• Title/Summary/Keyword: 자연 수소

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Numerical Analysis on the Autoignition of Hydrogen/Air Mixture Near a Hot Surface (고온벽면에 의한 수소-공기 예혼합기체의 자연발화에 관한 수치적 해석)

  • 박은성;백승욱
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.1
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    • pp.70-76
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    • 1992
  • Ignition of hydrogen-air premixed gas in the vicinity of a hot surface has been investigated. Especially multistep reaction model was compared with a single reaction model. It was found that the multistep model with 48 step elementary chemical reactions produced a phenomenologically reasonable trend in ignition delays. The ignition d(2lays increase as the mixture becomes either fuel-rich or fuel-lean with a minimum near the stoichiometric value. The minimum surface temperature has been deduced by extrapolating predicted ignition delays. It was in quite good agreement with the experimental data.

A Basic Experimental Study on Performance of Proton Exchange Membrane Fuel Cell System for Vehicle (PEM 연료전지 자동차 적용을 위한 성능실험에 관한 기초연구)

  • Lee, Hyun-kun;Oh, Byeong-soo;Jeong, Kwiseong
    • Transactions of the Korean hydrogen and new energy society
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    • v.11 no.3
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    • pp.137-147
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    • 2000
  • Not only study of fuel cell performance but study of fuel cell application is very important, therefore these studies were paralleled together for the commercialization of exciting power generation. The objective of this study is to determine the characteristics of shaft power and efficiency as a function of rpm and to compare natural convection air method to forced air method. From these results, performance of forced air was better than that of natural convection air because it enables to improve mass transportation by increasing air flow rate. With decreasing shaft power, efficiency of fuel cell decreases remarkably because dc motor drives at the low range of efficiency. Fuel cell powered vehicle has to be driven considering efficiency and shaft power. It should be driven at 35-45% of efficiency and 0.55-0.75v/cell.

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Development of Temporary Preservation Method for Small Scale Dairy Farm Milk by $H_2O$$_2$ Catalase Treatment (Part 1) Bactericidal Effect of Hydrogen Peroxide and Its Stability in Milk ($H_2O$$_2$-Catalase처리에 의한 소규모 목장우유의 일시적 보존법의 개발 (제1보) 우유에 있어서 과산화수소의 살균효과 및 안정성)

  • Park, I.S.;Pack, M.Y.
    • Microbiology and Biotechnology Letters
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    • v.5 no.3
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    • pp.113-118
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    • 1977
  • Into the precontaminated farm milk hydrogen peroxide ($H_2O$$_2$) was added at the concentrations ranging from 0.01% to 0.05% and kept at 3$0^{\circ}C$ for 16 hours with periodical determinations for viable counts, residual $H_2O$$_2$, and lactic acid. Under the tested conditions the initial level of contaminated bacteria could be arrested from growing at least for 8, 12, and 16 hours by treating the milk with 0.01, 0.02. and 0.03 per cent of $H_2O$$_2$, respectively. Furthermore, when the $H_2O$$_2$concentrations ware limited within the level of 0.03 Per cent the added $H_2O$$_2$was completely decomposed within 12 hours without the aid of external catalase and the decomposition time decreased in parallel with the $H_2O$$_2$ concentrations. A safer use of $H_2O$$_2$for preserving farm milk temporarily by limiting its concentration has been discussed.

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A Study on the Remediation using Microbial Activator from Oil-Contaminated Soil (미생물활성화제를 이용한 유류오염토양 복원에 관한 연구)

