• Title/Summary/Keyword: 정방

Search Result 626, Processing Time 0.028 seconds

기기보수용 크레인의 지진해석에 관한 연구

  • 윤정방;이동근
    • Computational Structural Engineering
    • /
    • v.5 no.2
    • /
    • pp.5-11
    • /
    • 1992
  • 크레인에 대한 내진해석 결과 구조부재의 응력, trolley의 반력, girder의 처짐 및 hoist rope의 인장력이 안전측임을 확인하였다. 또한 크레인 정착부의 설계에 필요한 정착하중을 구할 수 있었으며, 이에 근거하여 정착부의 간격과 부재의 변경을 제안하였다.

  • PDF

Accuracy Improvement of Frame Interpolation Algorithm using Wedge-shaped Block Partitioning (비정방형 블록을 이용한 보간 프레임의 정확도 향상 기법)

  • Jeong, Jae Heon;Jung, Ho Sun;Sunwoo, Myung Hoon
    • Journal of the Institute of Electronics and Information Engineers
    • /
    • v.52 no.5
    • /
    • pp.85-91
    • /
    • 2015
  • This paper presents a novel frame rate up-conversion (FRUC) algorithm. Existing algorithms, in general, employ rectangular blocks for motion estimation and arbitrary shape of an actual object region cannot be precisely represented. On the other hand, the proposed wedge-shaped block partitioning algorithm partitions a rectangular block into two wedge-shaped blocks using the texture information, which makes better approximation for an actual object region. The wedge-shaped block partitioning algorithm as well as the adaptive motion vector prediction algorithm is used to reliably estimate the actual motion. Experimental results show that the proposed FRUC algorithm is superior to existing algorithms up to 1.988dB in PSNR and 0.0167 in SSIM comparisons.

Equilibrium Studies and Thermodynamics for the Mutarotation of Poly(cis-5-methylproline) in Chloroform-Chloroethanol (Chloroform-Chloroethanol 용매중에서 Poly(cis-5-methylproline)의 평형 및 열역학적연구)

  • M. J. Han
    • Journal of the Korean Chemical Society
    • /
    • v.23 no.4
    • /
    • pp.187-197
    • /
    • 1979
  • The molar optical rotation of poly(cis-5-methylproline) was measured in solvent mixtures of chloroform and chloroethanol. After proper allowance for time-dependent mutarota-tions, equilibrium states between form A and form B were observed to occur with a solvent composition of 0.5~10 % chloroethanol in chloroform by volume. From the equilibrium constants, which were calculated by optical rotations at equilibrium measured at three different temperatures (5, 25, and 45 $^{circ}$C), the thermodynamic parameters-free enthalpy, enthalpy and entropy changes for the mutarotation-were evaluated. It was found that starting with equimolar concentrations of form A and form B, the forward mutarotation occurred in the solvent compositions of chloroethanol greater than 3 % by volume, whereas the reverse mutarotation resulted in solvent compositions of chloroethanol less than 3 % by volume. The changes in enthalpy and entropy for the forward mutarotation were found to be positive, while those were for the reverse mutarotation were negative. The driving forces for the forward mutarotation were found to be the increase in entropy, whereas that for the reverse mutarotation was the negative enthalpy change. The thermodynamic data were explained by the interaction between polymer and solvent, i.e., preferential hydrogen bonding of chloroethanol with the carbonyl group in form B over form A, and by difference in conformational energies between form A and form B.

  • PDF

Synthesis and crystallization of nanosized zirconia powder using hydrothermal process (수열반응에 의한 나노 지르코니아 분말의 합성 및 결정화)

  • 노희진;이종국;서동석;황규홍
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.12 no.3
    • /
    • pp.126-132
    • /
    • 2002
  • The nanocrystalline zirconia powder with anisotropic shapes was synthesized by hydrothermal treatment of the tetragonal zirconia prepared by aging the zirconium hydroxide precipitate, which was obtained from the reaction between $ZrOCl_2{\cdot}8H_2O$ and KOH solutions under the fixed pH of 13.5, at $100^{\circ}C$ for 24 h. With increasing the hydrothermal reaction temperature and time, the fraction of tetragonal phase with spherical zirconia decreased, whereas, relatively the fraction of monoclinic phase with spindle-like and rod shape zirconia increased. As increased concentration of the NaOH solution it promoted the particle size to become larger and the crystalline phase to transform tetragonal to monoclinic. However, the specific surface area at the early stage of the reaction increased and subsequently decreased because of grain growth in powder with longer reaction time.

Synthesis of Tetragonal Barium Titanate Powder by Solvothermal Technique (용매열법에 의한 정방정 티탄산 바륨 분말의 합성)

  • Kwon, Soon-Gyu;Choi, Kyoon;Pee, Jae-Hwan;Choi, Eui-Seok
    • Journal of the Korean Ceramic Society
    • /
    • v.42 no.2 s.273
    • /
    • pp.123-126
    • /
    • 2005
  • Barium Titanate (BT) powders were synthesized by solvothermal method with an ethanol as a solvent. The average particle size was increased with the feedstock concentration: the size was 59 nm at $6.25{\times}10^{-2}$ M and 89 nm at 0.5 M. The sample obtained at 0.5 M concentration was analysed by Rietveld refinement and the mole fraction of tetragonal phase was $75.5\%$ and lattice parameter of tetragonal phase was a=0.3999 (nm), c=0.4032 (nm), and cubic phase was a=0.4015 (nm). TEM analysis for the samples with condition of annealing at $500^{\circ}C$ for I h showed that hydroxyl ions on oxygen sites were not found for these experimental conditions.

