• Title/Summary/Keyword: 전기화학 유효도 모델

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Numerical Study on Oxygen Depletion Characteristics of Porous Cathodes in Anode-Supported Solid Oxide Fuel Cells (음극지지 고체산화물 연료전지 다공성 양극에서의 산소고갈 특성에 관한 수치해석 연구)

  • Shin, Dongwoo;Nam, Jin Hyun;Kim, Charn-Jung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.4
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    • pp.257-268
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    • 2017
  • This paper proposes an efficient two-dimensional simulation model for solid oxide fuel cells (SOFCs) based on the electrochemical effectiveness model. The effectiveness model is known to accurately predict the current generation performance of SOFC electrodes, by considering the complex reaction/transport processes that occur within thin active functional layers near the electrolyte. After validation tests, the two-dimensional simulation model was used to calculate the distribution of current density and oxygen concentration transverse to the flow channel in anode-supported SOFCs, with which the oxygen depletion characteristics were investigated in detail. In addition, simulations were also conducted to determine the minimum number of grids required in the transverse direction to efficiently obtain accurate results.

A Numerical Modeling of the Temperature Dependence on Electrochemical Properties for Solid Oxide Electrolysis Cell(SOEC) (고체 산화물 수전해 시스템(SOEC)에서 전기화학적 특성의 온도 의존성에 대한 수치 모델링)

  • Han, Kyoung Ho;Jung, Jung Yul;Yoon, Do Young
    • Journal of Energy Engineering
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    • v.29 no.2
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    • pp.1-9
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    • 2020
  • In recent days, fuel cell has received attention from the world as an alternative power source to hydrocarbon used in automobile engines. With the industrial advances of fuel cell, There have been a lot of researches actively conducted to find a way of generating hydrogen. Among many hydrogen production methods, Solid Oxide Electrolysis Cell(SOEC) is not only a basic way but also environment-friendly method to produce hydrogen gas. Solid Oxide Electrolysis Cell has lower electrical energy demands and high thermal efficiency since it is possible to operate under high temperature and high pressure conditions. For these reasons, experimental researches as well as studies on numerical modeling for Solid Oxide Electrolysis Cell have been under way. However, studies on numerical modeling are relatively less enough than experimental accomplishments and have limited performance prediction, which mostly is considered as a result from inadequate effects of electrochemical properties by temperature and pressure. In this study, various experimental studies of commercial Membrane Electrode Assembly (MEA) composed of Ni-YSZ (40wt%, Ni-60 wt% YSZ)/8-YSZ (TOSOH, TZ8Y)/LSM (La0.9Sr0.1MnO3) was utilized for improving effectiveness of SOEC model. After numerically analyzing effects of electrochemical properties according to operating temperature, causing the largest deviation between experiments and simulation are that Charge Transfer Coefficient (CTC), exchange current density, diffusion coefficient, electrical conductivity in SOEC. Analyzing temperature effect on parameter used in overpotential model is conducted for modeling of SOEC. cross-validation method is adopted for application of various MEA and evaluating feasibility of model. As a result, the study confirm that the numerical model of SOEC based on structured process of effectiveness evaluation makes performance prediction better.

Numerical Modeling of Physical Property and Electrochemical Reaction for Solid Oxide Fuel Cells (고체 산화물 연료전지를 위한 물성치 및 전기화학반응의 수치해석 모델링)

  • Park, Joon-Guen;Kim, Sun-Young;Bae, Joong-Myeon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.2
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    • pp.157-163
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    • 2010
  • Solid oxide fuel cells (SOFCs) are commonly composed of ceramic compartments, and it is known that the physical properties of the ceramic materials can be changed according to the operating temperature. Thus, the physical properties of the ceramic materials have to be properly predicted to develop a highly reliable simulation model. In this study, several physical properties that can affect the performance of SOFCs were selected, and simulation models for those physical properties were developed using our own code. The Gibbs free energy for the open circuit voltage, exchange current densities for the activation polarization, and electrical conductivity for the electrolyte were calculated. In addition, the diffusion coefficient-including the binary and Knudsen diffusion mechanisms-was calculated for mass transport analysis at the porous electrode. The physical property and electrochemical reaction models were then simulated simultaneously. The numerical results were compared with the experimental results and previous works studied by Chan et al. for code validation.