  • Lee, Chae-Young;Chung, Chan-Kyo;Kim, Jong-Moon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.19 no.2
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    • pp.41-48
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    • 2011
  • In this study, the soil remediation by landfarming was carried out using microbial activators. Feasibility studies and reduction capacity of TPH(Total Petroleum Hydrocarbons) were investigated in order to find out how fast and eco-friendly the contaminated soil can be recovered. The lab-test confirmed not only the performance and degradation efficiency of microbial activators but also the effect of TPH reduction in the contaminated soil. The optimum growth conditions for indigenous microorganisms were identified using microbial activators. Based on the results of TPH removal, although there had been a little of difference in between natural decomposition and microbial activators until 20 days, the sample groups of microbial activators were higher than the control ones after 20 days. Microbial activators were applied to the field experiments on landfarming. Based on the results of removal rate in each floor of soil, it was found that the removal rates were 85.8 % in the upper, 84.4 % in the middle, and 66.10 % in the bottom. Considering that the reduction rate of TPH for the control group averaged 71.1%, the microbial activators might not be fully transferred into the bottom, which resulted from the piles of soil. As the piles have already reached 1 m in the field experiments, the low piles of soil under 0.6 m may enhance the treatment efficiency of TPH.

The Development of Cylinder Shaped Air-breathing PEMFC (원통형 자연대류 방식 PEMFC 개발)

  • Lee, Kang-In;Lee, Se-Won;Park, Min-Soo;Chu, Chong-Nam
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.2
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    • pp.125-132
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    • 2009
  • Cylinder shaped air-breathing PEMFC has been developed to have small volume, low contact resistance and better air accessibility to the open cathode. This cylinder shaped design consists of an anode cylinder with helical flow channel and a cathode current collector with slits. The pressure distribution measurement according to the shapes was performed. The test result indicated that cylinder shaped fuel cell has better pressure distribution compared with the planar shaped fuel cell. The better pressure distribution was connected to the higher performance. The maximum power density of cylinder shaped fuel cell was about 20% higher than the planar shaped fuel cell. The maximum power density of the developed cylinder shaped air-breathing PEMFC with dry hydrogen was $220\;mW/cm^2$ and with humidified hydrogen was $293\;mW/cm^2$.

Numerical Study on Spontaneous Combustion in Coal Stockpile (저탄장에서의 석탄 자연발화에 관한 수치 해석적 연구)

  • HONG, JINPYO;KIM, JAEKWAN;CHI, JUNHWA;PARK, SUKWOON;SEO, DONGGYUN;LEE, JINHYANG
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.6
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    • pp.721-728
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    • 2017
  • In this work, an one-dimensional analysis on spontaneous combustion in a coal stockpile was conducted using a commercial software $gPROMS^{(R)}$ based on assumption suggested by Arioy and Akgun. According to them, it is assumed that there is temperature difference between the surface of coal particle and the gas surrounded around the particle, and it is also assumed that the velocity of the gas is constant and thus oxygen is fed to the stockpile with same velocity. The higher temperature zone is formed to the surface of the coal stockpile at the initial phase and it became deepen as time is taken. Finally it was found that the temperature difference between coal particle and the gas was calculated as $57^{\circ}C$ and spontaneous combustion have not been occurred during 6 months since coal was piled in the stock.

Operation Performance of a Polymer Electrolyte Fuel Cell Cogeneration System for Residential Application (가정용 고분자연료전지 시스템의 운전 방법에 따른 성능 비교)

  • Lee, W.Y.;Jeong, K.S.;Yu, S.P.;Um, S.K.;Kim, C.S.
    • Transactions of the Korean hydrogen and new energy society
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    • v.16 no.4
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    • pp.364-371
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    • 2005
  • Fuel cell systems(FCS) have a financial and environmental advantage by providing electricity at a high efficiency and useful heat. For use in a residence, a polymer electrolyte fuel cell system(PEFCS) with a battery pack and a hot water storage tank has been modelled and simulated. The system is operated without connection to grid line. Its electric conversion efficiency and heat recovery performance are highly dependent on operation strategies and also on the seasonal thermal and electric load pattern. The output of the fuel cell is controlled stepwise as a function of the state of the battery and/or the storage water tank. In this study various operation strategies for cogeneration fuel cell systems are investigated. Average fuel saving rates at different seasons are calculated to find proper load management strategy. The scheme can be used to determine the optimal operating strategies of PEFCS for residential and building applications.

