• Polymer Science and Technology
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• v.15 no.4
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• pp.449-456
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• 2004

이온성 액체 (ionic liquid)는 유기 양이온과 유기 (또는 무기) 음이온으로 이루어진 화합물이다. 이온들이 작아, 서로 가깝게 packing되어 있는 일반 이온성 염 (상온에서 고체상)과는 다르게, 이온성 액체는 양이온과 음이온의 크기가 상대적으로 커서, packing이 잘 되지 않아 낮은 lattice energy를 갖고 있게 되어,$^1$ 10$0^{\circ}C$나 그 이하의 낮은 녹는점을 갖는 염이다. 녹는점, 밀도, 점도, 친수성 및 소수성 특성은 주어진 이온성 액체의 양이온과 음이온을 적절히 선택하면 얼마든지 조절할 수 있어, 이온성 액체를 des구nor solvent로 부르고 있다.(중략)

• Membrane Journal
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• v.30 no.3
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• pp.149-157
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• 2020

Ionic Liquid (IL) in the category of low-temperature molten salts with organic cation and organic/inorganic anion has shown great potentiality in CO₂ gas separation. CO₂ gas separation from flue gas by IL based membrane has been widely researched in recent years to overcome climate change and global warming. Membranes based on free standing polyionic liquid (PIL), blend of ionic liquid and composite ionic liquid membranes are discussed in this review. Introducing different IL monomers and tuning microstructure of PIL membrane and composite of PIL-IL to enhance mechanical properties of membranes with good CO₂ gas permeability and selectivity. Variations in cation and anions of monomer has great impact on the membrane gas separation performance.

• Journal of the Korean Applied Science and Technology
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• v.37 no.6
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• pp.1591-1596
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• 2020

The solid-state electrolyte based on polymer has great attention to develop its ionic conductivity from conventional polymer electrolyte by using wide range of ionic liquids with remarkable processability, flexibility and is applicable to various electrochemical devices including batteries, supercapacitor. Polymer electrolyte based on Ionic liquid with high conductivity, wide electrochemical stability, thermal stability is used in various electronic devices. In this work, we have investigated and developed solid-state electrolyte based on ionic liquid and polymer with enhanced ionic conductivity and electrochemical performances to conduct to various electronic devices including secondary battery. The ionic conductivity of polymer based solid state electrolyte with optimized ratio of the ionic liquid was 1.46-2 S/cm. The ionic liquid and polymer based electrolyte with enhanced ionic conductivity is promising candidates to utilize in wide range of secondary batteries.

• Analytical Science and Technology
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• v.24 no.6
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• pp.467-476
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• 2011

Solubility data of carbon dioxide ($CO_2$) in the imidazolium-based ionic liquids with methylsulfate anion are presented at pressures up to about 45 MPa and at temperatures between 303.15 K and 343.15 K. The ionic liquids studied in this work were 1-ethyl-3-methylimidazolium methylsulfate ([emim][$mSO_4$]), 1-butyl-3-methylimidazolium methylsulfate ([bmim][$mSO_4$]). The solubilities of $CO_2$ were determined by measuring the bubble point or cloud point pressures of the binary mixtures using a high-pressure equilibrium apparatus equipped with a variable-volume view cell. The equilibrium pressure increased very steeply at high $CO_2$ compositions. The $CO_2$ solubility in ionic liquids increased with increase of the total length of alkyl chains attached to the imidazolium cation of the ionic liquids. The phase equilibrium data for the $CO_2$ + ionic liquid systems have been correlated using the Peng-Robinson equation of state.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.12 no.1
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• pp.45-57
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• 2014

Academic interests in ionic liquid (IL) technologies have been extended to the nuclear industry and the applicability of ionic liquids for processing radioactive materials have been investigated by many researchers. A number of studies have reported interesting results with respect to the spectroscopic and electrochemical behaviors of metal elements included in spent nuclear fuels. The measured and observed properties of metal ions in TBP(tri-butyl phosphate) dissolved ILs have led the development of alternative technologies to traditional aqueous processes. On the other hand, the electrochemical deposition of metal ions in ILs have been investigated for the application of the solvents to aqueous as well as to non-aqueous processes. In this work, a review on the application of ILs in nuclear fuel cycle is presented for the purpose of categorizing and summarizing the notable researches on ILs.

