause mitigation. The qualitative and quantitative data presented precisely in this study could be help to select and breed isoflavone-rich varieties. Furthermore, their basic isoflavone profile is expected to be applied to estimate the change of isoflavone conjugates on bioavailability after soy food supplements.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.34 no.1
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• pp.59-69
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• 2021

Recently, large-scale offshore and coastal structures have been constructed owing to the increasing interest in eco-friendly energy development. To achieve this, precise simulations of waves are necessary to ensure the safe operations of marine structures. Several experiments are required in the field to understand the offshore wave; however, in terms of scale, it is difficult to control variables, and the cost is significant. In this study, numerical waves under various wave conditions are produced using a piston-type wavemaker, and the produced wave profiles are verified by comparing with the results from a numerical wave tank (NWT) modeled using the smoothed particle hydrodynamics (SPH) method and theoretical equations. To minimize the effect by the reflected wave, a mass-weighted damping zone is set at the right end of the NWT, and therefore, stable and uniform waves are simulated. The waves are generated using the linear and Stokes wave theories, and it is observed that the numerical wave profiles calculated by the Stokes wave theory yield high accuracy. When the relative depth is smaller than two, the results show good agreement irrespective of the wave steepness. However, when the relative depth and wave steepness are larger than 2 and 0.04, respectively, the errors are negligible if the measurement position is close to the excitation plate. However, the error is 10% or larger if the measurement position is away from the excitation location. Applicable target wave ranges are confirmed through various case studies.

• Applied Chemistry for Engineering
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• v.31 no.6
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• pp.639-645
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• 2020

Among the components of redox flow battery (RFB), the electrode serves as a diffusion layer of an electrolyte and a path for electrons and also is a major component that directly affects the RFB performance. In this paper, chloric/sulfuric mixed acidwas used as a supporting electrolyte in RFB system with Fe2+/Fe3+ and V2+/V3+ as redox couple. The optimum electrode and activation temperature were suggested by comparing the capacity, coulombic efficiency and energy efficiency according to the electrode type and activation temperature. In the RFB single cell evaluation using 5 types of carbon electrodes used in the experiments, all of them showed close to the theoretical capacity to retain the reliability of the evaluation results. GFD4EA showed relatively excellent energy efficiency and charge/discharge capacity. In order to investigate the electrochemical performance according to the activation temperature, GFD4EA electrode was activated by heat treatment at different temperatures of 400, 450, 500, 600 and 700 ℃ under an air atmosphere. Changes in physical properties before and after the activation were observed using electrode mass retention, scanning electron microscope (SEM), XPS analysis, and electrochemical performance was compared by conducting RFB single evaluation using electrodes activated at each temperature given above.

• Journal of the Korean earth science society
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• v.43 no.1
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• pp.77-90
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• 2022

Despite the decreasing trend of anthropogenic emissions in East Asia in recent years, haze days still frequently occur in spring. Atmospheric blocking, which occurs frequently in the northeastern Pacific, leads to persistent changes in large-scale circulation and blocks westerly flow in the East Asian region. During March 2019, frequent warm and stagnant synoptic meteorological conditions over East Asia were accompanied 6-7 days later by the Alaskan atmospheric blocking. The Alaskan atmospheric blocking over the period of March 18-24, 2019 led to high particulate matter (PM₁₀) severe haze days exceeding a daily average of 50 ㎍ m^-3 over the period of March 25-28, 2019 in South Korea. Although the high-PM₁₀ severe haze days were caused by warm and stagnant meteorological conditions, the regional contribution of anthropogenic emissions in eastern China was calculated to be 30-40% using the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem). The major regional contributions of PM₁₀ aerosols in the period of high-PM₁₀ severe haze days were as follows: nitrates, 20-25%; sulphates, 10-15%; ammonium, 5-10%; and other inorganics, 15-20%. Ammonium nitrate generated via gas-to-aerosol conversion in a warm and stagnant atmosphere largely contributed to the regional transport of PM₁₀ aerosols in the high-PM₁₀ severe haze days in South Korea.

