• Title/Summary/Keyword: 전체평형

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대홍활석광상 주위의 편마암류의 지화학적 특징과 공존광물의 화학적 평형

  • 이상헌;최기주
    • The Journal of the Petrological Society of Korea
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    • v.3 no.2
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    • pp.138-155
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    • 1994
  • Granitic gneiss containing biotite banded gneiss relict around the Daeheung talc deposit are widely distributed which were formed by regional metamorphism of both epidote-amphibolite and iater greenschist facies and granitization. They were derived from same silico-aluminous rocks of sedimentary origin. The mineral assemblages, which are common in the biotite banded gneiss, formed during regional metamorphisms, are survived in the granitic gneiss. The mineral assemblages of the latter greenschist facies may be formed retrogressively from the first epidote-amphibolite facies. The chemical compositions of biotite, muscovite, and chlorite, the important constituents of the gneisses, were controlled by the bulk composition, the chemical composition of the original mineral, and environment of the regional metamorphisms and granitization. The chemical equilibrium between coexisting'minerals, especially biotite and muscovite, is relatively well established, which was controlled mainly by tschermakitic and phengitic substitutions. Cholrite was formed mainly from either biotite or muscovite by retrogressive alteration or granitization, and have nearly similar chemical compositions regardless of the occurrences. The orientation trend of the foliation, joint and quartz vein developed in the gneisses was analyzed by equal area projection which the latter two show nearly identical trend in the strike and dip. This may suggest that the hydrothermal solution was introduced along joint during wet granitization.

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Recovery of Paraffin Components from Pyrolysis Oil Fraction of Waste Plastic by Batch Cocurrent 4 Stages Equilibrium Extraction (회분 병류 4단 평형추출에 의한 폐플라스틱 열분해유 유분 중의 파라핀 성분의 회수)

  • Kang, Ho-Cheol;Shin, Sung Soon;Kim, Doo Han;Kim, Su Jin
    • Applied Chemistry for Engineering
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    • v.29 no.5
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    • pp.630-634
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    • 2018
  • The recovery of paraffin components contained in the fraction as a part of improving the quality for the fraction of waste plastics pyrolysis oil (WPPO) was investigated by batch cocurrent 4 stages equilibrium extraction. The fraction at a distilling temperature of $120-350^{\circ}C$ recovered from WPPO by the simple distillation and a little water-added dimethylformamide (DMF) solution were used as a raw material and solvent, respectively. As the number of equilibrium extraction (n) and the carbon number of paraffin component increased, the concentration of paraffin component contained in the raffinate increased. The concentrations of $C_{12}$, $C_{14}$, $C16$ and $C_{18}$ paraffin components present in the raffinate recovered at n = 4 were about 1.2, 1.5, 1.6 and 1.8 times higher than those of using the raw materials, respectively. Recovery rates (residue rates present in raffinate) of paraffin components rapidly decreased with increasing n, and increased sharply with increasing the carbon number. Furthermore, it was possible to predict the recovery rates at n = 1 - 4 for all paraffin components ($C_7-C_{24}$) contained in the raw material. The raffinate recovered through this study is expected to be used as a renewable energy.

A Stability Analysis of Geosynthetics Reinforced Soil Slopes I. - Slope Stability Analysis Considering Reinforcing Effects - (토목섬유 보강 성토사면의 안정해석 I. - 보강효과를 고려한 사면안정해석 -)

  • Kim Kyeong-Mo;Kim Hong-Taek;Lee Eun-Soo;Kim Young-Yoon;Ahn Kwang-Kuk
    • Journal of the Korean Geotechnical Society
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    • v.21 no.8
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    • pp.95-105
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    • 2005
  • Generally, a modified version of limit equilibrium method can be used to evaluate a slope stability of the geosynthetic reinforced soil slopes. In most cases, resisting effects of geosynthetic reinforcement are dealt with considering an increased shear strength on the potential slip surface. However, it is not clear that the methods satisfy all three equilibrium equations. As we know, the pattern of normal stress distribution along the slip surface is the key factor in calculating the safety factor of slopes. In this study, the new slope stability analysis method in which not only reinforcing effects of geosynthetics can be considered but also all three equilibrium equations can be satisfied was proposed with assuming the normal stress distribution along the slip surface as quadratic curve with horizontal $\chi-coordinate$. A number of illustrative examples, including published slope stability analysis examples for the reinforced and unreinforced soil slopes, loading test of large scale reinforced earth wall and centrifuge model tests on the geotextile reinforced soil slopes, were analyzed. As a result, it is shown that the newly suggested method yields a relatively accurate factor of safety for the reinforced and unreinforced soil slopes.