• Prospectives of Industrial Chemistry
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• v.23 no.1
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• pp.30-41
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• 2020

최근 전기차, 신재생에너지 등장 등으로 중대형 이차전지 시장이 확대되면서, 리튬 이온 배터리 안전성 이슈 관련 고안전성 전해액 소재에 대한 관심이 높아졌다. 다양한 고안전성 전해액 시스템 중, 상온 이온성 액체는 비발화성, 낮은 증기압 특성으로 많은 관심을 받고 있다. 뛰어난 물리적 특성에도 불구하고 리튬 이온 배터리의 전해액으로 사용되기 위해서는 전도도 및 전기화학 안전성, 전극 계면 거동이 전기화학 성능을 얻는데 만족되어야 한다. 많은 종류의 상온 이온성 액체들이 분자 구조 설계 및 양극/음극 전해액 사용, 전지 내 부품 안전성 확보 등의 다양한 접근 방법들로 연구가 진행되어 왔다. 향후 지속적인 전지 안전성의 이슈에 대한 중요성 증대로 상온 이온성 액체에 대한 연구 역시 더 활발해질 것으로 기대되며, 본 기고문에서는 다양한 상온 이온성 액체들이 전지 시스템에 적용된 연구동향에 대해서 정리하고 소개하고자 한다.

• Clean Technology
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• v.20 no.4
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• pp.354-358
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• 2014

Ionic liquid (IL) is a salt presents in a liquid form at room temperature. Recently, it attracts huge attention due to its possibilities as a clean solvent, electrolyte, and catalyst. In the present work, the charging behavior of six different ILs were investigated using droplet contact charging phenomenon in a dielectric medium. Basically, the charging of an IL droplet can be explained by a perfect conductor theory. However, there were several different features depending on the species of ions of ILs, which requires rigorous molecular level modeling of charge transport through electrochemical reaction of IL. We hope the present results contribute to build up fundamental understanding of electrochemical charge transport of IL.

• Applied Chemistry for Engineering
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• v.23 no.5
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• pp.510-513
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• 2012

Palladium particles were synthesized by conventional chemical reduction method with ionic liquids. The size and shape of palladium particles were significantly affected by the cation parts of ionic liquids. This is mainly attributed to the different stabilities of the ionic liquid structure formed by the physical bond between the cation parts. Among ionic liquids with [$BF_{4}$] as an anion part, the hexyl substituent in the cation parts was more effective to synthesize palladium particles with the smaller size and more uniform shape.

• Applied Chemistry for Engineering
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• v.27 no.5
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• pp.551-554
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• 2016

Silver particles were synthesized by chemical reduction with ionic liquids. Structure of silver particles were significantly affected by the cation parts of the ionic liquids. With increasing the length of the cation part, the smaller silver particles were formed regardless of the anion type. This is mainly attributed to the different stability of the ionic liquid structure formed by physical bond between cation parts. Among seven ionic liquids, [Omim][$PF_6$] was the most effective for synthesizing silver particles.

• Korean Chemical Engineering Research
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• v.51 no.1
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• pp.106-110
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• 2013

In this work, we investigated 20 kinds of ionic liquids as catalyst during the hydrolysis of Saccharina japonica. Three kinds of ionic liquid, 1-ethyl-3-methylimidazolium tetrafluoroborate, n-butyl-4-methylpyridinium tetrafluoroborate, and n-methylmorpholine [$HSO_4$], are selected, and then investigated the effect of reaction temperature, catalyst amount and reaction time. The hydrolysis of S. japonica was increased by the increasing of reaction temperature and ionic liquid amount. Also, the hydrolysis presented the linear increase by the increasing of reaction time. After 90 min of reaction, the concentrations of reducing sugar of 1-ethyl-3-methylimidazolium tetrafluoroborate, n-butyl-4-methylpyridinium tetrafluoroborate, and n-methylmorpholine [$HSO_4$] are reached to 6.2 g/L, 6.4 g/L and 6.0 g/L, respectively. As an overall result, we obtained the possibility of hydrolysis of marine biomass using ionic liquids.