Structural and Dielectric Properties of PLT Thin Plates (PLT 박편의 구조 및 유전특성)

  • Lee, Jae-Man;Park, Ki-Cheol
    • Journal of Sensor Science and Technology
    • /
    • v.7 no.1
    • /
    • pp.51-60
    • /
    • 1998
  • La-modified $PbTiO_{3}$(PLT) thin plates were prepared for the fabrication of PLT pyroelectric IR sensors. The effects of the preparation parameters such as tile sintering temperature, the La content, and the ambient powder quantity, on the microstructural and dielectric properties of PLT thin plates were investigated by X-ray diffraction, scanning electron microscope, and measurements of relative density and dielectric properties. With an increased La content, the tetragonality c/a was decreased but the densification and the grain size were increased, which is considered to be due to the increased Pb vacancy concentration to maintain charge neutrality at the increased of La content. When the quantity of the ambient powder wvas increased, the tetragonality was slightly increased, which is believed io be due to the reduced evaporation of PbO. But the e(fect is insignificant compared to that of La content. The dielectric constant at room temperature was increased and the Curie temperature was decreased in accordance with the decreased tetragonality ratio c/a with the increase of La content. The dielectric constant and tan ${\delta}$ of $500{\mu}m$ thick PLT thin plate with 10 wt% excess PbO and 10 mol% La contant sintered at $1250^{\circ}C$ for 2 hours in ambient powder of $0.02\;g/cm^{3}$ were 360 and 0.02, respectively.

  • PDF

Formation Rate of Tetragonal BaTiO3 Powder by Hydrothermal Synthesis and its Dielectric Property (수열합성법에 의한 정방정 BaTiO3 분말의 생성속도 및 유전특성)

  • 이종현;최용각;원창환;김채성
    • Journal of the Korean Ceramic Society
    • /
    • v.39 no.7
    • /
    • pp.628-634
    • /
    • 2002
  • Formation rate of tetragonal BaTiO$_3$powder by hydrothermal synthesis and its dielectric property were studied. Submicron tetragonal BaTiO$_3$ powders were prepared hydrothermally, using Ba(OH)$_2$.8$H_2O$, TiO$_2$(anatase) and KOH as starting chemicals. Characterization via X-ray diffractometry, field emission scanning electron microscopy confirmed that increasing calcination temperatures(from 1100 to 130$0^{\circ}C$) promotes the formation of tetragonal BaTiO$_3$. Tetragonal BaTiO$_3$ ceramics, obtained by calcining at 1200 for 3 h after hydrothermal synthesis at 200 for 168 h, exhibited submicron size of 0.5 ~ 0.7 ${\mu}{\textrm}{m}$ and high relative permittivity.

Analysis on Thermomechanical Response to Tensile Deformation of GaN Nanowires (GaN 나노와이어의 인장 변형에 의한 열기계적 거동 해석)

  • Jung, Kwangsub;Zhou, Min;Cho, Maenghyo
    • Journal of the Computational Structural Engineering Institute of Korea
    • /
    • v.25 no.4
    • /
    • pp.301-305
    • /
    • 2012
  • In this work the mechanical behaviors of GaN nanowires are analyzed during tension, compression, and unloading deformations. The thermal conductivity of the nanowires at each deformed state is evaluated using an equilibrium Green-Kubo approach. Under tensile loading, the [0001]-oriented nanowires with hexagonal cross-sections undergo a phase transformation from wurtzite to a tetragonal structure. The phase transformation is not observed under compressive loading. The thermal conductivity decreases on going from compressive strains to tensile strains. The strain dependence of the thermal conductivity results from the relaxation time of phonon. A reverse transformation from the tetragonal structure to the wurtzite structure is observed during unloading. The thermal conductivities in the intermediate states are lower than the conductivity in the wurtzite structure at same strain. Such differences in the thermal conductivity between different atomic structures are mainly due to changes in the group velocity of phonon.

Changes in Solution Properties of Poly(trans-5-methylproline) During Mutarotation (Poly(trans-5-methylproline)의 변광회전에 따른 용액의 성질변화)

  • Han Man Jung
    • Journal of the Korean Chemical Society
    • /
    • v.23 no.1
    • /
    • pp.7-14
    • /
    • 1979
  • Changes in CD, ORD and uv-spectra during the mutarotation of poly(trans-5-methyl-L-proline) (PTMP) were studied. The forward mutarotion of PTMP occurred in strong organic acids and trifluoroethanol, while the reverse mutarotation was observed by dilution of the trifluoroethanol solution with excess aliphatic alcohols. The changes in CD, ORD and uv-spectra during the forward and reverse mutarotation proceeded paralell to those found for the mutarotation of polyproline. The chemical shift of the ${\alpha}CH-$proton was shifted downfield about 0.3 ppm during the forward mutarotation. The reduced viscosity for the forward mutarotation increased from 0.15 to 0.26 (dl/g) during 5 days. The equilibrium between form I and form II was estabilished in an appropriate solvent mixture. All changes in solution properties mentioned above are similar to those found for polypoline. These results support that the two forms of PTMP are the same conformations as polyproline form I and form II, i. e., a right-handed helix with all cis amide bonds and a lefthanded helix with all trans amide bonds.

  • PDF