A Study on The Velocity Distribution in Closed Conduit by Using The Entropy Concept (엔트로피 개념을 이용한 관수로내의 유속분포에 관한 연구)

  • Choo, Tai Ho;Ok, Chi Youl;Kim, Jin Won;Maeng, Seung Jin
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.4B
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    • pp.357-363
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    • 2009
  • When yields the mean velocity of the closed conduit which is used generally, it is available to use Darcy Weisbach Friction Loss Head equation. But, it is inconvenient very because Friction Loss coefficient f is the function of Reynolds Number and Relative roughness (${\varepsilon}$/d). So, it is demanded more convenient equation to estimate. In order to prove the reliability and an accuracy of Chiu's velocity equation from the research which sees hereupon, proved agreement very well about measured velocity measurement data by using Laser velocimeter which is a non-insertion velocity measuring equipment from the closed conduit (Laser Doppler Velocimeter: LDV) and an insertion velocity measuring equipment and the Pitot tube which is a supersonic flow meter (Transit-Time Flowmeters). By proving theoretical linear-relation between maximum velocity and mean velocity in laboratory flume without increase and decrease of discharge, the equilibrium state of velocity in the closed conduit which reachs to equilibrium state corresponding to entropy parameter M value has a trend maintaining consistently this state. If entropy M value which is representing one section is determinated, mean velocity can be gotten only by measuring the velocity in the point appearing the maximum velocity. So, it has been proved to estimate simply discharge and it indicates that this method can be a theoretical way, which is the most important in the future, when designing, managing and operating the closed conduit.

Applications of the Fast Grain Boundary Model to Cosmochemistry (빠른 입계 확산 수치 모델의 우주화학에의 적용)

  • Changkun Park
    • Korean Journal of Mineralogy and Petrology
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    • v.36 no.3
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    • pp.199-212
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    • 2023
  • Diffusion is a powerful tool to understand geological processes recorded in terrestrial rocks as well as extraterrestrial materials. Since the diffusive exchange of elements or isotopes may have occurred differently in the solar nebula (high temperature and rapid cooling) and on the parent bodies (fluid-assisted thermal metamorphism at relatively low temperature), it is particularly important to model elemental or isotopic diffusion profiles within the mineral grains to better understand the evolution of the early solar system. A numerical model with the finite difference method for the fast grain boundary diffusion was established for the exchange of elements or isotopes between constituent minerals in a closed system. The fast grain boundary diffusion numerical model was applied to 1) 26Mg variation in plagioclase of an amoeboid olivine aggregate (AOA) from a CH chondrite and 2) Fe-Mg interdiffusion between chondrules, AOA, and matrix minerals in a CO chondrite. Equilibrium isotopic fractionation and equilibrium partitioning were also included in the numerical model, based on the assumption that equilibrium can be reached at the interfaces of mineral crystals. The numerical model showed that diffusion profiles observed in chondrite samples likely resulted from the diffusive exchange of elements or isotopes between the constituent minerals. This study also showed that the closure temperature is determined not only by the mineral with the slowest diffusivity in the system, but also strongly depends on the constituent mineral abundances.

Improvement of Oxygen Isotope Analysis in Seawater samples with Stable Isotope Mass Spectrometer (질량분석기를 이용한 해수 중 산소안정동위원소 분석법의 개선)

  • Park, Mi-Kyung;Kang, Dong-Jin;Kim, Kyung-Ryul
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.13 no.4
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    • pp.348-353
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    • 2008
  • Oxygen isotope has not been used actively in water mass studies because of difficulties on the analysis though it has advantages as a water mass tracer. The most popular method to analysis the oxygen isotope ratio in water samples is equilibration method: isotopic equilibrium of water with $CO_2$ at constant temperature. The precision of oxygen isotope analysis using commercial automatic $H_2O/CO_2$ equilibrator is ${\pm}0.1%o$. This value is not sufficient for studies in open ocean. The object of this study is to improve the analytical precision enough to apply open ocean studies by modification of the instrument. When sample gas is transferred by the pressure difference, the fractionation which is preferential transportation of light isotope can be occurred since the long transportation path between the equilibrator and mass spectrometer. And the The biggest source of error during the analysis is long distance and large volume of the pathway of sample gas between. Therefore, liquid nitrogen trap and high vacuum system are introduced to the system. The precisions of 14 time analysis of same seawater sample are ${\pm}0.081%o$ and ${\pm}0.021%o$ by built-in system and by modified system in this study, respectively.