An Experimental Study on the Natural Convection Heat Transfer of Air-cooling PEMFC in a Enclosure (밀폐된 공간 내 공랭식 PEMFC의 자연대류 열전달에 대한 실험적 연구)

  • LEE, JUNSIK;KIM, SEUNGGON;SOHN, YOUNGJUN
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.1
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    • pp.42-48
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    • 2016
  • This study presents an experiment investigation on natural convection heat transfer of air-cooling Proton exchange membrane fuel cells (PEMFCs) in a enclosure system for unmanned aerial vehicles (UAVs). Considered are replacing fuel cell stack with Aluminum block for heat generating inside a enclosure chamber. The volume ratio of fuel cell stack and chamber for simulation to the actual size of aerial vehicle is 1 to 15. The parameters considered for experimental study are the environmental temperature range from $25^{\circ}C$ to $-60^{\circ}C$ and the block heat input of 10 W, 20 W and 30 W. Effect of the thermal conductivity of the block and power level on heat transfer in the chamber are investigated. Experimental results illustrate the temperature rise at various locations inside the chamber as dependent upon heat input of fuel cell stack and environmental temperature. From the results, dimensionless correlation in natural convection was proposed with Nusselt number and Rayleigh number for designing air-cooling PEMFC powered high altitude long endurance (HALE) UAV.

Construction and Characterization of Poly (Phenylene Oxide)-Based Organic/Inorganic Composite Membranes Containing Graphene Oxide for the Development of an Anion Exchange Membrane with Extended Ion Cluster (확장된 이온 클러스터를 갖는 음이온 교환막 개발을 위한 그래핀 옥사이드를 함유한 폴리(페닐렌 옥사이드) 기반 유·무기 복합막의 제조 및 특성분석)

  • CHU, JI YOUNG;YOO, DONG JIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.6
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    • pp.524-533
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    • 2021
  • In this study, a series of anion conductive organic/inorganic composite membranes with excellent ionic conductivity and chemical stability were prepared by introducing graphene oxide (GO) inorganic nanofiller into the quaternized poly(phenylen oxide (Q-PPO) polymer matrix. The fabricated organic/inorganic composite membranes showed higher ionic conductivity than the pristine membrane. In particular, Q-PPO/GO 0.7 showed the highest ionic conductivity value of 143.2 mS/cm at 90℃, which was 1.56 times higher than the pristine membrane Q-PPO (91.5 mS/cm). In addition, the organic/inorganic composite membrane showed superior dimensional stability and alkaline stability compared to the pristine membrane, and the physicochemical stability was improved as the content of inorganic fillers increased. Therefore, we suggest that the as-prepared organic/inorganic composite membranes are very promising materials for anion exchange membrane applications with high conductivity and alkaline stability.

Effect of Silicotungstic Acid as Inorganic Filler on the Properties of Anion Exchange Composite Membranes (무기첨가제 규소텅스텐산이 음이온교환 복합막 특성에 미치는 영향)

  • LEE, KYU HA;YOO, DONG JIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.1
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    • pp.28-37
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    • 2022
  • In this study, we synthesized a poly(pheneylene oxide) (PPO)-based organic/inorganic composite membrane having silicotungstic acid (STA) for the development of an anion exchange membrane with excellent ionic conductivity and physicochemical stability. The organic/inorganic composite membranes were prepared by introducing different STA contents (0 wt%, 10 wt%, 30 wt%, and 50 wt%) into the quaternizaed(Q)-PPO matrix. The prepared anion exchange membranes were subjected to structural analysis by proton neclear magnetic resonance and Fourier transform infrared, and thermal behavior of membranes was confirmed by thermogravimetric analysis. Among the prepared composite membranes, the ion conductivity of Q-PPO/STA-50 (40.5 mS cm-1) showed 1.46 times compared to that of the pristine membrane (27.6 mS cm-1). Therefore, these results demonstrated that organic/inorganic composite membranes are promising candidates for application of anion exchange membranes.