• Journal of the Korean Wood Science and Technology
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• v.49 no.3
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• pp.234-253
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• 2021

The Quercus mongolica has a high utilization value in industrial economic sector. The species is distributed throughout Korea, however, the damage caused by deterioration such as discoloration and decay is severe. For this reason, the deterioration of Q. mongolica is an obstacle to its use as wood, but research on deterioration factors is insufficient. In this study, we focused on fungi as a factor influencing the deterioration of Q. mongolica, and isolated and identified the fungi from the deteriorated Q. mongolica. In additions, in order to confirm whether the identified fungi actually affects wood deterioration, enzyme activities of the identified fungi were evaluated and related mass loss of wood treated with the fungi was measured by wood decay test. As a result of sequencing analysis using the ITS region of the genomic DNA of the fungi isolated from Q. mongolica, Mucor circinelloides, Cunninghamella elegans, and Umbelopsis isabellina 3 species belonging to Mucoromycota phylum, and Ophiostoma piceae and Aureobasidium melanogenum 2 species belonging to Ascomycota phylum were identified. These five fungi had enzyme (i.e. cellulase, laccase) activities related to wood decay and reduced the mass of heartwood and sapwood of Q. mongolica in practice. In particular, O. piceae and A. melanogenum, which have both cellulase and laccase activities, showed 6.9% and 1.5% mass loss, respectively. These results indicated that five fungi identified in this study influence the deterioration of Q. mongolica and are wood decaying fungi for Q. mongolica potentially.

• Journal of the Korean Wood Science and Technology
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• v.30 no.1
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• pp.63-71
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• 2002

The bark of P. alba × glandulosa, P. euramericana and P. nigra × maximounczii F₁, several Populus trees, were collected, extracted with acetone-H₂O(7:3, v/v), fractionated with hexane, chloroform and ethylacetate, and freeze dried to give some dark brown powder. Each fraction of the powder was chromatographed on a Sephadex LH-20 column using a series of aqueous methanol and ethanol-hexane mixture as eluents and then identified by thin layer chromatography using TBA and 6% acetic acid as developing solvents. The structures of the isolated compounds were characterized by ¹H, ¹³C and 2D-NMR tools including mass spectrometry. Most of the compounds were flavonoids and salicin derivatives as follows: (+)-catechin, taxifolin, aromadendrin, eriodictyol, naringenin, sakuranetin, sakuranetin-5-O-𝛽-D-glucopyranoside, neosaturanin, salireposide, p-coumaric acid, and aesculin from P. alba × glandulosa, (+)-catechin, salireposide, populoside and salicortin from P. euramericana and (+)-catechin, quercetin, padmatin, salireposide, populoside and salicortin from P. nigra × maximounczii F₁.

• Korean Chemical Engineering Research
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• v.60 no.3
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• pp.386-391
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• 2022

This study is about a technique for obtaining collagen by extracting fat by treating collagen-containing liposuction effluent in the presence of supercritical fluid. Using a supercritical solvent, a collagen extract could be obtained from animal-derived fat in a short time (about 6 hours), and about 2-3% of collagen by mass compared to the raw material could be obtained. The presence of collagen in the extract obtained by supercritical extraction was confirmed by SDS-PAGE, and it was confirmed that it was type 1 collagen having a relatively large molecular weight. In addition, the growth factors of IGF-1, bFGF, VEGF and NGF were analyzed to find out which growth factors were present in the collagen obtained by supercritical extraction, and it was found that these growth factors were contained in the extract. There was no significant difference in DNA content per mg of sample before and after supercritical treatment. Further in-depth studies are likely to be needed on decellularization technology using the supercritical process. In conclusion, the extracellular matrix obtained through the solvent extraction process using a supercritical fluid contains growth factors above a certain amount even after decellularization and removal of fat, so that it was found that not only biocompatibility is greatly increased, but also tissue regeneration can be rapidly induced.