Prognostics and Health Management for Battery Remaining Useful Life Prediction Based on Electrochemistry Model: A Tutorial (배터리 잔존 유효 수명 예측을 위한 전기화학 모델 기반 고장 예지 및 건전성 관리 기술)

  • Choi, Yohwan;Kim, Hongseok
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.42 no.4
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    • pp.939-949
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    • 2017
  • Prognostics and health management(PHM) is actively utilized by industry as an essential technology focusing on accurately monitoring the health state of a system and predicting the remaining useful life(RUL). An effective PHM is expected to reduce maintenance costs as well as improve safety of system by preventing failure in advance. With these advantages, PHM can be applied to the battery system which is a core element to provide electricity for devices with mobility, since battery faults could lead to operational downtime, performance degradation, and even catastrophic loss of human life by unexpected explosion due to non-linear characteristics of battery. In this paper we mainly review a recent progress on various models for predicting RUL of battery with high accuracy satisfying the given confidence interval level. Moreover, performance evaluation metrics for battery prognostics are presented in detail to show the strength of these metrics compared to the traditional ones used in the existing forecasting applications.

Study on the separation of large ionic-molecules by electrofiltration (전기여과에 의한 거대이온성 분자체 분리현상연구)

  • Park Young-Gyu
    • Journal of the Korean Electrochemical Society
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    • v.1 no.1
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    • pp.18-23
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    • 1998
  • Theoretical model has been derived in the electrophoretic separation system where an electric potential is applied to the system in the axial direction. The effect of electrophoretic convection in the polymeric media is significantly contributed to separate large ionic-molecules because the conformation of large ionic-molecule quickly orients in the field direction. The dependence of the transport in the polymeric media upon field intensity and molecular size aids in understanding the transport of large ionic-molecule in the system, since the convective velocity of large ionic-molecule is accelerated inside a porous material. The separation of two different large ionic-molecules is predicted with a value of $(Pe_t/Pe_g)$ of individual large ionic-molecule using an operator and the reptation theories.

Radiation characteristics analysis of Langevin transducer having a rim-fixed circular plate (주위가 고정된 원형 평판을 가진 란주반 트랜스듀서의 방사 특성 해석)

  • Jungsoon Kim;Jiwon Yoon;Moojoon Kim
    • The Journal of the Acoustical Society of Korea
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    • v.43 no.4
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    • pp.391-399
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    • 2024
  • In order to analyze the distribution of sound fields radiating from a circular plate vibrated by a Langevin transducer, a theoretical analysis model was derived. The boundary conditions of the driving area and fixed boundary area were appropriately applied to the equation of motion of the vibrating plate, which was derived by L. Rayleigh. By calculating the vibration displacement distributed on the surface of the vibrating plate using the derived analysis model and then calculating the sound field formed by the ultrasonic waves radiating from it, it was confirmed that the radiation characteristics vary significantly depending on the area of the vibrating plate. For comparison, a simulation of the same system was performed using the COMSOL program, a finite element method, and showed good agreement with the theoretical calculation results, confirming the effectiveness of the theoretical analysis model derived in thisstudy. It is expected that the theoretical analysis model derived from this study can be used in the design and development of related devices, such as in the ultrasonic chemistry field.

Effect of Flow Direction on Temperature Uniformity in Solid Oxide Fuel Cell (고체산화물 연료전지의 유동방향에 따른 온도 균일성 영향)

  • Jeon, Dong Hyup;Shin, Dong-Ryul;Ryu, Kwang-Hyun;Song, Rak-Hyun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.10
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    • pp.667-673
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    • 2017
  • We investigated the temperature uniformity in an anode-supported solid oxide fuel cell, using the open source computational fluid dynamics (CFD) toolbox, OpenFOAM. Numerical simulation was performed in three different flow paths, i.e., co-flow, counter-flow, and cross-flow paths. Gas flow in a porous electrode was calculated using effective diffusivity while considering the effect of interconnect rib. A lumped internal resistance model derived from a semi-empirical correlation was implemented for the calculation of electrochemical reaction. The result showed that the counter-flow path displayed the most uniform temperature distribution.

Using Effective Temperatures to Determine Safety Cultivation Season in Direct Seeding Rice on Dry Paddy (작물생육 유효기온 출현시기를 이용한 건답직파 벼의 지역별 안전작기 설정)

  • 최돈향;윤경민;윤성호;박무언
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.42 no.6
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    • pp.666-672
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    • 1997
  • Twenty years' daily mean air temperature data was used to calculate the critical early seeding date(CESD), the optimum heading date(OHD), the critical late heading date for stable ripening(CHDR) and the critical late ripening date(CLRD) for rice seeded on dry paddy in different agroclimatic zones in Korea. The CESD was defined as the first day with mean air temperature of 13$^{\circ}C$, and the OHD as the first day of the 40 consecutive days with mean air temperature of 22$^{\circ}C$ or above after heading. The CHDR was defined as the date after which the cumulative daily mean air temperature would be at least 76$0^{\circ}C$. Lastly, the CLRD was defined as the last day when daily mean air temperature remains above 15$^{\circ}C$. This information was used for the estimation of periods from the earliest date of seeding to optimum heading date, the latest possible date of heading and the latest possible date of ripening in respective regions. For instance, in Suwon, those respective periods mentioned were found to be 104days, 124days, and 165days.

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