Behavior of Mooring Line of Silt Protector According to the Change of Sea Level (조위변화에 따른 오탁방지막 계류라인의 거동)

  • 홍남식;김정윤
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.14 no.3
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    • pp.232-239
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    • 2002
  • This paper studies the behavior of mooring line of silt protector according to the change of sea level. It is found from the analysis of the behavior that if the taut cable length has been determined appropriately within the range of safety factor, the tensioned cable has almost constant tension regardless of the water depth. The whole structure, however, becomes unstable due to the loss (zero tension) of the released cable tension. It is also recognized from the investigation for the effect of intial straight line angle on the behavior of mooring line that the design through the conceptually combined consideration of the cable tension, total scope and buoy deflection has to be required in the mooring analysis. Finally, the material of cable is not damaged because the cable tension is reduced by attached shellfish, but the whole structure may be also unstable by the effect on the anchor angle, total scope and buoy deflection.

Study on the Qualitative Defects Detection in Composites by Optical Infrared Thermography (적외선 열화상 기술을 이용한 복합재료의 결함 검출 정량화 연구)

  • Park, Hee-Sang;Choi, Man-Yong;Park, Jeong-Hak;Kim, Won-Tae;Choi, Won-Jong
    • Journal of the Korean Society for Nondestructive Testing
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    • v.31 no.2
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    • pp.150-156
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    • 2011
  • In this paper, infrared thermography measurement technique has been used to develop standard measurement technique for nondestructive testing of composite materials which is widely used in aerospace industries. To increase the defect detection rate, the related experiment used the lock-in IR-thermographiy method. Therefore it is of considerable interest in the field of non-destructive testing for fast discontinuity detection by using ultrasonic lock-in infrared thermography. The result also shows that as the investigation period of light source is lengthened according to the thickness of specimen, the possibility of detecting defects gets higher as well. However, the reason why the result values were not favorable when less than 50 mHz of light source was provided is because it was difficult to detect defects as the defect parts became a state of thermal equilibrium in general when thermal diffusivity affects the entire materials.

Design and Development of Thermoacoustic Rdfrierator : I. Acoustic Analysis of Resonator and Prediction of Energy Conversion (열음향 냉동기의 설계 및 개발 : I. 내부공간의 음향해석 및 에너지 변환 예측)

  • Park, Chul-Min;Ih, Jeong-Guon
    • The Journal of the Acoustical Society of Korea
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    • v.15 no.5
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    • pp.44-52
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    • 1996
  • Acoustical characteristics of internal pipe structures and a loudspeaker of the thermoacoustic refrigerator are analyzed by using the transfer matrix method. The resonator system is dismantled into verious basic acoustic elements, and then linearized transfer matrices are serially combined with the dynamical system of linearized loudspeaker model, that the total system of thermoacoustic refrigerator can be analyzed in terms of frequency characteristics and acoustic field shape. Additionally, by using equations for energy flow through the capillary stack, the temperature distribution over the stack is numerically estimated. After expressing the acoustic work flow, thermoacoustic flow, and energy loss per unit length in a single capillary duct by using the transverse functional variations, overall energy flow rate and energy balance are obtained for the whole capillary stack. The final expression for energy flow through the stack is numerically evaluated by varying physical parameters obtained from the sound field analysis. After confirming good agreements between predicted and experimental results for the interior sound field of a refrigerator model, the thermoacoustic characteristics of Hofler's apparatus is analyzed by the proposed method and it is observed that the results agree well with Hofler's experimental results.

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Thermal Stability of a Nanostructured Exchange-coupled Trilayer (나노구조 교환결합 삼층박막의 열적 안정성 예측)

  • Lee, Jong-Min;Lim, S.H.
    • Journal of the Korean Magnetics Society
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    • v.20 no.2
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    • pp.75-82
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    • 2010
  • A recent progress on the prediction of the thermal stability of a nanostructured exchange-coupled trilayer is reviewed. An analytical/numerical combined method is used to calculate its magnetic energy barrier and hence the thermal stability parameter. An important feature of the method is the use of an analytical equation for the total energy that contains the magnetostatic fields. Under an assumption of the single domain state, the effective values of all the magnetostatic fields can be obtained by averaging their nonuniform values over the entire magnetic volume. In an equilibrium state, however, it is not easy to calculate the magnetostatic fields at the saddle point due to the absence of suitable methods of the accessing its magnetic configuration. This difficulty is overcome with the use of equations that link the magnetostatic fields at the saddle point and critical fields. Since the critical fields can readily be obtained by micromagnetic simulation, the present method should provide accurate results for the thermal stability of a nanostructured exchange-coupled trilayer.